Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling
Само за регистроване кориснике
2020
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Density, viscosity, and refractive index of four binary mixtures with 1-hexanol are experimentally determined at seven temperatures, in the temperature range from 288.15 to 318.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for applications in flue gas cleaning processes. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and partial and excess partial molar volumes are calculated, correlated with the Redlich-Kister equation, and used for better understanding of molecular interactions between the mixture components. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical applications, modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches and the results are compared with experimental values.
Извор:
Journal of Chemical and Engineering Data, 2020, 65, 6, 3044-3062Издавач:
- Amer Chemical Soc, Washington
Финансирање / пројекти:
- Research Fund of Ministry of Education, Science and Technological Development, Republic of Serbia
- Нови индустријски и еколошки аспекти примене хемијске термодинамике на унапређење хемијских процеса са вишефазним и вишекомпонентним системима (RS-MESTD-Basic Research (BR or ON)-172063)
DOI: 10.1021/acs.jced.0c00083
ISSN: 0021-9568
WoS: 000541740100014
Scopus: 2-s2.0-85085752630
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Živković, Nikola V. AU - Majstorović, Divna AU - Kijevčanin, Mirjana AU - Živković, Emila PY - 2020 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4531 AB - Density, viscosity, and refractive index of four binary mixtures with 1-hexanol are experimentally determined at seven temperatures, in the temperature range from 288.15 to 318.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for applications in flue gas cleaning processes. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and partial and excess partial molar volumes are calculated, correlated with the Redlich-Kister equation, and used for better understanding of molecular interactions between the mixture components. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical applications, modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches and the results are compared with experimental values. PB - Amer Chemical Soc, Washington T2 - Journal of Chemical and Engineering Data T1 - Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling EP - 3062 IS - 6 SP - 3044 VL - 65 DO - 10.1021/acs.jced.0c00083 ER -
@article{ author = "Živković, Nikola V. and Majstorović, Divna and Kijevčanin, Mirjana and Živković, Emila", year = "2020", abstract = "Density, viscosity, and refractive index of four binary mixtures with 1-hexanol are experimentally determined at seven temperatures, in the temperature range from 288.15 to 318.15 K and at atmospheric pressure. The choice of mixtures was based on their potential for applications in flue gas cleaning processes. From experimental data, excess molar volume, viscosity deviation, excess molar Gibbs free energy of activation of viscous flow, deviation in refractive index, and partial and excess partial molar volumes are calculated, correlated with the Redlich-Kister equation, and used for better understanding of molecular interactions between the mixture components. Since the mixtures were investigated both from the theoretical point of view and with the aspect for practical applications, modeling of two key properties, viscosity and excess molar volume, was performed with different models and approaches and the results are compared with experimental values.", publisher = "Amer Chemical Soc, Washington", journal = "Journal of Chemical and Engineering Data", title = "Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling", pages = "3062-3044", number = "6", volume = "65", doi = "10.1021/acs.jced.0c00083" }
Živković, N. V., Majstorović, D., Kijevčanin, M.,& Živković, E.. (2020). Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. in Journal of Chemical and Engineering Data Amer Chemical Soc, Washington., 65(6), 3044-3062. https://doi.org/10.1021/acs.jced.0c00083
Živković NV, Majstorović D, Kijevčanin M, Živković E. Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling. in Journal of Chemical and Engineering Data. 2020;65(6):3044-3062. doi:10.1021/acs.jced.0c00083 .
Živković, Nikola V., Majstorović, Divna, Kijevčanin, Mirjana, Živković, Emila, "Volumetric and Viscometric Study of 1-Hexanol-Based Binary Systems: Experimental Determination and Modeling" in Journal of Chemical and Engineering Data, 65, no. 6 (2020):3044-3062, https://doi.org/10.1021/acs.jced.0c00083 . .