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dc.creatorKaranović, Ljiljana
dc.creatorPoleti, Dejan
dc.creatorRogan, Jelena
dc.creatorBogdanović, Goran A.
dc.creatorSpasojević-de Bire, Anne
dc.date.accessioned2021-03-10T10:00:51Z
dc.date.available2021-03-10T10:00:51Z
dc.date.issued2002
dc.identifier.issn2053-2296
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/437
dc.description.abstractThe title complexes, catena-poly[[aqua(1,10-phenanthroline- kappa(2)N,N')cobalt(II)]-mu-benzene-1,4-dicarboxylato-kappa(2)O(1):O-4], [Co(C8H4O4)(C12H8N2)(H2O)], (I), and catena-poly[[[(di-2-pyridyl-kappaN-amine)copper(II)]-mu-benzene-1,4-dicarboxylato- kappa(4)O(1), O-1' :O-4,O-4'] hydrate], [Cu(C8H4O4)(C10H9N3)].H2O, (II), take the form of zigzag chains, with the 1,4-benzenedicarboxylate ion acting as an amphimonodentate ligand in (I) and a bis-bidentate ligand in (II). The Co-II ion in (I) is five-coordinate and has a distorted trigonal-bipyramidal geometry. The Cu-II ion in (II) is in a very distorted octahedral 4+2 environment, with the octahedron elongated along the trans O-Cu-O bonds and with a trans O-Cu-O angle of only 137.22 (8)degrees.en
dc.publisherInt Union Crystallography, Chester
dc.rightsrestrictedAccess
dc.sourceActa Crystallographica Section C-Structural Chemistry
dc.titleComparison of two polymeric transition metal complexes with 1,4-benzenedicarboxylate ions as bridging ligands, [Co(C8H4O4)(C12H8N2)(H2O)] and [Cu(C8H4O4)(C10H9N3)] center dot H2Oen
dc.typearticle
dc.rights.licenseARR
dc.citation.epagem279
dc.citation.other58: m275-m279
dc.citation.spagem275
dc.citation.volume58
dc.identifier.doi10.1107/S0108270102004341
dc.identifier.pmid11983964
dc.identifier.rcubconv_2205
dc.identifier.scopus2-s2.0-0036588028
dc.identifier.wos000175316400008
dc.type.versionpublishedVersion


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