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dc.creatorJugović, Branimir
dc.creatorTrišović, Tomislav
dc.creatorStevanović, Jasmina
dc.creatorMaksimović, Miodrag D.
dc.creatorGrgur, Branimir
dc.date.accessioned2021-03-10T10:33:09Z
dc.date.available2021-03-10T10:33:09Z
dc.date.issued2006
dc.identifier.issn0013-4686
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/933
dc.description.abstractElectrochemical behavior of zinc and thin polyaniline (PANI) polymerized from 0.1 M HCl to 0.1 M aniline on graphite electrode, in 0.2 M ZnCl(2) and 0.50 M NH(4)Cl (chloride electrolyte) and with addition of 0.33 M Na-citrate (chloride/citrate electrolyte) were investigated. In the chloride/citrate comparing with chloride containing electrolyte zinc electrode shows negative shift of the open circuit potential of similar to 130 mV, decreases of exchange current density for more than order of magnitude and increase of cathodic Tafel slope, due to the zinc ions complexation. In citrate/chloride electrolyte zinc dendrite formation were suppressed. In the range of investigated charge/discharge current densities of 0.25-1 mA cm(-2), initially obtained specific capacity was in the range of 140-85 mAh g(-1), respectively. In cycling regime specific capacity and columbic efficiency were affected with anodic potential limits. For anodic potential limits of 0.32 V (SCE) citrate/chloride electrolyte shows better characteristic than chloride electrolyte, due to the influence of citrate ions on negative shift of doping reaction. Increasing anodic potential limit to 0.5 V (SCE), leads to faster decrease of specific capacity in citrate/chloride than in chloride electrolyte, which was explained by higher hydrophilic effect of citrate anions.en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.rightsrestrictedAccess
dc.sourceElectrochimica Acta
dc.subjectpolyanilineen
dc.subjectzincen
dc.subjectbatteriesen
dc.subjectchlorideen
dc.subjectcitratesen
dc.subjectdendritesen
dc.titleComparative studies of chloride and chloride/citrate based electrolytes for zinc-polyaniline batteriesen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage6274
dc.citation.issue28
dc.citation.other51(28): 6268-6274
dc.citation.rankM21
dc.citation.spage6268
dc.citation.volume51
dc.identifier.doi10.1016/j.electacta.2006.04.009
dc.identifier.scopus2-s2.0-33747817733
dc.identifier.wos000240855100007
dc.type.versionpublishedVersion


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