Greenness of dispersive microextraction using molecularly imprinted polymers
Аутори
Tadić, TamaraMarković, Bojana
Bulatović, Sandra
Lukić, Jelena
Radulović, Jelena
Nastasović, Aleksandra
Onjia, Antonije
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Molecularly imprinted polymers (MIPs) as materials with determined levels of selectivity and specificity for designated analytes have recently gained much attention in various application fields. However, with the growing adoption of green analytical chemistry (GAC) principles, it is essential to investigate the greenness of MIP synthesis and its subsequent application in sample preparation, as well as to evaluate the "green"nature of the developed analytical methodologies, such as dispersive solid-phase microextraction (DSPME). Accordingly, the main objective of this research was to evaluate the greenness of MIP-based glycidyl methacrylate synthesis and MIP use as a DSPME sorbent prior to high-performance liquid chromatography with mass spectrometry (HPLC-MS). The green perspective of MIP-DSPME prior to HPLC-MS was investigated using various analytical metric tools such as the Analytical Eco-Scale, the Green Analytical Procedure Index, and Analytical GREEnness (AGREE). Since these ana...lytical tools are not fully implementable for the assessment of the greenness of the MIP synthesis, some alternative approaches were used to optimize the synthesis parameters to make the MIP DSPME sorbent as close as possible to the GAC principles. The calculated AGREE score (0.62) and 91 points in the Analytical Eco-Scale for the proposed DSPME technique using MIP indicated a high level of greenness.
Кључне речи:
AGREE / analytical eco-scale / DSPME / GAPI / green sorbent / magnetic MIPИзвор:
Reviews in Analytical Chemistry, 2024, 43, 1, 20230070-Издавач:
- Walter de Gruyter
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-MESTD-inst-2020-200026)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200135 (Универзитет у Београду, Технолошко-металуршки факултет) (RS-MESTD-inst-2020-200135)
Колекције
Институција/група
Inovacioni centarTY - JOUR AU - Tadić, Tamara AU - Marković, Bojana AU - Bulatović, Sandra AU - Lukić, Jelena AU - Radulović, Jelena AU - Nastasović, Aleksandra AU - Onjia, Antonije PY - 2024 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7321 AB - Molecularly imprinted polymers (MIPs) as materials with determined levels of selectivity and specificity for designated analytes have recently gained much attention in various application fields. However, with the growing adoption of green analytical chemistry (GAC) principles, it is essential to investigate the greenness of MIP synthesis and its subsequent application in sample preparation, as well as to evaluate the "green"nature of the developed analytical methodologies, such as dispersive solid-phase microextraction (DSPME). Accordingly, the main objective of this research was to evaluate the greenness of MIP-based glycidyl methacrylate synthesis and MIP use as a DSPME sorbent prior to high-performance liquid chromatography with mass spectrometry (HPLC-MS). The green perspective of MIP-DSPME prior to HPLC-MS was investigated using various analytical metric tools such as the Analytical Eco-Scale, the Green Analytical Procedure Index, and Analytical GREEnness (AGREE). Since these analytical tools are not fully implementable for the assessment of the greenness of the MIP synthesis, some alternative approaches were used to optimize the synthesis parameters to make the MIP DSPME sorbent as close as possible to the GAC principles. The calculated AGREE score (0.62) and 91 points in the Analytical Eco-Scale for the proposed DSPME technique using MIP indicated a high level of greenness. PB - Walter de Gruyter T2 - Reviews in Analytical Chemistry T1 - Greenness of dispersive microextraction using molecularly imprinted polymers IS - 1 SP - 20230070 VL - 43 DO - 10.1515/revac-2023-0070 ER -
@article{ author = "Tadić, Tamara and Marković, Bojana and Bulatović, Sandra and Lukić, Jelena and Radulović, Jelena and Nastasović, Aleksandra and Onjia, Antonije", year = "2024", abstract = "Molecularly imprinted polymers (MIPs) as materials with determined levels of selectivity and specificity for designated analytes have recently gained much attention in various application fields. However, with the growing adoption of green analytical chemistry (GAC) principles, it is essential to investigate the greenness of MIP synthesis and its subsequent application in sample preparation, as well as to evaluate the "green"nature of the developed analytical methodologies, such as dispersive solid-phase microextraction (DSPME). Accordingly, the main objective of this research was to evaluate the greenness of MIP-based glycidyl methacrylate synthesis and MIP use as a DSPME sorbent prior to high-performance liquid chromatography with mass spectrometry (HPLC-MS). The green perspective of MIP-DSPME prior to HPLC-MS was investigated using various analytical metric tools such as the Analytical Eco-Scale, the Green Analytical Procedure Index, and Analytical GREEnness (AGREE). Since these analytical tools are not fully implementable for the assessment of the greenness of the MIP synthesis, some alternative approaches were used to optimize the synthesis parameters to make the MIP DSPME sorbent as close as possible to the GAC principles. The calculated AGREE score (0.62) and 91 points in the Analytical Eco-Scale for the proposed DSPME technique using MIP indicated a high level of greenness.", publisher = "Walter de Gruyter", journal = "Reviews in Analytical Chemistry", title = "Greenness of dispersive microextraction using molecularly imprinted polymers", number = "1", pages = "20230070", volume = "43", doi = "10.1515/revac-2023-0070" }
Tadić, T., Marković, B., Bulatović, S., Lukić, J., Radulović, J., Nastasović, A.,& Onjia, A.. (2024). Greenness of dispersive microextraction using molecularly imprinted polymers. in Reviews in Analytical Chemistry Walter de Gruyter., 43(1), 20230070. https://doi.org/10.1515/revac-2023-0070
Tadić T, Marković B, Bulatović S, Lukić J, Radulović J, Nastasović A, Onjia A. Greenness of dispersive microextraction using molecularly imprinted polymers. in Reviews in Analytical Chemistry. 2024;43(1):20230070. doi:10.1515/revac-2023-0070 .
Tadić, Tamara, Marković, Bojana, Bulatović, Sandra, Lukić, Jelena, Radulović, Jelena, Nastasović, Aleksandra, Onjia, Antonije, "Greenness of dispersive microextraction using molecularly imprinted polymers" in Reviews in Analytical Chemistry, 43, no. 1 (2024):20230070, https://doi.org/10.1515/revac-2023-0070 . .