ADVANCING BIOCOMPOSITES: INTRODUCTION OF NANOCELLULOSE AS A SUSTAINABLE FILLER OF BIOBASED UNSATURATED POLYESTER RESINS
Само за регистроване кориснике
2023
Аутори
Pantić, OlgaPanić, Vesna
Marković, Maja
Spasojević Savković, Milica
Savić, Sanja
Kalagasidis Krušić, Melina
Spasojević, Pavle
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Biocomposites are materials that are composed of a matrix and fillers both of which derived from
renewable resources. They offer an alternative to traditional petroleum-based composites and
have gained interest due to potential environmental benefits and sustaina
idea, itaconic and succinic acids and propylene glycol were used in the synthesis of a biobased
unsaturated polyester, diluted with biobased reactive diluent, dimethyl itaconate, to cure fully
biobased unsaturated polyester resin (UPR). Despite having a low environmental impact, the
mechanical properties of biobased UPRs are not considered commercially viable compared to
their petroleum-based counterparts. To lessen the discrepancy between the two, nanocellulose
(NC) was incorporated into the biobased UPR in two ways. Firstly, NC was added during synthesis,
while secondly it was added after the synthesis of UPR was completed. Both series implied the
use of three different quan s of NC (1, 2, 3 wt.%). FTIR spectroscop...y, gel content analysis,
SEM, dynamic mechanical analysis, and uniaxial tensile test were used to characterize obtained
biocomposites. It was demonstrcted that when NC was added during the synthesis, it had no
effect on UPR viscosity. On the other hand, adding NC after the synthesis significantly increased
viscosity. Overall results showed that higher quantities of NC increased tensile strength, storage
modulus at lower frequencies, and decreased glass transition temperature.
Извор:
Book of Abstracts / 29thPolyChar - World Forum on Advanced Materials, 26 - 29 September 2023, Nice, France, 2023, 52-Издавач:
- University of North Texas
Финансирање / пројекти:
- Step2PolyGreen - A step to green polyester products: Sustainable solutions for everyday objects (RS-ScienceFundRS-Zeleni-6793)
Колекције
Институција/група
Inovacioni centarTY - CONF AU - Pantić, Olga AU - Panić, Vesna AU - Marković, Maja AU - Spasojević Savković, Milica AU - Savić, Sanja AU - Kalagasidis Krušić, Melina AU - Spasojević, Pavle PY - 2023 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/6867 AB - Biocomposites are materials that are composed of a matrix and fillers both of which derived from renewable resources. They offer an alternative to traditional petroleum-based composites and have gained interest due to potential environmental benefits and sustaina idea, itaconic and succinic acids and propylene glycol were used in the synthesis of a biobased unsaturated polyester, diluted with biobased reactive diluent, dimethyl itaconate, to cure fully biobased unsaturated polyester resin (UPR). Despite having a low environmental impact, the mechanical properties of biobased UPRs are not considered commercially viable compared to their petroleum-based counterparts. To lessen the discrepancy between the two, nanocellulose (NC) was incorporated into the biobased UPR in two ways. Firstly, NC was added during synthesis, while secondly it was added after the synthesis of UPR was completed. Both series implied the use of three different quan s of NC (1, 2, 3 wt.%). FTIR spectroscopy, gel content analysis, SEM, dynamic mechanical analysis, and uniaxial tensile test were used to characterize obtained biocomposites. It was demonstrcted that when NC was added during the synthesis, it had no effect on UPR viscosity. On the other hand, adding NC after the synthesis significantly increased viscosity. Overall results showed that higher quantities of NC increased tensile strength, storage modulus at lower frequencies, and decreased glass transition temperature. PB - University of North Texas C3 - Book of Abstracts / 29thPolyChar - World Forum on Advanced Materials, 26 - 29 September 2023, Nice, France T1 - ADVANCING BIOCOMPOSITES: INTRODUCTION OF NANOCELLULOSE AS A SUSTAINABLE FILLER OF BIOBASED UNSATURATED POLYESTER RESINS SP - 52 UR - https://hdl.handle.net/21.15107/rcub_technorep_6867 ER -
