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dc.creatorLopičić, Zorica
dc.creatorStojanović, Mirjana
dc.creatorMarković, Smilja
dc.creatorMilojković, Jelena V.
dc.creatorMihajlović, Marija L.
dc.creatorKaluđerović-Radoičić, Tatjana
dc.creatorKijevčanin, Mirjana
dc.date.accessioned2021-03-10T13:57:11Z
dc.date.available2021-03-10T13:57:11Z
dc.date.issued2019
dc.identifier.issn1878-5352
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/4100
dc.description.abstractIn this paper, the character of structural changes induced by different mechanical treatments to Prunus persica stones (PSs), and its subsequent effect on biosorption kinetics of Cu(II) were investigated. PSs were processed in vibratory disk mill (PS-V) and ultra-centrifugal mill (PS-C) and characterized by XRD, BET, SEM and FTIR spectroscopy. It was shown that PS-V was smaller and more reactive with less crystallinity index and hydrogen bond intensity compared to PS-C. In opposite, surface area of the PS-C was bigger than that of the PS-V. The total pore volume was about threefold, while the volume of micro pores was 9.29 times higher in PS-Cs than in PS-Vs. The kinetics of Cu(II) biosorption by both PSs was tested through various kinetic models: pseudo-first and pseudo-second order rate equations, Elovich equation, Boyd model, Weber-Morris and Urano-Tachikawa intraparticle diffusion model. For both sample types, Cu(II) biosorption occurred through combination of intraparticle and film diffusion mechanism, while kinetic results were best described by the pseudo-second order kinetic model. At the same time, the results indicated that together with kinetic rate the biosorption capacity of PS-C (21.20 mg g(-1)) was higher than that of PS-V (16.30 mg g(-1)). Mechanical activation like crushing and grinding will change material particle size, specific surface area and porosity, as well as its crystallinity. However, this paper elucidates that such physical structural changes will impact on heavy metal ions removal efficiency. This investigation suggests that the type of size reduction in lignocellulosic biosorbent preparation plays a very important role in overall biosorption performance, so it should be carefully considered every time when the mechanical treatment of material is necessary to be applied.en
dc.publisherElsevier, Amsterdam
dc.relationinfo:eu-repo/grantAgreement/MESTD/Technological Development (TD or TR)/31003/RS//
dc.rightsopenAccess
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.sourceArabian Journal of Chemistry
dc.subjectLignocellulosesen
dc.subjectPeach stoneen
dc.subjectMechanical treatmenten
dc.subjectModificationen
dc.subjectCopperen
dc.subjectBiosorption kineticsen
dc.titleEffects of different mechanical treatments on structural changes of lignocellulosic waste biomass and subsequent Cu(II) removal kineticsen
dc.typearticle
dc.rights.licenseBY-NC-ND
dc.citation.epage4103
dc.citation.issue8
dc.citation.other12(8): 4091-4103
dc.citation.rankM21
dc.citation.spage4091
dc.citation.volume12
dc.identifier.doi10.1016/j.arabjc.2016.04.005
dc.identifier.fulltexthttp://TechnoRep.tmf.bg.ac.rs/bitstream/id/1828/4097.pdf
dc.identifier.rcubconv_6023
dc.identifier.scopus2-s2.0-84964679930
dc.identifier.wos000504900300221
dc.type.versionpublishedVersion


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