High pressure densities and derived thermodynamic properties of deep eutectic solvents with menthol and saturated fatty acids
Samo za registrovane korisnike
2021
Autori
Sas, Olalla G.Ivaniš, Gorica
Kijevčanin, Mirjana
Gonzalez, Begona
Dominguez, Angeles
Radović, Ivona
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Densities of four Deep Eutectic Solvents (DESs) based on menthol and organic acids (menthol:octanoic acid (1:1), menthol:decanoic acid (1:1), menthol:dodecanoic acid (2:1) and decanoic acid:octanoic acid (1:3)) were measured at high pressures (0.1 to 60) MPa and several temperatures (293.15 to 413.15) K. Tammann-Tait equation was used to model the experimental density data; the average absolute percentage deviations between calculated and experimental data were less or equal 0.012 %. The influence of the temperature and pressure on the derived volumetric properties: isothermal compressibility (k(T)), isobaric thermal expansivity (alpha(p)), internal pressure (p(int)) and difference between heat capacity at constant pressure (c(p)) and constant volume (c(v)) was analysed. Considering the experimental results, it is possible to observe that deep eutectic solvent formed by linear organic acids presents higher density values than those formed by menthol, being the densest the solvent forme...d by dodecanoic and octanoic acid. Attending to the derived volumetric properties in general, isothermal compressibility and isobaric thermal expansivity increase as temperature increases and decrease with pressure for all studied systems, being the octanoic acid based DESs slightly more compressible than the other studied DESs.
Ključne reči:
Deep eutectic solvents / High pressure density / Menthol / Fatty acidsIzvor:
Journal of Chemical Thermodynamics, 2021, 162Finansiranje / projekti:
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200135 (Univerzitet u Beogradu, Tehnološko-metalurški fakultet) (RS-MESTD-inst-2020-200135)
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200135 (Univerzitet u Beogradu, Tehnološko-metalurški fakultet) (RS-MESTD-inst-2020-200135)
DOI: 10.1016/j.jct.2021.106578
ISSN: 0021-9614
WoS: 000684873500004
Scopus: 2-s2.0-85111850635
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Sas, Olalla G. AU - Ivaniš, Gorica AU - Kijevčanin, Mirjana AU - Gonzalez, Begona AU - Dominguez, Angeles AU - Radović, Ivona PY - 2021 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/4856 AB - Densities of four Deep Eutectic Solvents (DESs) based on menthol and organic acids (menthol:octanoic acid (1:1), menthol:decanoic acid (1:1), menthol:dodecanoic acid (2:1) and decanoic acid:octanoic acid (1:3)) were measured at high pressures (0.1 to 60) MPa and several temperatures (293.15 to 413.15) K. Tammann-Tait equation was used to model the experimental density data; the average absolute percentage deviations between calculated and experimental data were less or equal 0.012 %. The influence of the temperature and pressure on the derived volumetric properties: isothermal compressibility (k(T)), isobaric thermal expansivity (alpha(p)), internal pressure (p(int)) and difference between heat capacity at constant pressure (c(p)) and constant volume (c(v)) was analysed. Considering the experimental results, it is possible to observe that deep eutectic solvent formed by linear organic acids presents higher density values than those formed by menthol, being the densest the solvent formed by dodecanoic and octanoic acid. Attending to the derived volumetric properties in general, isothermal compressibility and isobaric thermal expansivity increase as temperature increases and decrease with pressure for all studied systems, being the octanoic acid based DESs slightly more compressible than the other studied DESs. T2 - Journal of Chemical Thermodynamics T1 - High pressure densities and derived thermodynamic properties of deep eutectic solvents with menthol and saturated fatty acids VL - 162 DO - 10.1016/j.jct.2021.106578 ER -
@article{ author = "Sas, Olalla G. and Ivaniš, Gorica and Kijevčanin, Mirjana and Gonzalez, Begona and Dominguez, Angeles and Radović, Ivona", year = "2021", abstract = "Densities of four Deep Eutectic Solvents (DESs) based on menthol and organic acids (menthol:octanoic acid (1:1), menthol:decanoic acid (1:1), menthol:dodecanoic acid (2:1) and decanoic acid:octanoic acid (1:3)) were measured at high pressures (0.1 to 60) MPa and several temperatures (293.15 to 413.15) K. Tammann-Tait equation was used to model the experimental density data; the average absolute percentage deviations between calculated and experimental data were less or equal 0.012 %. The influence of the temperature and pressure on the derived volumetric properties: isothermal compressibility (k(T)), isobaric thermal expansivity (alpha(p)), internal pressure (p(int)) and difference between heat capacity at constant pressure (c(p)) and constant volume (c(v)) was analysed. Considering the experimental results, it is possible to observe that deep eutectic solvent formed by linear organic acids presents higher density values than those formed by menthol, being the densest the solvent formed by dodecanoic and octanoic acid. Attending to the derived volumetric properties in general, isothermal compressibility and isobaric thermal expansivity increase as temperature increases and decrease with pressure for all studied systems, being the octanoic acid based DESs slightly more compressible than the other studied DESs.", journal = "Journal of Chemical Thermodynamics", title = "High pressure densities and derived thermodynamic properties of deep eutectic solvents with menthol and saturated fatty acids", volume = "162", doi = "10.1016/j.jct.2021.106578" }
Sas, O. G., Ivaniš, G., Kijevčanin, M., Gonzalez, B., Dominguez, A.,& Radović, I.. (2021). High pressure densities and derived thermodynamic properties of deep eutectic solvents with menthol and saturated fatty acids. in Journal of Chemical Thermodynamics, 162. https://doi.org/10.1016/j.jct.2021.106578
Sas OG, Ivaniš G, Kijevčanin M, Gonzalez B, Dominguez A, Radović I. High pressure densities and derived thermodynamic properties of deep eutectic solvents with menthol and saturated fatty acids. in Journal of Chemical Thermodynamics. 2021;162. doi:10.1016/j.jct.2021.106578 .
Sas, Olalla G., Ivaniš, Gorica, Kijevčanin, Mirjana, Gonzalez, Begona, Dominguez, Angeles, Radović, Ivona, "High pressure densities and derived thermodynamic properties of deep eutectic solvents with menthol and saturated fatty acids" in Journal of Chemical Thermodynamics, 162 (2021), https://doi.org/10.1016/j.jct.2021.106578 . .