Physical-chemical behavior of novel copolymers composed of methacrylic acid and 2-acrylamido-2-methylpropane sulfonic acid
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2016
Authors
Nešić, AleksandraPanić, Vesna
Ostojić, Sanja
Micić, Darko
Pajić-Lijaković, Ivana
Onjia, Antonije
Veličković, Sava
Article (Published version)
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This article described the synthesis and characterization of new copolymer hydrogels containing two hydrophilic units-methacrylic acid (MAA) and 2-Acrylamido-2-methylpropane sulfonic acid (AMPS). The resulting hydrogels were characterized by various techniques: FTIR, Elemental analysis, SEM, Dynamic Molecular simulation, Dynamic-Mechanical analysis and DSC in order to confirm the structure of hydrogels and to predict the best ratio composition with enhanced physical chemical properties. The swelling behavior in water was studied as a function of ratio of monomers and their concentration in medium. An increase in AMPS content led to expansion of network and increase in swelling degree capacity in water. An increase in AMPS content did not significantly influence the glass transition temperature of copolymers, indicated that the physical properties of initial components were preserved. The equal amount of monomers contributed to the highest strength of hydrogels. Meanwhile, the introduct...ion of AMPS to the system was an effective method for improving the performances of the poly(methacrylic acid)- based hydrogels.
Keywords:
Polymers / Differential scanning calorimetry (DSC) / Electron microscopy (STEM, TEM and SEM) / Fourier transform infrared spectroscopy (FTIR)Source:
Materials Chemistry and Physics, 2016, 174, 156-163Publisher:
- Elsevier Science Sa, Lausanne
Funding / projects:
- Advanced technologies for monitoring and environmental protection from chemical pollutants and radiation burden (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
- Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-MESTD-Basic Research (BR or ON)-172062)
- Osmotic dehydration of food - energy and ecological aspects of sustainable production (RS-MESTD-Technological Development (TD or TR)-31055)
- Content of bioactive components in small and stone fruits as affected by cultivar specificities and growing conditions, and obtaining biologically valuable products by improved and newly developed technologies (RS-MESTD-Technological Development (TD or TR)-31093)
DOI: 10.1016/j.matchemphys.2016.02.063
ISSN: 0254-0584
WoS: 000373865700019
Scopus: 2-s2.0-84977867193
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Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Nešić, Aleksandra AU - Panić, Vesna AU - Ostojić, Sanja AU - Micić, Darko AU - Pajić-Lijaković, Ivana AU - Onjia, Antonije AU - Veličković, Sava PY - 2016 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3415 AB - This article described the synthesis and characterization of new copolymer hydrogels containing two hydrophilic units-methacrylic acid (MAA) and 2-Acrylamido-2-methylpropane sulfonic acid (AMPS). The resulting hydrogels were characterized by various techniques: FTIR, Elemental analysis, SEM, Dynamic Molecular simulation, Dynamic-Mechanical analysis and DSC in order to confirm the structure of hydrogels and to predict the best ratio composition with enhanced physical chemical properties. The swelling behavior in water was studied as a function of ratio of monomers and their concentration in medium. An increase in AMPS content led to expansion of network and increase in swelling degree capacity in water. An increase in AMPS content did not significantly influence the glass transition temperature of copolymers, indicated that the physical properties of initial components were preserved. The equal amount of monomers contributed to the highest strength of hydrogels. Meanwhile, the introduction of AMPS to the system was an effective method for improving the performances of the poly(methacrylic acid)- based hydrogels. PB - Elsevier Science Sa, Lausanne T2 - Materials Chemistry and Physics T1 - Physical-chemical behavior of novel copolymers composed of methacrylic acid and 2-acrylamido-2-methylpropane sulfonic acid EP - 163 SP - 156 VL - 174 DO - 10.1016/j.matchemphys.2016.02.063 ER -
@article{ author = "Nešić, Aleksandra and Panić, Vesna and Ostojić, Sanja and Micić, Darko and Pajić-Lijaković, Ivana and Onjia, Antonije and Veličković, Sava", year = "2016", abstract = "This article described the synthesis and characterization of new copolymer hydrogels containing two hydrophilic units-methacrylic acid (MAA) and 2-Acrylamido-2-methylpropane sulfonic acid (AMPS). The resulting hydrogels were characterized by various techniques: FTIR, Elemental analysis, SEM, Dynamic Molecular simulation, Dynamic-Mechanical analysis and DSC in order to confirm the structure of hydrogels and to predict the best ratio composition with enhanced physical chemical properties. The swelling behavior in water was studied as a function of ratio of monomers and their concentration in medium. An increase in AMPS content led to expansion of network and increase in swelling degree capacity in water. An increase in AMPS content did not significantly influence the glass transition temperature of copolymers, indicated that the physical properties of initial components were preserved. The equal amount of monomers contributed to the highest strength of hydrogels. Meanwhile, the introduction of AMPS to the system was an effective method for improving the performances of the poly(methacrylic acid)- based hydrogels.", publisher = "Elsevier Science Sa, Lausanne", journal = "Materials Chemistry and Physics", title = "Physical-chemical behavior of novel copolymers composed of methacrylic acid and 2-acrylamido-2-methylpropane sulfonic acid", pages = "163-156", volume = "174", doi = "10.1016/j.matchemphys.2016.02.063" }
Nešić, A., Panić, V., Ostojić, S., Micić, D., Pajić-Lijaković, I., Onjia, A.,& Veličković, S.. (2016). Physical-chemical behavior of novel copolymers composed of methacrylic acid and 2-acrylamido-2-methylpropane sulfonic acid. in Materials Chemistry and Physics Elsevier Science Sa, Lausanne., 174, 156-163. https://doi.org/10.1016/j.matchemphys.2016.02.063
Nešić A, Panić V, Ostojić S, Micić D, Pajić-Lijaković I, Onjia A, Veličković S. Physical-chemical behavior of novel copolymers composed of methacrylic acid and 2-acrylamido-2-methylpropane sulfonic acid. in Materials Chemistry and Physics. 2016;174:156-163. doi:10.1016/j.matchemphys.2016.02.063 .
Nešić, Aleksandra, Panić, Vesna, Ostojić, Sanja, Micić, Darko, Pajić-Lijaković, Ivana, Onjia, Antonije, Veličković, Sava, "Physical-chemical behavior of novel copolymers composed of methacrylic acid and 2-acrylamido-2-methylpropane sulfonic acid" in Materials Chemistry and Physics, 174 (2016):156-163, https://doi.org/10.1016/j.matchemphys.2016.02.063 . .