Remediation of environment contaminated by lead using synthetic and natural apatites
Stabilizacija zagađenja olovom korišćenjem sintetičkih i prirodnih apatita
Апстракт
Lead contamination is an environmental concern due to its effect on human health. One of the ways of remediating lead contamination is the in situ stabilization of this heavy metal. This can be achieved by converting different types of lead species into Pb-phosphates (pyromorphites), which are among the least soluble Pb-bearing solids. Synthetic hydroxyapatite (Ca5(PO4)3OH) and natural apatite can be used for this purpose. Both hydroxyapatite and some natural apatites are effective in reducing the aqueous Pb concentration to below 15 µgl-1 (EPA drinking water limit). The main mechanism in the case of hydroxyapatite is its dissolution and subsequent precipitation of pyromorphites. The mechanism and the effectiveness of natural apatites depend on the type of apatite, its composition, crystallinity and presence of impurities. Apatites are also effective in reducing the Pb concentration in leachets from contaminated soils in the pH range from 6 to 10. The percentage of Pb concentration red...uction is from 60 to 99.9% depending on the type of contamination and type of apatite amendment applied. These data suggest that apatites have potential to provide cost-effective in situ Pb immobilization.
Кључне речи:
Contamination remediation / Environmental protection / Hydroxyapatite / Lead / Natural apatiteИзвор:
Chemical Industry & Chemical Engineering Quarterly, 2001, 7, 1, 114-119Издавач:
- Association of the Chemical Engineers of Serbia
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Kaluđerović, Tatjana AU - Duduković, Aleksandar AU - Raičević, Slavica PY - 2001 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/347 AB - Lead contamination is an environmental concern due to its effect on human health. One of the ways of remediating lead contamination is the in situ stabilization of this heavy metal. This can be achieved by converting different types of lead species into Pb-phosphates (pyromorphites), which are among the least soluble Pb-bearing solids. Synthetic hydroxyapatite (Ca5(PO4)3OH) and natural apatite can be used for this purpose. Both hydroxyapatite and some natural apatites are effective in reducing the aqueous Pb concentration to below 15 µgl-1 (EPA drinking water limit). The main mechanism in the case of hydroxyapatite is its dissolution and subsequent precipitation of pyromorphites. The mechanism and the effectiveness of natural apatites depend on the type of apatite, its composition, crystallinity and presence of impurities. Apatites are also effective in reducing the Pb concentration in leachets from contaminated soils in the pH range from 6 to 10. The percentage of Pb concentration reduction is from 60 to 99.9% depending on the type of contamination and type of apatite amendment applied. These data suggest that apatites have potential to provide cost-effective in situ Pb immobilization. PB - Association of the Chemical Engineers of Serbia T2 - Chemical Industry & Chemical Engineering Quarterly T1 - Remediation of environment contaminated by lead using synthetic and natural apatites T1 - Stabilizacija zagađenja olovom korišćenjem sintetičkih i prirodnih apatita EP - 119 IS - 1 SP - 114 VL - 7 UR - https://hdl.handle.net/21.15107/rcub_technorep_347 ER -
@article{ author = "Kaluđerović, Tatjana and Duduković, Aleksandar and Raičević, Slavica", year = "2001", abstract = "Lead contamination is an environmental concern due to its effect on human health. One of the ways of remediating lead contamination is the in situ stabilization of this heavy metal. This can be achieved by converting different types of lead species into Pb-phosphates (pyromorphites), which are among the least soluble Pb-bearing solids. Synthetic hydroxyapatite (Ca5(PO4)3OH) and natural apatite can be used for this purpose. Both hydroxyapatite and some natural apatites are effective in reducing the aqueous Pb concentration to below 15 µgl-1 (EPA drinking water limit). The main mechanism in the case of hydroxyapatite is its dissolution and subsequent precipitation of pyromorphites. The mechanism and the effectiveness of natural apatites depend on the type of apatite, its composition, crystallinity and presence of impurities. Apatites are also effective in reducing the Pb concentration in leachets from contaminated soils in the pH range from 6 to 10. The percentage of Pb concentration reduction is from 60 to 99.9% depending on the type of contamination and type of apatite amendment applied. These data suggest that apatites have potential to provide cost-effective in situ Pb immobilization.", publisher = "Association of the Chemical Engineers of Serbia", journal = "Chemical Industry & Chemical Engineering Quarterly", title = "Remediation of environment contaminated by lead using synthetic and natural apatites, Stabilizacija zagađenja olovom korišćenjem sintetičkih i prirodnih apatita", pages = "119-114", number = "1", volume = "7", url = "https://hdl.handle.net/21.15107/rcub_technorep_347" }
Kaluđerović, T., Duduković, A.,& Raičević, S.. (2001). Remediation of environment contaminated by lead using synthetic and natural apatites. in Chemical Industry & Chemical Engineering Quarterly Association of the Chemical Engineers of Serbia., 7(1), 114-119. https://hdl.handle.net/21.15107/rcub_technorep_347
Kaluđerović T, Duduković A, Raičević S. Remediation of environment contaminated by lead using synthetic and natural apatites. in Chemical Industry & Chemical Engineering Quarterly. 2001;7(1):114-119. https://hdl.handle.net/21.15107/rcub_technorep_347 .
Kaluđerović, Tatjana, Duduković, Aleksandar, Raičević, Slavica, "Remediation of environment contaminated by lead using synthetic and natural apatites" in Chemical Industry & Chemical Engineering Quarterly, 7, no. 1 (2001):114-119, https://hdl.handle.net/21.15107/rcub_technorep_347 .