Photocatalytic and antimicrobial effects of zinc oxide nanoparticles prepared by thermal decomposition of zinc benzenepolycarboxylato complexes
Аутори
Rogan, JelenaRadovanović, Lidija
Simović, Bojana
Radovanović, Željko
Mihajlovski, Katarina
Dapčević, Aleksandra
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Zinc oxide nanoparticles (ZnO-NPs) have been a subject of numerous researches owing to their multifunctional properties in many applications, such as solar cells, UV light-emitting devices, gas sensors and photocatalysts. ZnO-NPs can be synthesized through various methods and their features can be tailored by shape and size, resulting in new applications relevant to their structural properties. The synthesis of ZnO-NPs via controlled thermal decomposition of the single-source precursors represents a novel synthetic methodology. The basic goal of this study was to investigate the influence of precursors on crystallite size and morphology of the resulting ZnO-NPs. Four structurally characterized Zn complexes with different benzenepolycarboxylato ligands [1] were used as precursors for investigation of photocatalytic and antimicrobial effects of thermally obtained ZnO-NPs. The XRPD and FESEM analysis of ZnO-NPs, prepared by thermolysis of Zn precursors at 450 °C in the air atmosphere, rev...ealed hexagonal wurtzite structure (space group P63mc, a ≈ 3.25 and c ≈ 5.21 Å) with an average crystallite size in the range of 39–47 nm and similar morphology. The best photocatalytic activity for degradation of Reactive orange 16 dye has been observed for ZnO-NPs where crystallites form the smallest agglomerates. All obtained ZnO-NPs showed excellent inhibitory effect against Gram-positive bacteria Staphylococcus aureus and Gram-negative bacteria Escherichia coli.
Кључне речи:
Thermal decomposition / Zinc oxide nanoparticles / Photocatalytic activity / Antimicrobial activityИзвор:
Book of Abstracts / The European Powder Diffraction Conference EPDIC 17, Šibenik, Croatia, 31 May – 03 June 2022, 2022, 127-Издавач:
- Zagreb : Croatian Association of Crystallographers
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200135 (Универзитет у Београду, Технолошко-металуршки факултет) (RS-MESTD-inst-2020-200135)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200287 (Иновациони центар Технолошко-металуршког факултета у Београду доо) (RS-MESTD-inst-2020-200287)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200053 (Универзитет у Београду, Институт за мултидисциплинарна истраживања) (RS-MESTD-inst-2020-200053)
Колекције
Институција/група
Tehnološko-metalurški fakultetTY - CONF AU - Rogan, Jelena AU - Radovanović, Lidija AU - Simović, Bojana AU - Radovanović, Željko AU - Mihajlovski, Katarina AU - Dapčević, Aleksandra PY - 2022 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/7404 AB - Zinc oxide nanoparticles (ZnO-NPs) have been a subject of numerous researches owing to their multifunctional properties in many applications, such as solar cells, UV light-emitting devices, gas sensors and photocatalysts. ZnO-NPs can be synthesized through various methods and their features can be tailored by shape and size, resulting in new applications relevant to their structural properties. The synthesis of ZnO-NPs via controlled thermal decomposition of the single-source precursors represents a novel synthetic methodology. The basic goal of this study was to investigate the influence of precursors on crystallite size and morphology of the resulting ZnO-NPs. Four structurally characterized Zn complexes with different benzenepolycarboxylato ligands [1] were used as precursors for investigation of photocatalytic and antimicrobial effects of thermally obtained ZnO-NPs. The XRPD and FESEM analysis of ZnO-NPs, prepared by thermolysis of Zn precursors at 450 °C in the air atmosphere, revealed hexagonal wurtzite structure (space group P63mc, a ≈ 3.25 and c ≈ 5.21 Å) with an average crystallite size in the range of 39–47 nm and similar morphology. The best photocatalytic activity for degradation of