Synthesis and characterization of a new chiral polyurea-based catalyst

dc.creator	Dunjić, Branko
dc.creator	Gamez, P
dc.creator	Fache, F
dc.creator	Lemaire, M
dc.date.accessioned	2021-03-10T09:38:32Z
dc.date.available	2021-03-10T09:38:32Z
dc.date.issued	1996
dc.identifier.issn	0021-8995
dc.identifier.uri	http://TechnoRep.tmf.bg.ac.rs/handle/123456789/92
dc.description.abstract	A series of chiral poly(urea)s was synthesized by solution polyaddition. The polymers are characterized by NMR, FTIR, DSC, viscosimetry, and microanalysis. After deposition of the rhodium, the insoluble chiral polymers were used as catalysts in the reduction of acetophenone by hydrogen transfer. The influence of the structure of the polymers on the catalytic activity and selectivity was investigated. The enantiomeric excesses (e.e.) obtained were up to 60%, and the polymeric catalysts were reused without loss of activity and selectivity.	en
dc.publisher	John Wiley & Sons Inc, New York
dc.rights	restrictedAccess
dc.source	Journal of Applied Polymer Science
dc.title	Synthesis and characterization of a new chiral polyurea-based catalyst	en
dc.type	article
dc.rights.license	ARR
dc.citation.epage	1262
dc.citation.issue	8
dc.citation.other	59(8): 1255-1262
dc.citation.spage	1255
dc.citation.volume	59
dc.identifier.doi	10.1002/(SICI)1097-4628(19960222)59:81255::AID-APP83.0.CO;2-B
dc.identifier.scopus	2-s2.0-0030085530
dc.identifier.wos	A1996TR92400008
dc.type.version	publishedVersion