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dc.creatorAntonović, Dušan
dc.creatorVajs, Vlatka
dc.creatorStojanović, N.D.
dc.creatorNikolić, A.D.
dc.creatorPetrović, Slobodan
dc.date.accessioned2021-03-10T09:35:02Z
dc.date.available2021-03-10T09:35:02Z
dc.date.issued1992
dc.identifier.issn0022-2860
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/38
dc.description.abstractAs a part of a study on the structural characteristics of some new various N-alkyl-N-substituted 2-phenylacetamides the infrared and 1H N.M.R. spectra were obtained and interpreted. The synthesis of a various N-n-propyl-N-alkyl 2-phenylacetamides of the general formula PhCH2CON(nPr)R, wherein R is ethyl, isopropyl, n-butyl, t-butyl and cyclohexyl, were performed. The corresponding mixed secondary amines of the type HNnPrR were obtained by catalytic hydrogenation of the synthetized propylidenealkylamines. The 1H N.M.R. spectra of these unsymmetrically N,N-disubstituted amides have been studied and the peaks have been assigned in each cases to two possible conformational isomers, arising from the lack of free rotation about the C(O)N bond. These results are in accordance with our previous investigation of the structure of N-substituted 2-phenylacetamides.en
dc.publisherElsevier, Amsterdam
dc.relationResearch Fund of Serbia for financial support.
dc.rightsrestrictedAccess
dc.sourceJournal of Molecular Structure
dc.titleConformations in unsymmetrically N-n-propyl-N-substituted 2-phenylacetamidesen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage258
dc.citation.issueC
dc.citation.other266(C): 255-258
dc.citation.rankM23
dc.citation.spage255
dc.citation.volume266
dc.identifier.doi10.1016/0022-2860(92)80075-S
dc.identifier.pmid
dc.identifier.rcubconv_7466
dc.identifier.scopus2-s2.0-0039839433
dc.type.versionpublishedVersion


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