Applicability of cubic equation of state mixing rules on correlation of excess molar volume of non-electrolyte binary mixtures
Abstract
The excess molar volume V data of the binary liquid systems were correlated by the Peng-Robinson-Stryjek-Vera equation of state coupled with two different types of mixing rules: composition dependent van der Waals mixing rule (vdW) and the mixing rule based on the Gupta-Rasmussen-Fredenslund method (GRF), with the NRTL equation as G(E) model. The results obtained by these models show that type of applied mixing rule, a number and position of interaction parameters are of great importance for a satisfactory correlation of V-E data. The GRF mixing rules coupled with the NRTL model gave mostly satisfactory results for V-E correlation of the nonideal binary systems of diverse complexity.
Keywords:
excess molar volume / CEOs / NRTL / correlation / mixing rulesSource:
Physics and Chemistry of Liquids, 2004, 42, 2, 147-158Publisher:
- Taylor & Francis Ltd, Abingdon
DOI: 10.1080/00319100310001634828
ISSN: 0031-9104
WoS: 000220739700005
Scopus: 2-s2.0-11144357312
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Kijevčanin, Mirjana AU - Đorđević, Bojan D. AU - Šerbanović, Slobodan P. AU - Grgurić, Ivona R. AU - Tasić, AZ PY - 2004 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/678 AB - The excess molar volume V data of the binary liquid systems were correlated by the Peng-Robinson-Stryjek-Vera equation of state coupled with two different types of mixing rules: composition dependent van der Waals mixing rule (vdW) and the mixing rule based on the Gupta-Rasmussen-Fredenslund method (GRF), with the NRTL equation as G(E) model. The results obtained by these models show that type of applied mixing rule, a number and position of interaction parameters are of great importance for a satisfactory correlation of V-E data. The GRF mixing rules coupled with the NRTL model gave mostly satisfactory results for V-E correlation of the nonideal binary systems of diverse complexity. PB - Taylor & Francis Ltd, Abingdon T2 - Physics and Chemistry of Liquids T1 - Applicability of cubic equation of state mixing rules on correlation of excess molar volume of non-electrolyte binary mixtures EP - 158 IS - 2 SP - 147 VL - 42 DO - 10.1080/00319100310001634828 ER -
@article{ author = "Kijevčanin, Mirjana and Đorđević, Bojan D. and Šerbanović, Slobodan P. and Grgurić, Ivona R. and Tasić, AZ", year = "2004", abstract = "The excess molar volume V data of the binary liquid systems were correlated by the Peng-Robinson-Stryjek-Vera equation of state coupled with two different types of mixing rules: composition dependent van der Waals mixing rule (vdW) and the mixing rule based on the Gupta-Rasmussen-Fredenslund method (GRF), with the NRTL equation as G(E) model. The results obtained by these models show that type of applied mixing rule, a number and position of interaction parameters are of great importance for a satisfactory correlation of V-E data. The GRF mixing rules coupled with the NRTL model gave mostly satisfactory results for V-E correlation of the nonideal binary systems of diverse complexity.", publisher = "Taylor & Francis Ltd, Abingdon", journal = "Physics and Chemistry of Liquids", title = "Applicability of cubic equation of state mixing rules on correlation of excess molar volume of non-electrolyte binary mixtures", pages = "158-147", number = "2", volume = "42", doi = "10.1080/00319100310001634828" }
Kijevčanin, M., Đorđević, B. D., Šerbanović, S. P., Grgurić, I. R.,& Tasić, A.. (2004). Applicability of cubic equation of state mixing rules on correlation of excess molar volume of non-electrolyte binary mixtures. in Physics and Chemistry of Liquids Taylor & Francis Ltd, Abingdon., 42(2), 147-158. https://doi.org/10.1080/00319100310001634828
Kijevčanin M, Đorđević BD, Šerbanović SP, Grgurić IR, Tasić A. Applicability of cubic equation of state mixing rules on correlation of excess molar volume of non-electrolyte binary mixtures. in Physics and Chemistry of Liquids. 2004;42(2):147-158. doi:10.1080/00319100310001634828 .
Kijevčanin, Mirjana, Đorđević, Bojan D., Šerbanović, Slobodan P., Grgurić, Ivona R., Tasić, AZ, "Applicability of cubic equation of state mixing rules on correlation of excess molar volume of non-electrolyte binary mixtures" in Physics and Chemistry of Liquids, 42, no. 2 (2004):147-158, https://doi.org/10.1080/00319100310001634828 . .