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dc.creatorRajić, Nevenka
dc.creatorZabukovec-Logar, Nataša
dc.creatorMali, Gregor
dc.creatorKaučič, Venčeslav
dc.date.accessioned2021-03-10T10:09:02Z
dc.date.available2021-03-10T10:09:02Z
dc.date.issued2003
dc.identifier.issn0897-4756
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/563
dc.description.abstractA new 3-D alumino(oxalato)phosphate, [H3NCH(CH3)CH2NH3](2)[Al4P6O20(OH)(4)(C2O4)(H2O)], consists of aluminophosphate layers which are pillared by oxalate anions. It contains a hybrid 12-membered channel where guest species, diprotonated 1,2-diaminopropane and water molecules, are found. The layers are composed of AlO6, AlO4, and PO4 polyhedra giving double chains, which are interconnected through Al-O-P-O-Al bridges. Oxalate ions are quadridentately bonded by participating in the coordination of AlO6 and by bridging the aluminophosphate layers. The guest species strongly interact with the alumino(oxalato)phosphate layers which is evidenced by solid-state NMR spectroscopy. Crystal data are: triclinic, space group P (1) over bar, a = 8.611(1) Angstrom, b = 9.096(1) Angstrom, c = 11.371(1) Angstrom, alpha = 104.811(1)degrees, beta = 111.368(1)degrees, and gamma = 94.248(1)degrees, V = 787.9(1) Angstrom(3), and R = 0.041.en
dc.publisherAmer Chemical Soc, Washington
dc.rightsrestrictedAccess
dc.sourceChemistry of Materials
dc.titleNew inorganic-organic hybrid: Synthesis and structural characterization of an alumino(oxalato)phosphateen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage1738
dc.citation.issue8
dc.citation.other15(8): 1734-1738
dc.citation.rankaM21
dc.citation.spage1734
dc.citation.volume15
dc.identifier.doi10.1021/cm021343u
dc.identifier.rcubconv_2294
dc.identifier.scopus2-s2.0-0037461235
dc.identifier.wos000182381300024
dc.type.versionpublishedVersion


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