Seawater zinc/polypyrrole-air cell possessing multifunctional charge-discharge characteristics
Authorized Users Only
2017
Authors
Al-Eggiely, Ali H.Alguail, Alsadek A.
Gvozdenović, Milica
Jugović, Branimir
Grgur, Branimir
Article (Published version)
Metadata
Show full item recordAbstract
An environmentally friendly cell using polypyrrole-air regenerative cathode and zinc as anode is investigated in the 3% sodium chloride solution. The cell can operate in different charge and discharge mode. Polypyrrole can be reoxidized (doped) with chloride anions either by using dissolved oxygen or by an external power supply, e.g., small photovoltaic cell. In that way, after discharge, capacity retaining can be achieved by using seawater as the electrolyte. During low discharge rate, the delicate balance between solid state diffusion-controlled dedoping and chemical oxidation of polypyrrole produced by hydrogen peroxide is achieved, generating stable voltage plateau. The cell is proposed to operate as a power supply for different sensor devices in two modes. In the low discharge mode (10-20 mA g(-1)), it can be used for data acquisition, and at the fast discharge mode (up to 2 A g(-1)) for collecting data transmission.
Keywords:
Conducting polymers / Air regenerative cathode / Immersion batteries / Metal-air batterySource:
Journal of Solid State Electrochemistry, 2017, 21, 10, 2769-2777Publisher:
- Springer, New York
Funding / projects:
- Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-MESTD-Basic Research (BR or ON)-172046)
DOI: 10.1007/s10008-017-3597-0
ISSN: 1432-8488
WoS: 000410749000002
Scopus: 2-s2.0-85018805863
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Al-Eggiely, Ali H. AU - Alguail, Alsadek A. AU - Gvozdenović, Milica AU - Jugović, Branimir AU - Grgur, Branimir PY - 2017 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3540 AB - An environmentally friendly cell using polypyrrole-air regenerative cathode and zinc as anode is investigated in the 3% sodium chloride solution. The cell can operate in different charge and discharge mode. Polypyrrole can be reoxidized (doped) with chloride anions either by using dissolved oxygen or by an external power supply, e.g., small photovoltaic cell. In that way, after discharge, capacity retaining can be achieved by using seawater as the electrolyte. During low discharge rate, the delicate balance between solid state diffusion-controlled dedoping and chemical oxidation of polypyrrole produced by hydrogen peroxide is achieved, generating stable voltage plateau. The cell is proposed to operate as a power supply for different sensor devices in two modes. In the low discharge mode (10-20 mA g(-1)), it can be used for data acquisition, and at the fast discharge mode (up to 2 A g(-1)) for collecting data transmission. PB - Springer, New York T2 - Journal of Solid State Electrochemistry T1 - Seawater zinc/polypyrrole-air cell possessing multifunctional charge-discharge characteristics EP - 2777 IS - 10 SP - 2769 VL - 21 DO - 10.1007/s10008-017-3597-0 ER -
@article{ author = "Al-Eggiely, Ali H. and Alguail, Alsadek A. and Gvozdenović, Milica and Jugović, Branimir and Grgur, Branimir", year = "2017", abstract = "An environmentally friendly cell using polypyrrole-air regenerative cathode and zinc as anode is investigated in the 3% sodium chloride solution. The cell can operate in different charge and discharge mode. Polypyrrole can be reoxidized (doped) with chloride anions either by using dissolved oxygen or by an external power supply, e.g., small photovoltaic cell. In that way, after discharge, capacity retaining can be achieved by using seawater as the electrolyte. During low discharge rate, the delicate balance between solid state diffusion-controlled dedoping and chemical oxidation of polypyrrole produced by hydrogen peroxide is achieved, generating stable voltage plateau. The cell is proposed to operate as a power supply for different sensor devices in two modes. In the low discharge mode (10-20 mA g(-1)), it can be used for data acquisition, and at the fast discharge mode (up to 2 A g(-1)) for collecting data transmission.", publisher = "Springer, New York", journal = "Journal of Solid State Electrochemistry", title = "Seawater zinc/polypyrrole-air cell possessing multifunctional charge-discharge characteristics", pages = "2777-2769", number = "10", volume = "21", doi = "10.1007/s10008-017-3597-0" }
Al-Eggiely, A. H., Alguail, A. A., Gvozdenović, M., Jugović, B.,& Grgur, B.. (2017). Seawater zinc/polypyrrole-air cell possessing multifunctional charge-discharge characteristics. in Journal of Solid State Electrochemistry Springer, New York., 21(10), 2769-2777. https://doi.org/10.1007/s10008-017-3597-0
Al-Eggiely AH, Alguail AA, Gvozdenović M, Jugović B, Grgur B. Seawater zinc/polypyrrole-air cell possessing multifunctional charge-discharge characteristics. in Journal of Solid State Electrochemistry. 2017;21(10):2769-2777. doi:10.1007/s10008-017-3597-0 .
Al-Eggiely, Ali H., Alguail, Alsadek A., Gvozdenović, Milica, Jugović, Branimir, Grgur, Branimir, "Seawater zinc/polypyrrole-air cell possessing multifunctional charge-discharge characteristics" in Journal of Solid State Electrochemistry, 21, no. 10 (2017):2769-2777, https://doi.org/10.1007/s10008-017-3597-0 . .