Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram
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A new Bi-rich part of Bi2O3-PbO phase diagram was determined using differential thermal analysis and X-ray powder diffraction techniques. Four solid solutions, alpha-Bi2O3, gamma-Bi2O3, d-Bi2O3 and ss(ss)-Bi8Pb5O17, can be distinguished below 37.5 mol % of PbO and one compound, ss(2)-Bi8Pb5O17. Two of them, d-Bi2O3 and ss(ss)-Bi8Pb5O17 are high-temperature phases. The large field of gamma-Bi2O3 stability was implemented making the crucial difference comparing to phase diagrams from the Bi2O3-PbO system published so far.
Кључне речи:
Bi2O3 / PbO / phase diagramИзвор:
Journal of the Serbian Chemical Society, 2017, 82, 12, 1433-1444Издавач:
- Srpsko hemijsko društvo, Beograd
Финансирање / пројекти:
- 0-3D наноструктуре за примену у електроници и обновљивим изворима енергије: синтеза, карактеризација и процесирање (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45007)
DOI: 10.2298/JSC170711111D
ISSN: 0352-5139
WoS: 000419391700009
Scopus: 2-s2.0-85040035518
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Dapčević, Aleksandra AU - Poleti, Dejan AU - Karanović, Ljiljana AU - Miladinović, Jelena PY - 2017 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3642 AB - A new Bi-rich part of Bi2O3-PbO phase diagram was determined using differential thermal analysis and X-ray powder diffraction techniques. Four solid solutions, alpha-Bi2O3, gamma-Bi2O3, d-Bi2O3 and ss(ss)-Bi8Pb5O17, can be distinguished below 37.5 mol % of PbO and one compound, ss(2)-Bi8Pb5O17. Two of them, d-Bi2O3 and ss(ss)-Bi8Pb5O17 are high-temperature phases. The large field of gamma-Bi2O3 stability was implemented making the crucial difference comparing to phase diagrams from the Bi2O3-PbO system published so far. PB - Srpsko hemijsko društvo, Beograd T2 - Journal of the Serbian Chemical Society T1 - Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram EP - 1444 IS - 12 SP - 1433 VL - 82 DO - 10.2298/JSC170711111D ER -
@article{ author = "Dapčević, Aleksandra and Poleti, Dejan and Karanović, Ljiljana and Miladinović, Jelena", year = "2017", abstract = "A new Bi-rich part of Bi2O3-PbO phase diagram was determined using differential thermal analysis and X-ray powder diffraction techniques. Four solid solutions, alpha-Bi2O3, gamma-Bi2O3, d-Bi2O3 and ss(ss)-Bi8Pb5O17, can be distinguished below 37.5 mol % of PbO and one compound, ss(2)-Bi8Pb5O17. Two of them, d-Bi2O3 and ss(ss)-Bi8Pb5O17 are high-temperature phases. The large field of gamma-Bi2O3 stability was implemented making the crucial difference comparing to phase diagrams from the Bi2O3-PbO system published so far.", publisher = "Srpsko hemijsko društvo, Beograd", journal = "Journal of the Serbian Chemical Society", title = "Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram", pages = "1444-1433", number = "12", volume = "82", doi = "10.2298/JSC170711111D" }
Dapčević, A., Poleti, D., Karanović, L.,& Miladinović, J.. (2017). Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram. in Journal of the Serbian Chemical Society Srpsko hemijsko društvo, Beograd., 82(12), 1433-1444. https://doi.org/10.2298/JSC170711111D
Dapčević A, Poleti D, Karanović L, Miladinović J. Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram. in Journal of the Serbian Chemical Society. 2017;82(12):1433-1444. doi:10.2298/JSC170711111D .
Dapčević, Aleksandra, Poleti, Dejan, Karanović, Ljiljana, Miladinović, Jelena, "Investigation of Bi2O3-rich part of Bi2O3-PbO phase diagram" in Journal of the Serbian Chemical Society, 82, no. 12 (2017):1433-1444, https://doi.org/10.2298/JSC170711111D . .