Change in structural, ferroelectric, and magnetic properties of bismuth ferrite induced by doping with gadolinium
Samo za registrovane korisnike
2019
Autori
Luković-Golić, DanijelaRadojković, Aleksandar
Dapčević, Aleksandra
Pajić, Damir
Dragović, Jure
Torić, Filip
Ćirković, Jovana
Branković, Goran
Branković, Zorica
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Bismuth ferrite, BiFeO3, was doped with a wide range of concentrations (0-30%) of Gd in order to investigate structural, ferroelectric, and magnetic properties and their correlation. Powder samples of Bi1-xGdxFeO3 (x = 0.00-0.30) were prepared using the hydro-evaporation synthesis method. Sintering process at 870 degrees C for 6 h of as-prepared, Gd doped BiFeO3 powders resulted in ceramic samples with relative densities in the range of (74-86) %. XRD analysis revealed that Bi1-xGdxFeO3 samples (x = 0.00-0.09) crystallized in rhombohedral phase; Bi1-xGdxFeO3 samples (x = 0.10-0.20) contained both rhombohedral and orthorhombic phases, while Bi1-xGdxFeO3 (x = 0.30) sample contained only the orthorhombic phase. The structural parameters obtained after Rietveld refinement for single-phase Bi1-xGdxFeO3 ceramic samples and microstructure image analysis were correlated with the results of ferroelectric and magnetic measurements. Bi1-xGdxFeO3 (x = 0.0625, 0.075, 0.09) samples showed improved f...erroelectric properties and reduced leakage current density in comparison with undoped BiFeO3. Gradual increase in Gd content in BiFeO3 led to enhanced magnetic responses and weak ferromagnetic behavior.
Ključne reči:
Perovskites / Ferrites / Sintering / Ferroelectric properties / Magnetic propertiesIzvor:
Ceramics International, 2019, 45, 15, 19158-19165Izdavač:
- Elsevier Sci Ltd, Oxford
Finansiranje / projekti:
- 0-3D nanostrukture za primenu u elektronici i obnovljivim izvorima energije: sinteza, karakterizacija i procesiranje (RS-45007)
- Croatian Science Foundation [UIP-2014-09-8276]
DOI: 10.1016/j.ceramint.2019.06.162
ISSN: 0272-8842
WoS: 000483454200122
Scopus: 2-s2.0-85067441497
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Luković-Golić, Danijela AU - Radojković, Aleksandar AU - Dapčević, Aleksandra AU - Pajić, Damir AU - Dragović, Jure AU - Torić, Filip AU - Ćirković, Jovana AU - Branković, Goran AU - Branković, Zorica PY - 2019 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4079 AB - Bismuth ferrite, BiFeO3, was doped with a wide range of concentrations (0-30%) of Gd in order to investigate structural, ferroelectric, and magnetic properties and their correlation. Powder samples of Bi1-xGdxFeO3 (x = 0.00-0.30) were prepared using the hydro-evaporation synthesis method. Sintering process at 870 degrees C for 6 h of as-prepared, Gd doped BiFeO3 powders resulted in ceramic samples with relative densities in the range of (74-86) %. XRD analysis revealed that Bi1-xGdxFeO3 samples (x = 0.00-0.09) crystallized in rhombohedral phase; Bi1-xGdxFeO3 samples (x = 0.10-0.20) contained both rhombohedral and orthorhombic phases, while Bi1-xGdxFeO3 (x = 0.30) sample contained only the orthorhombic phase. The structural parameters obtained after Rietveld refinement for single-phase Bi1-xGdxFeO3 ceramic samples and microstructure image analysis were correlated with the results of ferroelectric and magnetic measurements. Bi1-xGdxFeO3 (x = 0.0625, 0.075, 0.09) samples showed improved ferroelectric properties and reduced leakage current density in comparison with undoped BiFeO3. Gradual increase in Gd content in BiFeO3 led to enhanced magnetic responses and weak ferromagnetic behavior. PB - Elsevier Sci Ltd, Oxford T2 - Ceramics International T1 - Change in structural, ferroelectric, and magnetic properties of bismuth ferrite induced by doping with gadolinium EP - 19165 IS - 15 SP - 19158 VL - 45 DO - 10.1016/j.ceramint.2019.06.162 ER -
@article{ author = "Luković-Golić, Danijela and Radojković, Aleksandar and Dapčević, Aleksandra and Pajić, Damir and Dragović, Jure and Torić, Filip and Ćirković, Jovana and Branković, Goran and Branković, Zorica", year = "2019", abstract = "Bismuth ferrite, BiFeO3, was doped with a wide range of concentrations (0-30%) of Gd in order to investigate structural, ferroelectric, and magnetic properties and their correlation. Powder samples of Bi1-xGdxFeO3 (x = 0.00-0.30) were prepared using the hydro-evaporation synthesis method. Sintering process at 870 degrees C for 6 h of as-prepared, Gd doped BiFeO3 powders resulted in ceramic samples with relative densities in the range of (74-86) %. XRD analysis revealed that Bi1-xGdxFeO3 samples (x = 0.00-0.09) crystallized in rhombohedral phase; Bi1-xGdxFeO3 samples (x = 0.10-0.20) contained both rhombohedral and orthorhombic phases, while Bi1-xGdxFeO3 (x = 0.30) sample contained only the orthorhombic phase. The structural parameters obtained after Rietveld refinement for single-phase Bi1-xGdxFeO3 ceramic samples and microstructure image analysis were correlated with the results of ferroelectric and magnetic measurements. Bi1-xGdxFeO3 (x = 0.0625, 0.075, 0.09) samples showed improved ferroelectric properties and reduced leakage current density in comparison with undoped BiFeO3. Gradual increase in Gd content in BiFeO3 led to enhanced magnetic responses and weak ferromagnetic behavior.", publisher = "Elsevier Sci Ltd, Oxford", journal = "Ceramics International", title = "Change in structural, ferroelectric, and magnetic properties of bismuth ferrite induced by doping with gadolinium", pages = "19165-19158", number = "15", volume = "45", doi = "10.1016/j.ceramint.2019.06.162" }
Luković-Golić, D., Radojković, A., Dapčević, A., Pajić, D., Dragović, J., Torić, F., Ćirković, J., Branković, G.,& Branković, Z.. (2019). Change in structural, ferroelectric, and magnetic properties of bismuth ferrite induced by doping with gadolinium. in Ceramics International Elsevier Sci Ltd, Oxford., 45(15), 19158-19165. https://doi.org/10.1016/j.ceramint.2019.06.162
Luković-Golić D, Radojković A, Dapčević A, Pajić D, Dragović J, Torić F, Ćirković J, Branković G, Branković Z. Change in structural, ferroelectric, and magnetic properties of bismuth ferrite induced by doping with gadolinium. in Ceramics International. 2019;45(15):19158-19165. doi:10.1016/j.ceramint.2019.06.162 .
Luković-Golić, Danijela, Radojković, Aleksandar, Dapčević, Aleksandra, Pajić, Damir, Dragović, Jure, Torić, Filip, Ćirković, Jovana, Branković, Goran, Branković, Zorica, "Change in structural, ferroelectric, and magnetic properties of bismuth ferrite induced by doping with gadolinium" in Ceramics International, 45, no. 15 (2019):19158-19165, https://doi.org/10.1016/j.ceramint.2019.06.162 . .