New interaction parameters for the groups CYCH(1)-furfural(2) and CyCH(1)-DMSO(2) of the ASOG-H model were determined, for 293.15 K-323.15 K and 303.15 K-323.15K respectively. The values of the CyCH(1)-furfural(2) parameters are A 1,2 = 1.2259, A 2,1 = -0.6307, B 1,2 = -36.57, B 2,1 = 63.32, C 1,2 = 9300, C 2,1 = -29317, whereas those for CyCH(1)-DMSO(2) are A 1,2 = 1.2570, A 2,1 = -3.5029, B 1,2 = -153.12, B 2,1 = -68.31, C 1,2 = 10500, C 2,1 = 31000. Using these values satisfactory results of h E data correlation for the systems cyclohexane-furfural and dimethyl sulfoxide-cyclohexanol were obtained. Also, it was shown that if the group interaction parameters ArCH and CH 2 were generated from the n-hexane-toluene h E data, the quality of the results was significantly improved, when compared with those obtained using the parameters from the literature.
TY - JOUR
AU - Kaluđerović, Tatjana
AU - Šerbanović, Slobodan P.
AU - Tasić, Aleksandar Ž.
AU - Đorđević, B.D.
PY - 1996
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/73
AB - New interaction parameters for the groups CYCH(1)-furfural(2) and CyCH(1)-DMSO(2) of the ASOG-H model were determined, for 293.15 K-323.15 K and 303.15 K-323.15K respectively. The values of the CyCH(1)-furfural(2) parameters are A 1,2 = 1.2259, A 2,1 = -0.6307, B 1,2 = -36.57, B 2,1 = 63.32, C 1,2 = 9300, C 2,1 = -29317, whereas those for CyCH(1)-DMSO(2) are A 1,2 = 1.2570, A 2,1 = -3.5029, B 1,2 = -153.12, B 2,1 = -68.31, C 1,2 = 10500, C 2,1 = 31000. Using these values satisfactory results of h E data correlation for the systems cyclohexane-furfural and dimethyl sulfoxide-cyclohexanol were obtained. Also, it was shown that if the group interaction parameters ArCH and CH 2 were generated from the n-hexane-toluene h E data, the quality of the results was significantly improved, when compared with those obtained using the parameters from the literature.
PB - Serbian Chemical Society, Belgrade
T2 - Journal of the Serbian Chemical Society
T1 - Determination of new ASOG-H parameters of CyCH, furfural and DMSO groups
EP - 348
IS - 4-5
SP - 343
VL - 61
UR - conv_7345
ER -
@article{
author = "Kaluđerović, Tatjana and Šerbanović, Slobodan P. and Tasić, Aleksandar Ž. and Đorđević, B.D.",
year = "1996",
abstract = "New interaction parameters for the groups CYCH(1)-furfural(2) and CyCH(1)-DMSO(2) of the ASOG-H model were determined, for 293.15 K-323.15 K and 303.15 K-323.15K respectively. The values of the CyCH(1)-furfural(2) parameters are A 1,2 = 1.2259, A 2,1 = -0.6307, B 1,2 = -36.57, B 2,1 = 63.32, C 1,2 = 9300, C 2,1 = -29317, whereas those for CyCH(1)-DMSO(2) are A 1,2 = 1.2570, A 2,1 = -3.5029, B 1,2 = -153.12, B 2,1 = -68.31, C 1,2 = 10500, C 2,1 = 31000. Using these values satisfactory results of h E data correlation for the systems cyclohexane-furfural and dimethyl sulfoxide-cyclohexanol were obtained. Also, it was shown that if the group interaction parameters ArCH and CH 2 were generated from the n-hexane-toluene h E data, the quality of the results was significantly improved, when compared with those obtained using the parameters from the literature.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Determination of new ASOG-H parameters of CyCH, furfural and DMSO groups",
pages = "348-343",
number = "4-5",
volume = "61",
url = "conv_7345"
}
Kaluđerović, T., Šerbanović, S. P., Tasić, A. Ž.,& Đorđević, B.D.. (1996). Determination of new ASOG-H parameters of CyCH, furfural and DMSO groups. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 61(4-5), 343-348.
conv_7345
Kaluđerović T, Šerbanović SP, Tasić AŽ, Đorđević B. Determination of new ASOG-H parameters of CyCH, furfural and DMSO groups. in Journal of the Serbian Chemical Society. 1996;61(4-5):343-348.
conv_7345 .
Kaluđerović, Tatjana, Šerbanović, Slobodan P., Tasić, Aleksandar Ž., Đorđević, B.D., "Determination of new ASOG-H parameters of CyCH, furfural and DMSO groups" in Journal of the Serbian Chemical Society, 61, no. 4-5 (1996):343-348,
conv_7345 .
