Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O
Samo za registrovane korisnike
2002
Autori
Karanović, LjiljanaPoleti, Dejan
Rogan, Jelena
Bogdanović, Goran A.
Spasojević-de Bire, Anne
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The title complexes, catena-poly[[aqua(1,10-phenanthroline- kappa(2)N,N')cobalt(II)]-mu-benzene-1,4-dicarboxylato-kappa(2)O(1):O-4], [Co(C8H4O4)(C12H8N2)(H2O)], (I), and catena-poly[[[(di-2-pyridyl-kappaN-amine)copper(II)]-mu-benzene-1,4-dicarboxylato- kappa(4)O(1), O-1' :O-4,O-4'] hydrate], [Cu(C8H4O4)(C10H9N3)].H2O, (II), take the form of zigzag chains, with the 1,4-benzenedicarboxylate ion acting as an amphimonodentate ligand in (I) and a bis-bidentate ligand in (II). The Co-II ion in (I) is five-coordinate and has a distorted trigonal-bipyramidal geometry. The Cu-II ion in (II) is in a very distorted octahedral 4+2 environment, with the octahedron elongated along the trans O-Cu-O bonds and with a trans O-Cu-O angle of only 137.22 (8)degrees.
Izvor:
Acta Crystallographica Section C-Structural Chemistry, 2002, 58, m275-m279Izdavač:
- Int Union Crystallography, Chester
DOI: 10.1107/S0108270102004341
ISSN: 2053-2296
PubMed: 11983964
WoS: 000175316400008
Scopus: 2-s2.0-0036588028
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Karanović, Ljiljana AU - Poleti, Dejan AU - Rogan, Jelena AU - Bogdanović, Goran A. AU - Spasojević-de Bire, Anne PY - 2002 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/437 AB - The title complexes, catena-poly[[aqua(1,10-phenanthroline- kappa(2)N,N')cobalt(II)]-mu-benzene-1,4-dicarboxylato-kappa(2)O(1):O-4], [Co(C8H4O4)(C12H8N2)(H2O)], (I), and catena-poly[[[(di-2-pyridyl-kappaN-amine)copper(II)]-mu-benzene-1,4-dicarboxylato- kappa(4)O(1), O-1' :O-4,O-4'] hydrate], [Cu(C8H4O4)(C10H9N3)].H2O, (II), take the form of zigzag chains, with the 1,4-benzenedicarboxylate ion acting as an amphimonodentate ligand in (I) and a bis-bidentate ligand in (II). The Co-II ion in (I) is five-coordinate and has a distorted trigonal-bipyramidal geometry. The Cu-II ion in (II) is in a very distorted octahedral 4+2 environment, with the octahedron elongated along the trans O-Cu-O bonds and with a trans O-Cu-O angle of only 137.22 (8)degrees. PB - Int Union Crystallography, Chester T2 - Acta Crystallographica Section C-Structural Chemistry T1 - Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O EP - m279 SP - m275 VL - 58 DO - 10.1107/S0108270102004341 ER -
@article{ author = "Karanović, Ljiljana and Poleti, Dejan and Rogan, Jelena and Bogdanović, Goran A. and Spasojević-de Bire, Anne", year = "2002", abstract = "The title complexes, catena-poly[[aqua(1,10-phenanthroline- kappa(2)N,N')cobalt(II)]-mu-benzene-1,4-dicarboxylato-kappa(2)O(1):O-4], [Co(C8H4O4)(C12H8N2)(H2O)], (I), and catena-poly[[[(di-2-pyridyl-kappaN-amine)copper(II)]-mu-benzene-1,4-dicarboxylato- kappa(4)O(1), O-1' :O-4,O-4'] hydrate], [Cu(C8H4O4)(C10H9N3)].H2O, (II), take the form of zigzag chains, with the 1,4-benzenedicarboxylate ion acting as an amphimonodentate ligand in (I) and a bis-bidentate ligand in (II). The Co-II ion in (I) is five-coordinate and has a distorted trigonal-bipyramidal geometry. The Cu-II ion in (II) is in a very distorted octahedral 4+2 environment, with the octahedron elongated along the trans O-Cu-O bonds and with a trans O-Cu-O angle of only 137.22 (8)degrees.", publisher = "Int Union Crystallography, Chester", journal = "Acta Crystallographica Section C-Structural Chemistry", title = "Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O", pages = "m279-m275", volume = "58", doi = "10.1107/S0108270102004341" }
Karanović, L., Poleti, D., Rogan, J., Bogdanović, G. A.,& Spasojević-de Bire, A.. (2002). Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O. in Acta Crystallographica Section C-Structural Chemistry Int Union Crystallography, Chester., 58, m275-m279. https://doi.org/10.1107/S0108270102004341
Karanović L, Poleti D, Rogan J, Bogdanović GA, Spasojević-de Bire A. Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O. in Acta Crystallographica Section C-Structural Chemistry. 2002;58:m275-m279. doi:10.1107/S0108270102004341 .
Karanović, Ljiljana, Poleti, Dejan, Rogan, Jelena, Bogdanović, Goran A., Spasojević-de Bire, Anne, "Comparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2O" in Acta Crystallographica Section C-Structural Chemistry, 58 (2002):m275-m279, https://doi.org/10.1107/S0108270102004341 . .