@conference{ author = "Pantić, Olga and Panić, Vesna and Marković, Maja and Spasojević Savković, Milica and Savić, Sanja and Kalagasidis Krušić, Melina and Spasojević, Pavle", year = "2023", abstract = "Biocomposites are materials that are composed of a matrix and fillers both of which derived from renewable resources. They offer an alternative to traditional petroleum-based composites and have gained interest due to potential environmental benefits and sustaina idea, itaconic and succinic acids and propylene glycol were used in the synthesis of a biobased unsaturated polyester, diluted with biobased reactive diluent, dimethyl itaconate, to cure fully biobased unsaturated polyester resin (UPR). Despite having a low environmental impact, the mechanical properties of biobased UPRs are not considered commercially viable compared to their petroleum-based counterparts. To lessen the discrepancy between the two, nanocellulose (NC) was incorporated into the biobased UPR in two ways. Firstly, NC was added during synthesis, while secondly it was added after the synthesis of UPR was completed. Both series implied the use of three different quan s of NC (1, 2, 3 wt.%). FTIR spectroscopy, gel content analysis, SEM, dynamic mechanical analysis, and uniaxial tensile test were used to characterize obtained biocomposites. It was demonstrcted that when NC was added during the synthesis, it had no effect on UPR viscosity. On the other hand, adding NC after the synthesis significantly increased viscosity. Overall results showed that higher quantities of NC increased tensile strength, storage modulus at lower frequencies, and decreased glass transition temperature.", publisher = "University of North Texas", journal = "Book of Abstracts / 29thPolyChar - World Forum on Advanced Materials, 26 - 29 September 2023, Nice, France", title = "ADVANCING BIOCOMPOSITES: INTRODUCTION OF NANOCELLULOSE AS A SUSTAINABLE FILLER OF BIOBASED UNSATURATED POLYESTER RESINS", pages = "52", url = "https://hdl.handle.net/21.15107/rcub_technorep_6867" }
Pantić, O., Panić, V., Marković, M., Spasojević Savković, M., Savić, S., Kalagasidis Krušić, M.,& Spasojević, P.. (2023). ADVANCING BIOCOMPOSITES: INTRODUCTION OF NANOCELLULOSE AS A SUSTAINABLE FILLER OF BIOBASED UNSATURATED POLYESTER RESINS. in Book of Abstracts / 29thPolyChar - World Forum on Advanced Materials, 26 - 29 September 2023, Nice, France University of North Texas., 52. https://hdl.handle.net/21.15107/rcub_technorep_6867
Pantić O, Panić V, Marković M, Spasojević Savković M, Savić S, Kalagasidis Krušić M, Spasojević P. ADVANCING BIOCOMPOSITES: INTRODUCTION OF NANOCELLULOSE AS A SUSTAINABLE FILLER OF BIOBASED UNSATURATED POLYESTER RESINS. in Book of Abstracts / 29thPolyChar - World Forum on Advanced Materials, 26 - 29 September 2023, Nice, France. 2023;:52. https://hdl.handle.net/21.15107/rcub_technorep_6867 .
Pantić, Olga, Panić, Vesna, Marković, Maja, Spasojević Savković, Milica, Savić, Sanja, Kalagasidis Krušić, Melina, Spasojević, Pavle, "ADVANCING BIOCOMPOSITES: INTRODUCTION OF NANOCELLULOSE AS A SUSTAINABLE FILLER OF BIOBASED UNSATURATED POLYESTER RESINS" in Book of Abstracts / 29thPolyChar - World Forum on Advanced Materials, 26 - 29 September 2023, Nice, France (2023):52, https://hdl.handle.net/21.15107/rcub_technorep_6867 .