Characterization and kinetics of thermal decomposition behavior of plum and fig pomace biomass
Само за регистроване кориснике
2022
Аутори
Katnić, ĐuricaMarinović-Cincović, Milena
Porobić, Slavica J.
Vujčić, Ivica
Šaponjić, Aleksandra
Sikirić, Biljana
Živojinović, Dragana
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Redirecting waste biomass back into the economy can reduce their burden on the environment. The use of waste biomass for the production of fuels, value-added materials or natural fillers has significant economic and environmental benefits. Physico-chemical characterization of waste biomass (plum pomace and fig pomace) was done by proximate, elemental, biochemical analysis, FTIR and SEM analysis. The calorific value of both biomasses can be compared with the calorific value of lignite, which rises their potential use as a solid biofuel. The combustion behavior of biomass was investigated by thermal analysis techniques. Based on thermal degradation experiments performed at four heating rates a kinetic analysis of the biomass decomposition process was accomplished. The kinetic study was done using Kissinger method, Ozawa method, Flynn-Wall-Ozawa (FWO) method, Starink method, and Kissinger-Akahira-Sunose (KAS) method. The value of activation energy obtained by different kinetic methods was... ∼210 kJ/mol for plum pomace and ∼162 kJ/mol for fig pomace. Estimated activation energy values were used to calculate thermodynamic parameters. In addition to the fact that the obtained results can serve as a useful reference for the design of pyrolysis reactors, this research has ecological significance because it solves the problem of solid waste disposal.
Кључне речи:
Kinetics analysis / Plum and fig pomace / Pyrolysis / Thermal analysis TG/DTG / Thermodynamic parametersИзвор:
Journal of Cleaner Production, 2022, 352, 131637-Издавач:
- Elsevier Ltd
Финансирање / пројекти:
- info:eu-repo/grantAgreement/MESTD/inst-2020/200017/RS/ (-)
- Нове технологије за мониторинг и заштиту животног окружења од штетних хемијских супстанци и радијационог оптерећења (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43009)
DOI: 10.1016/j.jclepro.2022.131637
ISSN: 0959-6526
WoS: 00079122530000
Scopus: 2-s2.0-85127616534
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Katnić, Đurica AU - Marinović-Cincović, Milena AU - Porobić, Slavica J. AU - Vujčić, Ivica AU - Šaponjić, Aleksandra AU - Sikirić, Biljana AU - Živojinović, Dragana PY - 2022 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5107 AB - Redirecting waste biomass back into the economy can reduce their burden on the environment. The use of waste biomass for the production of fuels, value-added materials or natural fillers has significant economic and environmental benefits. Physico-chemical characterization of waste biomass (plum pomace and fig pomace) was done by proximate, elemental, biochemical analysis, FTIR and SEM analysis. The calorific value of both biomasses can be compared with the calorific value of lignite, which rises their potential use as a solid biofuel. The combustion behavior of biomass was investigated by thermal analysis techniques. Based on thermal degradation experiments performed at four heating rates a kinetic analysis of the biomass decomposition process was accomplished. The kinetic study was done using Kissinger method, Ozawa method, Flynn-Wall-Ozawa (FWO) method, Starink method, and Kissinger-Akahira-Sunose (KAS) method. The value of activation energy obtained by different kinetic methods was ∼210 kJ/mol for plum pomace and ∼162 kJ/mol for fig pomace. Estimated activation energy values were used to calculate thermodynamic parameters. In addition to the fact that the obtained results can serve as a useful reference for the design of pyrolysis reactors, this research has ecological significance because it solves the problem of solid waste disposal. PB - Elsevier Ltd T2 - Journal of Cleaner Production T1 - Characterization and kinetics of thermal decomposition behavior of plum and fig pomace biomass SP - 131637 VL - 352 DO - 10.1016/j.jclepro.2022.131637 ER -
@article{ author = "Katnić, Đurica and Marinović-Cincović, Milena and Porobić, Slavica J. and Vujčić, Ivica and Šaponjić, Aleksandra and Sikirić, Biljana and Živojinović, Dragana", year = "2022", abstract = "Redirecting waste biomass back into the economy can reduce their burden on the environment. The use of waste biomass for the production of fuels, value-added materials or natural fillers has significant economic and environmental benefits. Physico-chemical characterization of waste biomass (plum pomace and fig pomace) was done by proximate, elemental, biochemical analysis, FTIR and SEM analysis. The calorific value of both biomasses can be compared with the calorific value of lignite, which rises their potential use as a solid biofuel. The combustion behavior of biomass was investigated by thermal analysis techniques. Based on thermal degradation experiments performed at four heating rates a kinetic analysis of the biomass decomposition process was accomplished. The kinetic study was done using Kissinger method, Ozawa method, Flynn-Wall-Ozawa (FWO) method, Starink method, and Kissinger-Akahira-Sunose (KAS) method. The value of activation energy obtained by different kinetic methods was ∼210 kJ/mol for plum pomace and ∼162 kJ/mol for fig pomace. Estimated activation energy values were used to calculate thermodynamic parameters. In addition to the fact that the obtained results can serve as a useful reference for the design of pyrolysis reactors, this research has ecological significance because it solves the problem of solid waste disposal.", publisher = "Elsevier Ltd", journal = "Journal of Cleaner Production", title = "Characterization and kinetics of thermal decomposition behavior of plum and fig pomace biomass", pages = "131637", volume = "352", doi = "10.1016/j.jclepro.2022.131637" }
Katnić, Đ., Marinović-Cincović, M., Porobić, S. J., Vujčić, I., Šaponjić, A., Sikirić, B.,& Živojinović, D.. (2022). Characterization and kinetics of thermal decomposition behavior of plum and fig pomace biomass. in Journal of Cleaner Production Elsevier Ltd., 352, 131637. https://doi.org/10.1016/j.jclepro.2022.131637
Katnić Đ, Marinović-Cincović M, Porobić SJ, Vujčić I, Šaponjić A, Sikirić B, Živojinović D. Characterization and kinetics of thermal decomposition behavior of plum and fig pomace biomass. in Journal of Cleaner Production. 2022;352:131637. doi:10.1016/j.jclepro.2022.131637 .
Katnić, Đurica, Marinović-Cincović, Milena, Porobić, Slavica J., Vujčić, Ivica, Šaponjić, Aleksandra, Sikirić, Biljana, Živojinović, Dragana, "Characterization and kinetics of thermal decomposition behavior of plum and fig pomace biomass" in Journal of Cleaner Production, 352 (2022):131637, https://doi.org/10.1016/j.jclepro.2022.131637 . .