Osmotic coefficient of the ZnSO4(aq) at T=298.15 K
Abstract
The osmotic coefficient of ZnSO4(aq) has been measured at T = 298.15 K by the iso-piestic method, in the range of molalities from 1.3 to 3.0 mol . kg(-1), with KCl(aq) as the reference solution. Experimental data of osmotic coefficient were treated to determine the ionic interaction parameters in Pitzer's equation and equation of Clegg-Pitzer-Brimblecombe. These equations were used to calculate the activity coefficient of ZnSO4 at T = 298. 15 K.
Keywords:
isopiestic measurements / zinc sulfate / osmotic coefficient / activity coefficient / Pitzer's equation / Clegg-Pitzer-Brimblecombe equationSource:
Journal of Chemical Thermodynamics, 2002, 34, 11, 1769-1776Publisher:
- Academic Press Ltd- Elsevier Science Ltd, London
DOI: 10.1016/S0021-9614(02)00164-7
ISSN: 0021-9614
WoS: 000179874300004
Scopus: 2-s2.0-0036026886
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Miladinović, Jelena AU - Todorović, M. AU - Ninković, Rozalija PY - 2002 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/435 AB - The osmotic coefficient of ZnSO4(aq) has been measured at T = 298.15 K by the iso-piestic method, in the range of molalities from 1.3 to 3.0 mol . kg(-1), with KCl(aq) as the reference solution. Experimental data of osmotic coefficient were treated to determine the ionic interaction parameters in Pitzer's equation and equation of Clegg-Pitzer-Brimblecombe. These equations were used to calculate the activity coefficient of ZnSO4 at T = 298. 15 K. PB - Academic Press Ltd- Elsevier Science Ltd, London T2 - Journal of Chemical Thermodynamics T1 - Osmotic coefficient of the ZnSO4(aq) at T=298.15 K EP - 1776 IS - 11 SP - 1769 VL - 34 DO - 10.1016/S0021-9614(02)00164-7 ER -
@article{ author = "Miladinović, Jelena and Todorović, M. and Ninković, Rozalija", year = "2002", abstract = "The osmotic coefficient of ZnSO4(aq) has been measured at T = 298.15 K by the iso-piestic method, in the range of molalities from 1.3 to 3.0 mol . kg(-1), with KCl(aq) as the reference solution. Experimental data of osmotic coefficient were treated to determine the ionic interaction parameters in Pitzer's equation and equation of Clegg-Pitzer-Brimblecombe. These equations were used to calculate the activity coefficient of ZnSO4 at T = 298. 15 K.", publisher = "Academic Press Ltd- Elsevier Science Ltd, London", journal = "Journal of Chemical Thermodynamics", title = "Osmotic coefficient of the ZnSO4(aq) at T=298.15 K", pages = "1776-1769", number = "11", volume = "34", doi = "10.1016/S0021-9614(02)00164-7" }
Miladinović, J., Todorović, M.,& Ninković, R.. (2002). Osmotic coefficient of the ZnSO4(aq) at T=298.15 K. in Journal of Chemical Thermodynamics Academic Press Ltd- Elsevier Science Ltd, London., 34(11), 1769-1776. https://doi.org/10.1016/S0021-9614(02)00164-7
Miladinović J, Todorović M, Ninković R. Osmotic coefficient of the ZnSO4(aq) at T=298.15 K. in Journal of Chemical Thermodynamics. 2002;34(11):1769-1776. doi:10.1016/S0021-9614(02)00164-7 .
Miladinović, Jelena, Todorović, M., Ninković, Rozalija, "Osmotic coefficient of the ZnSO4(aq) at T=298.15 K" in Journal of Chemical Thermodynamics, 34, no. 11 (2002):1769-1776, https://doi.org/10.1016/S0021-9614(02)00164-7 . .