Removal of Estrone, 17 beta-Estradiol, and 17 alpha-Ethinylestradiol from Water by Adsorption onto Chemically Modified Activated Carbon Cloths
Аутори
Prokić, DanijelaVukčević, Marija
Kalijadis, Ana
Maletić, Marina
Babić, Biljana M.
Đurkić, Tatjana
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
This paper explores the applicability of unmodified and chemically modified activated carbon cloths (ACCs) for the removal of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water. In order to examine the influence of surface properties on hormone adsorption, chemical modification of ACCs with HNO3, HCl, or KOH was employed. Applied treatments increased the specific surface area and changed the content of oxygen functional groups. Increased content of acidic surface oxygen functionalities enhanced adsorption efficiency up to 30 % and had a more dominant influence on adsorption capacity than specific surface area. Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol followed pseudo-second-order kinetic model, while the equilibrium adsorption data fitted well with the Freundlich isotherm model. Calculated mean sorption energy values of 1.4475, 1.3387, and 1.0541 kJ/mol, for E1, E2, and EE2 respectively, indicated that removal of selected hormones was dom...inated by physisorption mechanism. Obtained Langmuir adsorption capacities, 12.34, 12.66, and 11.11 mg/g for estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol, respectively, as well as convenience of manipulation, recommend activated carbon cloth modified with HNO3 as an efficient adsorbent for removing estrogen hormones from the water.
Кључне речи:
Activated carbon cloth / Surface properties / Adsorption / Estrogenic hormonesИзвор:
Fibers and Polymers, 2020, 21, 10, 2263-2274Издавач:
- Korean Fiber Soc, Seoul
Финансирање / пројекти:
- Ministry of Education, Science and Technological Development of the Republic of Serbia
DOI: 10.1007/s12221-020-9758-2
ISSN: 1229-9197
WoS: 000583056800014
Scopus: 2-s2.0-85094633246
Колекције
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Prokić, Danijela AU - Vukčević, Marija AU - Kalijadis, Ana AU - Maletić, Marina AU - Babić, Biljana M. AU - Đurkić, Tatjana PY - 2020 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4450 AB - This paper explores the applicability of unmodified and chemically modified activated carbon cloths (ACCs) for the removal of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water. In order to examine the influence of surface properties on hormone adsorption, chemical modification of ACCs with HNO3, HCl, or KOH was employed. Applied treatments increased the specific surface area and changed the content of oxygen functional groups. Increased content of acidic surface oxygen functionalities enhanced adsorption efficiency up to 30 % and had a more dominant influence on adsorption capacity than specific surface area. Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol followed pseudo-second-order kinetic model, while the equilibrium adsorption data fitted well with the Freundlich isotherm model. Calculated mean sorption energy values of 1.4475, 1.3387, and 1.0541 kJ/mol, for E1, E2, and EE2 respectively, indicated that removal of selected hormones was dominated by physisorption mechanism. Obtained Langmuir adsorption capacities, 12.34, 12.66, and 11.11 mg/g for estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol, respectively, as well as convenience of manipulation, recommend activated carbon cloth modified with HNO3 as an efficient adsorbent for removing estrogen hormones from the water. PB - Korean Fiber Soc, Seoul T2 - Fibers and Polymers T1 - Removal of Estrone, 17 beta-Estradiol, and 17 alpha-Ethinylestradiol from Water by Adsorption onto Chemically Modified Activated Carbon Cloths EP - 2274 IS - 10 SP - 2263 VL - 21 DO - 10.1007/s12221-020-9758-2 ER -
@article{ author = "Prokić, Danijela and Vukčević, Marija and Kalijadis, Ana and Maletić, Marina and Babić, Biljana M. and Đurkić, Tatjana", year = "2020", abstract = "This paper explores the applicability of unmodified and chemically modified activated carbon cloths (ACCs) for the removal of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol from water. In order to examine the influence of surface properties on hormone adsorption, chemical modification of ACCs with HNO3, HCl, or KOH was employed. Applied treatments increased the specific surface area and changed the content of oxygen functional groups. Increased content of acidic surface oxygen functionalities enhanced adsorption efficiency up to 30 % and had a more dominant influence on adsorption capacity than specific surface area. Adsorption of estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol followed pseudo-second-order kinetic model, while the equilibrium adsorption data fitted well with the Freundlich isotherm model. Calculated mean sorption energy values of 1.4475, 1.3387, and 1.0541 kJ/mol, for E1, E2, and EE2 respectively, indicated that removal of selected hormones was dominated by physisorption mechanism. Obtained Langmuir adsorption capacities, 12.34, 12.66, and 11.11 mg/g for estrone, 17 beta-estradiol, and 17 alpha-ethinylestradiol, respectively, as well as convenience of manipulation, recommend activated carbon cloth modified with HNO3 as an efficient adsorbent for removing estrogen hormones from the water.", publisher = "Korean Fiber Soc, Seoul", journal = "Fibers and Polymers", title = "Removal of Estrone, 17 beta-Estradiol, and 17 alpha-Ethinylestradiol from Water by Adsorption onto Chemically Modified Activated Carbon Cloths", pages = "2274-2263", number = "10", volume = "21", doi = "10.1007/s12221-020-9758-2" }
Prokić, D., Vukčević, M., Kalijadis, A., Maletić, M., Babić, B. M.,& Đurkić, T.. (2020). Removal of Estrone, 17 beta-Estradiol, and 17 alpha-Ethinylestradiol from Water by Adsorption onto Chemically Modified Activated Carbon Cloths. in Fibers and Polymers Korean Fiber Soc, Seoul., 21(10), 2263-2274. https://doi.org/10.1007/s12221-020-9758-2
Prokić D, Vukčević M, Kalijadis A, Maletić M, Babić BM, Đurkić T. Removal of Estrone, 17 beta-Estradiol, and 17 alpha-Ethinylestradiol from Water by Adsorption onto Chemically Modified Activated Carbon Cloths. in Fibers and Polymers. 2020;21(10):2263-2274. doi:10.1007/s12221-020-9758-2 .
Prokić, Danijela, Vukčević, Marija, Kalijadis, Ana, Maletić, Marina, Babić, Biljana M., Đurkić, Tatjana, "Removal of Estrone, 17 beta-Estradiol, and 17 alpha-Ethinylestradiol from Water by Adsorption onto Chemically Modified Activated Carbon Cloths" in Fibers and Polymers, 21, no. 10 (2020):2263-2274, https://doi.org/10.1007/s12221-020-9758-2 . .