Show simple item record

dc.creatorUšćumlić, Gordana
dc.creatorNikolić, Jasmina
dc.creatorKrstić, Vera V.
dc.date.accessioned2021-03-10T10:19:43Z
dc.date.available2021-03-10T10:19:43Z
dc.date.issued2005
dc.identifier.issn0376-4699
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/729
dc.description.abstractThe rate constants for the reaction of diazodiphenylinethane with 2-substituted cyclohex-1-enylcarboxylic acids, determined in butan-1-ol, 2-methylpropan-1-ol and ethylene glycol, together with the rate constants determined previously in methanol, ethanol, propan-1-ol and propan-2-ol, are correlated using the total solvtochromic equation, of the form log k = A(o) + s pi* + a alpha + b beta the two parameter model log k =A(o)+ s pi* + a alpha and the single parameter model log k = A(o) + b beta, where pi*, beta and alpha represent the solvent dipolarity/polarizability, solvent hydrogen bond acceptor basicity and hydrogen bond donor acidity, respectively. The correlation of the kinetic data are carried Out by means of multiple linear regression analysis and solvent effects on the reaction rates have been analysed in terms of initial state and transition state contributions. The results obtained for 2-substituted cyclohex-1-enylcarboxylic acids are compared with the results for 2-subsituted benzoic acids under the same experimental conditions.en
dc.publisherNatl Inst Science Communication, New Delhi
dc.rightsrestrictedAccess
dc.sourceIndian Journal of Chemistry - Section B Organic and Medicinal Chemistry
dc.titleHydroxylic solvent effects on the reaction rates of diazodiphenyl methane with 2-substituted cyclohex-1-enylcarboxylic and 2-substituted benzoic acids: Part IIen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage1287
dc.citation.issue6
dc.citation.other44(6): 1283-1287
dc.citation.rankM23
dc.citation.spage1283
dc.citation.volume44
dc.identifier.pmid
dc.identifier.rcubconv_6996
dc.identifier.scopus2-s2.0-23844499698
dc.identifier.wos000229941900012
dc.type.versionpublishedVersion


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record