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dc.creatorRadovanović, Lidija
dc.creatorRogan, Jelena
dc.creatorPoleti, Dejan
dc.creatorRodić, Marko
dc.creatorJaglicić, Zvonko
dc.date.accessioned2021-03-10T13:25:00Z
dc.date.available2021-03-10T13:25:00Z
dc.date.issued2017
dc.identifier.issn0352-5139
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/3602
dc.description.abstractA terephthalate-bridged heteronuclear Cu(II)-Mn(II) complex [Cu2Mn(dipya)(2)(tpht)(3)](n), I, where dipya is 2,2'-dipyridylamine and tpht is the anion of 1,4-benzenedicarboxylic (terephthalic, H(2)tpht) acid was synthesized under hydrothermal conditions. The obtained complex I was characterized by a single-crystal X-ray diffraction, FTIR spectroscopy, TG/DSC analysis and magnetic measurements. The Cu(II) and Mn(II) metal centers adopt distorted octahedral geometry and they are linked by bridging tpht ligands. Two crystallographically different tpht anions are coordinated as tridentate and hexadentate ligands forming two-dimensional layers. The layers are interconnected by hydrogen bonds and additionally stabilized by non-covalent C-H center dot center dot center dot pi p interactions. The measurements of magnetic susceptibility proved that I is an almost perfect paramagnet.en
dc.publisherSrpsko hemijsko društvo, Beograd
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45007/RS//
dc.relationSlovenian Research AgencySlovenian Research Agency - Slovenia [P2-0348]
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.sourceJournal of the Serbian Chemical Society
dc.subjectheterometallic complexen
dc.subjectcrystal structureen
dc.subjectCu(II)en
dc.subjectMn(II)en
dc.subject1,4-benzenedicarboxylateen
dc.subjectmagnetic propertiesen
dc.titleA terephthalate-bridged two-dimensional heteronuclear Cu(II)-Mn(II) complex with a terminal 2,2 '-dipyridylamine liganden
dc.typearticle
dc.rights.licenseBY-NC-ND
dc.citation.epage1258
dc.citation.issue11
dc.citation.other82(11): 1247-1258
dc.citation.rankM23
dc.citation.spage1247
dc.citation.volume82
dc.identifier.doi10.2298/JSC170425086R
dc.identifier.fulltexthttp://TechnoRep.tmf.bg.ac.rs/bitstream/id/1451/3599.pdf
dc.identifier.rcubconv_5458
dc.identifier.scopus2-s2.0-85037622456
dc.identifier.wos000417845500004
dc.type.versionpublishedVersion


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