A study of the tetrahallogenonickel(II) complexes by the Fenske-Hall molecular orbital method
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1995
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The coordination geometry and electronic structure of the NiX4(2-) complex ions (X=Cl, Br, I) have been studied by the Fenske-Hall SCF method. The calculation confirm the presence of tetrahedral over square-planar geometry. They also show that the MO energy level splitting is consistent with the spectrochemical series. The calculation confirm that the Ni-X bond becomes increasingly covalent in the series: NiCl4(2-), NiBr4(2-), NiI4(2-)
Кључне речи:
tetrahalogenonickel(II) complexes / coordination geometry / electronic structure / Fenske-Hall calculationsИзвор:
Bulletin of the Chemists and Technologists of Macedonia, 1995, 14, 2, 95-100Издавач:
- Society of Chemists and Technologists of Macedonia
Финансирање / пројекти:
- Ministry of Science of Serbia
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Stojaković, Djordje AU - Rajić, Nevenka PY - 1995 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5158 AB - The coordination geometry and electronic structure of the NiX4(2-) complex ions (X=Cl, Br, I) have been studied by the Fenske-Hall SCF method. The calculation confirm the presence of tetrahedral over square-planar geometry. They also show that the MO energy level splitting is consistent with the spectrochemical series. The calculation confirm that the Ni-X bond becomes increasingly covalent in the series: NiCl4(2-), NiBr4(2-), NiI4(2-) PB - Society of Chemists and Technologists of Macedonia T2 - Bulletin of the Chemists and Technologists of Macedonia T1 - A study of the tetrahallogenonickel(II) complexes by the Fenske-Hall molecular orbital method EP - 100 IS - 2 SP - 95 VL - 14 UR - https://hdl.handle.net/21.15107/rcub_technorep_5158 ER -
@article{ author = "Stojaković, Djordje and Rajić, Nevenka", year = "1995", abstract = "The coordination geometry and electronic structure of the NiX4(2-) complex ions (X=Cl, Br, I) have been studied by the Fenske-Hall SCF method. The calculation confirm the presence of tetrahedral over square-planar geometry. They also show that the MO energy level splitting is consistent with the spectrochemical series. The calculation confirm that the Ni-X bond becomes increasingly covalent in the series: NiCl4(2-), NiBr4(2-), NiI4(2-)", publisher = "Society of Chemists and Technologists of Macedonia", journal = "Bulletin of the Chemists and Technologists of Macedonia", title = "A study of the tetrahallogenonickel(II) complexes by the Fenske-Hall molecular orbital method", pages = "100-95", number = "2", volume = "14", url = "https://hdl.handle.net/21.15107/rcub_technorep_5158" }
Stojaković, D.,& Rajić, N.. (1995). A study of the tetrahallogenonickel(II) complexes by the Fenske-Hall molecular orbital method. in Bulletin of the Chemists and Technologists of Macedonia Society of Chemists and Technologists of Macedonia., 14(2), 95-100. https://hdl.handle.net/21.15107/rcub_technorep_5158
Stojaković D, Rajić N. A study of the tetrahallogenonickel(II) complexes by the Fenske-Hall molecular orbital method. in Bulletin of the Chemists and Technologists of Macedonia. 1995;14(2):95-100. https://hdl.handle.net/21.15107/rcub_technorep_5158 .
Stojaković, Djordje, Rajić, Nevenka, "A study of the tetrahallogenonickel(II) complexes by the Fenske-Hall molecular orbital method" in Bulletin of the Chemists and Technologists of Macedonia, 14, no. 2 (1995):95-100, https://hdl.handle.net/21.15107/rcub_technorep_5158 .