The non-oxidative thermal degradation of poly(di-n-alkyl itaconates). I. Analysis of the thermolysis volatiles
Abstract
The volatiles arising from the thermal degradation of poly(di-n-alkyl itaconates) with ester substituents ranging from methyl to n-octyl were analysed. The corresponding monomer was found to be the major degradation product. A significant amount of itaconic acid in the volatiles was also found in the case of poly(diethyl itaconate). A detailed mechanism of the thermal degradation of the studied polymers is given.
Keywords:
thermal degradation / polyitaconates / volatiles / mechanismSource:
Polymer Degradation and Stability, 2005, 89, 1, 153-164Publisher:
- Elsevier Sci Ltd, Oxford
DOI: 10.1016/j.polymdegradstab.2005.01.012
ISSN: 0141-3910
WoS: 000229569500018
Scopus: 2-s2.0-17044398163
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Popović, Ivanka AU - Katsikas, Lynne AU - Veličković, Jovan S. PY - 2005 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/820 AB - The volatiles arising from the thermal degradation of poly(di-n-alkyl itaconates) with ester substituents ranging from methyl to n-octyl were analysed. The corresponding monomer was found to be the major degradation product. A significant amount of itaconic acid in the volatiles was also found in the case of poly(diethyl itaconate). A detailed mechanism of the thermal degradation of the studied polymers is given. PB - Elsevier Sci Ltd, Oxford T2 - Polymer Degradation and Stability T1 - The non-oxidative thermal degradation of poly(di-n-alkyl itaconates). I. Analysis of the thermolysis volatiles EP - 164 IS - 1 SP - 153 VL - 89 DO - 10.1016/j.polymdegradstab.2005.01.012 ER -
@article{ author = "Popović, Ivanka and Katsikas, Lynne and Veličković, Jovan S.", year = "2005", abstract = "The volatiles arising from the thermal degradation of poly(di-n-alkyl itaconates) with ester substituents ranging from methyl to n-octyl were analysed. The corresponding monomer was found to be the major degradation product. A significant amount of itaconic acid in the volatiles was also found in the case of poly(diethyl itaconate). A detailed mechanism of the thermal degradation of the studied polymers is given.", publisher = "Elsevier Sci Ltd, Oxford", journal = "Polymer Degradation and Stability", title = "The non-oxidative thermal degradation of poly(di-n-alkyl itaconates). I. Analysis of the thermolysis volatiles", pages = "164-153", number = "1", volume = "89", doi = "10.1016/j.polymdegradstab.2005.01.012" }
Popović, I., Katsikas, L.,& Veličković, J. S.. (2005). The non-oxidative thermal degradation of poly(di-n-alkyl itaconates). I. Analysis of the thermolysis volatiles. in Polymer Degradation and Stability Elsevier Sci Ltd, Oxford., 89(1), 153-164. https://doi.org/10.1016/j.polymdegradstab.2005.01.012
Popović I, Katsikas L, Veličković JS. The non-oxidative thermal degradation of poly(di-n-alkyl itaconates). I. Analysis of the thermolysis volatiles. in Polymer Degradation and Stability. 2005;89(1):153-164. doi:10.1016/j.polymdegradstab.2005.01.012 .
Popović, Ivanka, Katsikas, Lynne, Veličković, Jovan S., "The non-oxidative thermal degradation of poly(di-n-alkyl itaconates). I. Analysis of the thermolysis volatiles" in Polymer Degradation and Stability, 89, no. 1 (2005):153-164, https://doi.org/10.1016/j.polymdegradstab.2005.01.012 . .