Reactive orange 16 dye has been observed for ZnO-NPs where crystallites form the smallest agglomerates. All obtained ZnO-NPs showed excellent inhibitory effect against Gram-positive bacteria Staphylococcus aureus and Gram-negative bacteria Escherichia coli. PB - Zagreb : Croatian Association of Crystallographers C3 - Book of Abstracts / The European Powder Diffraction Conference EPDIC 17, Šibenik, Croatia, 31 May – 03 June 2022 T1 - Photocatalytic and antimicrobial effects of zinc oxide nanoparticles prepared by thermal decomposition of zinc benzenepolycarboxylato complexes SP - 127 UR - https://hdl.handle.net/21.15107/rcub_technorep_7404 ER -
@conference{ author = "Rogan, Jelena and Radovanović, Lidija and Simović, Bojana and Radovanović, Željko and Mihajlovski, Katarina and Dapčević, Aleksandra", year = "2022", abstract = "Zinc oxide nanoparticles (ZnO-NPs) have been a subject of numerous researches owing to their multifunctional properties in many applications, such as solar cells, UV light-emitting devices, gas sensors and photocatalysts. ZnO-NPs can be synthesized through various methods and their features can be tailored by shape and size, resulting in new applications relevant to their structural properties. The synthesis of ZnO-NPs via controlled thermal decomposition of the single-source precursors represents a novel synthetic methodology. The basic goal of this study was to investigate the influence of precursors on crystallite size and morphology of the resulting ZnO-NPs. Four structurally characterized Zn complexes with different benzenepolycarboxylato ligands [1] were used as precursors for investigation of photocatalytic and antimicrobial effects of thermally obtained ZnO-NPs. The XRPD and FESEM analysis of ZnO-NPs, prepared by thermolysis of Zn precursors at 450 °C in the air atmosphere, revealed hexagonal wurtzite structure (space group P63mc, a ≈ 3.25 and c ≈ 5.21 Å) with an average crystallite size in the range of 39–47 nm and similar morphology. The best photocatalytic activity for degradation of Reactive orange 16 dye has been observed for ZnO-NPs where crystallites form the smallest agglomerates. All obtained ZnO-NPs showed excellent inhibitory effect against Gram-positive bacteria Staphylococcus aureus and Gram-negative bacteria Escherichia coli.", publisher = "Zagreb : Croatian Association of Crystallographers", journal = "Book of Abstracts / The European Powder Diffraction Conference EPDIC 17, Šibenik, Croatia, 31 May – 03 June 2022", title = "Photocatalytic and antimicrobial effects of zinc oxide nanoparticles prepared by thermal decomposition of zinc benzenepolycarboxylato complexes", pages = "127", url = "https://hdl.handle.net/21.15107/rcub_technorep_7404" }
Rogan, J., Radovanović, L., Simović, B., Radovanović, Ž., Mihajlovski, K.,& Dapčević, A.. (2022). Photocatalytic and antimicrobial effects of zinc oxide nanoparticles prepared by thermal decomposition of zinc benzenepolycarboxylato complexes. in Book of Abstracts / The European Powder Diffraction Conference EPDIC 17, Šibenik, Croatia, 31 May – 03 June 2022 Zagreb : Croatian Association of Crystallographers., 127. https://hdl.handle.net/21.15107/rcub_technorep_7404
Rogan J, Radovanović L, Simović B, Radovanović Ž, Mihajlovski K, Dapčević A. Photocatalytic and antimicrobial effects of zinc oxide nanoparticles prepared by thermal decomposition of zinc benzenepolycarboxylato complexes. in Book of Abstracts / The European Powder Diffraction Conference EPDIC 17, Šibenik, Croatia, 31 May – 03 June 2022. 2022;:127. https://hdl.handle.net/21.15107/rcub_technorep_7404 .
Rogan, Jelena, Radovanović, Lidija, Simović, Bojana, Radovanović, Željko, Mihajlovski, Katarina, Dapčević, Aleksandra, "Photocatalytic and antimicrobial effects of zinc oxide nanoparticles prepared by thermal decomposition of zinc benzenepolycarboxylato complexes" in Book of Abstracts / The European Powder Diffraction Conference EPDIC 17, Šibenik, Croatia, 31 May – 03 June 2022 (2022):127, https://hdl.handle.net/21.15107/rcub_technorep_7404 .