13-Diaminopropane (DAP) was used as a structure-directing agent for the hydrothermal synthesis of an organically templated iron phosphate. During crystallization at 180 degreesC, iron phosphate (FePO-DAP) with a layered structure was formed after one day. Longer crystallization yielded a mixture of FePO-DAP and leucophosphite, raising the question whether a transformation of FePO-DAP to leucophosphite occurs. or wheter DAP decomposes under hydrothermal conditions resulting in leucophosphite formation. Lattice energy, and free energy calculations strongly support the supposition that a decomposition of DAP occurs prior to the formation of leueophosphite.
TY - JOUR
AU - Rajić, Nevenka
AU - Stojaković, D.
AU - Hanžel, Darko
AU - Kaučič, Venčeslav
PY - 2004
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/680
AB - 13-Diaminopropane (DAP) was used as a structure-directing agent for the hydrothermal synthesis of an organically templated iron phosphate. During crystallization at 180 degreesC, iron phosphate (FePO-DAP) with a layered structure was formed after one day. Longer crystallization yielded a mixture of FePO-DAP and leucophosphite, raising the question whether a transformation of FePO-DAP to leucophosphite occurs. or wheter DAP decomposes under hydrothermal conditions resulting in leucophosphite formation. Lattice energy, and free energy calculations strongly support the supposition that a decomposition of DAP occurs prior to the formation of leueophosphite.
PB - Srpsko hemijsko društvo, Beograd
T2 - Journal of the Serbian Chemical Society
T1 - The structure directing role of 1,3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate
EP - 185
IS - 3
SP - 179
VL - 69
DO - 10.2298/JSC0403179R
UR - conv_2414
ER -
@article{
author = "Rajić, Nevenka and Stojaković, D. and Hanžel, Darko and Kaučič, Venčeslav",
year = "2004",
abstract = "13-Diaminopropane (DAP) was used as a structure-directing agent for the hydrothermal synthesis of an organically templated iron phosphate. During crystallization at 180 degreesC, iron phosphate (FePO-DAP) with a layered structure was formed after one day. Longer crystallization yielded a mixture of FePO-DAP and leucophosphite, raising the question whether a transformation of FePO-DAP to leucophosphite occurs. or wheter DAP decomposes under hydrothermal conditions resulting in leucophosphite formation. Lattice energy, and free energy calculations strongly support the supposition that a decomposition of DAP occurs prior to the formation of leueophosphite.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "The structure directing role of 1,3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate",
pages = "185-179",
number = "3",
volume = "69",
doi = "10.2298/JSC0403179R",
url = "conv_2414"
}
Rajić, N., Stojaković, D., Hanžel, D.,& Kaučič, V.. (2004). The structure directing role of 1,3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 69(3), 179-185.
https://doi.org/10.2298/JSC0403179R
conv_2414
Rajić N, Stojaković D, Hanžel D, Kaučič V. The structure directing role of 1,3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate. in Journal of the Serbian Chemical Society. 2004;69(3):179-185.
doi:10.2298/JSC0403179R
conv_2414 .
Rajić, Nevenka, Stojaković, D., Hanžel, Darko, Kaučič, Venčeslav, "The structure directing role of 1,3-diaminopropane in the hydrothermal synthesis of iron(III) phosphate" in Journal of the Serbian Chemical Society, 69, no. 3 (2004):179-185,
https://doi.org/10.2298/JSC0403179R .,
conv_2414 .
