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Determination of new ASOG-H parameters of CyCH, furfural and DMSO groups
dc.creator | Kaluđerović, Tatjana | |
dc.creator | Šerbanović, Slobodan P. | |
dc.creator | Tasić, Aleksandar Ž. | |
dc.creator | Đorđević, B.D. | |
dc.date.accessioned | 2021-03-10T09:37:21Z | |
dc.date.available | 2021-03-10T09:37:21Z | |
dc.date.issued | 1996 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/73 | |
dc.description.abstract | New interaction parameters for the groups CYCH(1)-furfural(2) and CyCH(1)-DMSO(2) of the ASOG-H model were determined, for 293.15 K-323.15 K and 303.15 K-323.15K respectively. The values of the CyCH(1)-furfural(2) parameters are A 1,2 = 1.2259, A 2,1 = -0.6307, B 1,2 = -36.57, B 2,1 = 63.32, C 1,2 = 9300, C 2,1 = -29317, whereas those for CyCH(1)-DMSO(2) are A 1,2 = 1.2570, A 2,1 = -3.5029, B 1,2 = -153.12, B 2,1 = -68.31, C 1,2 = 10500, C 2,1 = 31000. Using these values satisfactory results of h E data correlation for the systems cyclohexane-furfural and dimethyl sulfoxide-cyclohexanol were obtained. Also, it was shown that if the group interaction parameters ArCH and CH 2 were generated from the n-hexane-toluene h E data, the quality of the results was significantly improved, when compared with those obtained using the parameters from the literature. | en |
dc.publisher | Serbian Chemical Society, Belgrade | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Journal of the Serbian Chemical Society | |
dc.subject | ASOG-H | en |
dc.subject | Excess enthalpies | en |
dc.subject | Interaction parameters | en |
dc.title | Determination of new ASOG-H parameters of CyCH, furfural and DMSO groups | en |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dc.citation.epage | 348 | |
dc.citation.issue | 4-5 | |
dc.citation.other | 61(4-5): 343-348 | |
dc.citation.spage | 343 | |
dc.citation.volume | 61 | |
dc.identifier.pmid | ||
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_technorep_73 | |
dc.identifier.scopus | 2-s2.0-0040058466 | |
dc.type.version | publishedVersion |
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