The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid)
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2017
Authors
Jokić, BojanDžunuzović, Enis
Grgur, Branimir
Jugović, Branimir
Trišović, Tomislav
Stevanović, Jasmina
Gvozdenović, Milica
Article (Published version)
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Show full item recordAbstract
Poly(aniline-co-(m-aminobenzoic acid)) was synthesized electrochemically at graphite electrode under galvanostatic conditions. Aqueous electrolyte for synthesis was consisted of HCl and different amount of aniline and m-aminobenzoic acid. The presence of the meta positioned carboxylic group in m-aminobenzoic acid influenced higher co-polymerization potential, different morphology and electrochemical behavior of copolymers compared to polyaniline. Electrochemical activity is achieved by proton exchange in neutral environment that can result in a faster charge/discharge process, which is in the case of PANI limited by slow anion exchange, making this material promising for consideration in super-capacitors and in biological system.
Keywords:
Electrochemical co-polymerization / Cyclic voltammetry / Poly(aniline-co-(m-aminobenzoic acid) / UV-vis spectroscopySource:
Journal of Polymer Research, 2017, 24, 9Publisher:
- Springer, Dordrecht
Funding / projects:
- Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)
DOI: 10.1007/s10965-017-1313-5
ISSN: 1022-9760
WoS: 000408478900001
Scopus: 2-s2.0-85028326537
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Jokić, Bojan AU - Džunuzović, Enis AU - Grgur, Branimir AU - Jugović, Branimir AU - Trišović, Tomislav AU - Stevanović, Jasmina AU - Gvozdenović, Milica PY - 2017 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3579 AB - Poly(aniline-co-(m-aminobenzoic acid)) was synthesized electrochemically at graphite electrode under galvanostatic conditions. Aqueous electrolyte for synthesis was consisted of HCl and different amount of aniline and m-aminobenzoic acid. The presence of the meta positioned carboxylic group in m-aminobenzoic acid influenced higher co-polymerization potential, different morphology and electrochemical behavior of copolymers compared to polyaniline. Electrochemical activity is achieved by proton exchange in neutral environment that can result in a faster charge/discharge process, which is in the case of PANI limited by slow anion exchange, making this material promising for consideration in super-capacitors and in biological system. PB - Springer, Dordrecht T2 - Journal of Polymer Research T1 - The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid) IS - 9 VL - 24 DO - 10.1007/s10965-017-1313-5 ER -
@article{ author = "Jokić, Bojan and Džunuzović, Enis and Grgur, Branimir and Jugović, Branimir and Trišović, Tomislav and Stevanović, Jasmina and Gvozdenović, Milica", year = "2017", abstract = "Poly(aniline-co-(m-aminobenzoic acid)) was synthesized electrochemically at graphite electrode under galvanostatic conditions. Aqueous electrolyte for synthesis was consisted of HCl and different amount of aniline and m-aminobenzoic acid. The presence of the meta positioned carboxylic group in m-aminobenzoic acid influenced higher co-polymerization potential, different morphology and electrochemical behavior of copolymers compared to polyaniline. Electrochemical activity is achieved by proton exchange in neutral environment that can result in a faster charge/discharge process, which is in the case of PANI limited by slow anion exchange, making this material promising for consideration in super-capacitors and in biological system.", publisher = "Springer, Dordrecht", journal = "Journal of Polymer Research", title = "The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid)", number = "9", volume = "24", doi = "10.1007/s10965-017-1313-5" }
Jokić, B., Džunuzović, E., Grgur, B., Jugović, B., Trišović, T., Stevanović, J.,& Gvozdenović, M.. (2017). The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid). in Journal of Polymer Research Springer, Dordrecht., 24(9). https://doi.org/10.1007/s10965-017-1313-5
Jokić B, Džunuzović E, Grgur B, Jugović B, Trišović T, Stevanović J, Gvozdenović M. The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid). in Journal of Polymer Research. 2017;24(9). doi:10.1007/s10965-017-1313-5 .
Jokić, Bojan, Džunuzović, Enis, Grgur, Branimir, Jugović, Branimir, Trišović, Tomislav, Stevanović, Jasmina, Gvozdenović, Milica, "The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid)" in Journal of Polymer Research, 24, no. 9 (2017), https://doi.org/10.1007/s10965-017-1313-5 . .