Study of quantitative structure-retention relationships for s-triazine derivatives in different RP HPTLC systems
Само за регистроване кориснике
2005
Аутори
Perišić-Janjić, Nada U.Djaković-Sekulić, Tatjana Lj.
Jevrić, Lidija R.
Jovanović, Bratislav Ž.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Quantitative structure-retention relationships (QSRR) have been used to study the chromatographic behavior of some s-triazines. Retention factors, RM0, on C18 layers corresponding to zero percent organic modifier in the aqueous mobile phase were determined for five mobile phase mixtures: methanol-water, acetone-water, acetonitrile-water, 2-propanol-water, and tetrahydrofuran-water and relationships between RM 0 values obtained with different organic mobile phase modifiers were examined. A variety of partition coefficients (Alog P, IAlog P, Clog P, Xlog P, log PKowin, and ACDlog P) were calculated by use of different software products. The correlation between partition coefficients and chromatographically obtained lipophilicity was analyzed. On the basis of correlations between RM0 and log P, C18 with methanol-water as mobile phase was selected as the best RP HPTLC system for determination of the octanol/water partition coefficient and thus the lipophilicity of the molecules.
Кључне речи:
Lipophilicity / Quantitative structure-retention relationships (QSRR) / RP HPTLC / s-Triazine derivativesИзвор:
Journal of Planar Chromatography - Modern TLC, 2005, 18, 103, 212-216Издавач:
- Akadémiai Kiadó
- Springer
Финансирање / пројекти:
- These results were obtained as part of project no. 1694 “Investigation of the Synthesis, Structure and Characteristics of Natural and Synthetic Organic Compounds”, which is supported financially by the Serbian Ministry of Science and Environment.
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Perišić-Janjić, Nada U. AU - Djaković-Sekulić, Tatjana Lj. AU - Jevrić, Lidija R. AU - Jovanović, Bratislav Ž. PY - 2005 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/5510 AB - Quantitative structure-retention relationships (QSRR) have been used to study the chromatographic behavior of some s-triazines. Retention factors, RM0, on C18 layers corresponding to zero percent organic modifier in the aqueous mobile phase were determined for five mobile phase mixtures: methanol-water, acetone-water, acetonitrile-water, 2-propanol-water, and tetrahydrofuran-water and relationships between RM 0 values obtained with different organic mobile phase modifiers were examined. A variety of partition coefficients (Alog P, IAlog P, Clog P, Xlog P, log PKowin, and ACDlog P) were calculated by use of different software products. The correlation between partition coefficients and chromatographically obtained lipophilicity was analyzed. On the basis of correlations between RM0 and log P, C18 with methanol-water as mobile phase was selected as the best RP HPTLC system for determination of the octanol/water partition coefficient and thus the lipophilicity of the molecules. PB - Akadémiai Kiadó PB - Springer T2 - Journal of Planar Chromatography - Modern TLC T1 - Study of quantitative structure-retention relationships for s-triazine derivatives in different RP HPTLC systems EP - 216 IS - 103 SP - 212 VL - 18 DO - 10.1556/JPC.18.2005.3.8 ER -
@article{ author = "Perišić-Janjić, Nada U. and Djaković-Sekulić, Tatjana Lj. and Jevrić, Lidija R. and Jovanović, Bratislav Ž.", year = "2005", abstract = "Quantitative structure-retention relationships (QSRR) have been used to study the chromatographic behavior of some s-triazines. Retention factors, RM0, on C18 layers corresponding to zero percent organic modifier in the aqueous mobile phase were determined for five mobile phase mixtures: methanol-water, acetone-water, acetonitrile-water, 2-propanol-water, and tetrahydrofuran-water and relationships between RM 0 values obtained with different organic mobile phase modifiers were examined. A variety of partition coefficients (Alog P, IAlog P, Clog P, Xlog P, log PKowin, and ACDlog P) were calculated by use of different software products. The correlation between partition coefficients and chromatographically obtained lipophilicity was analyzed. On the basis of correlations between RM0 and log P, C18 with methanol-water as mobile phase was selected as the best RP HPTLC system for determination of the octanol/water partition coefficient and thus the lipophilicity of the molecules.", publisher = "Akadémiai Kiadó, Springer", journal = "Journal of Planar Chromatography - Modern TLC", title = "Study of quantitative structure-retention relationships for s-triazine derivatives in different RP HPTLC systems", pages = "216-212", number = "103", volume = "18", doi = "10.1556/JPC.18.2005.3.8" }
Perišić-Janjić, N. U., Djaković-Sekulić, T. Lj., Jevrić, L. R.,& Jovanović, B. Ž.. (2005). Study of quantitative structure-retention relationships for s-triazine derivatives in different RP HPTLC systems. in Journal of Planar Chromatography - Modern TLC Akadémiai Kiadó., 18(103), 212-216. https://doi.org/10.1556/JPC.18.2005.3.8
Perišić-Janjić NU, Djaković-Sekulić TL, Jevrić LR, Jovanović BŽ. Study of quantitative structure-retention relationships for s-triazine derivatives in different RP HPTLC systems. in Journal of Planar Chromatography - Modern TLC. 2005;18(103):212-216. doi:10.1556/JPC.18.2005.3.8 .
Perišić-Janjić, Nada U., Djaković-Sekulić, Tatjana Lj., Jevrić, Lidija R., Jovanović, Bratislav Ž., "Study of quantitative structure-retention relationships for s-triazine derivatives in different RP HPTLC systems" in Journal of Planar Chromatography - Modern TLC, 18, no. 103 (2005):212-216, https://doi.org/10.1556/JPC.18.2005.3.8 . .