Kinetic of corrosion reactions in acid and neutral solutions on electrochemically deposited Ni-W alloys
Kinetika korozionih reakcija u kiselim i neutralnim rastvorima na elektrohemijski taloženim legurama Ni-W
Abstract
Ni-W alloys were electrochemically deposited from an ammonia-citrate electrolyte on rotating disc electrode with a gold disc, by direct and pulsating current. The corrosion potential and kinetics of cathodic and anodic reaction were investigated on the alloys with molar fraction of tungsten from 0.11 to 0.25 in acid and neutral sulfate solutions of various pH. On the basis of kinetic equations resulting from these data, it was proposed that a barrier lazer of nickel and tungsten oxide was formed on the alloy surface preventing further alloy dissolution.
Prevlake legure Ni-W su elektrohemijski taložene iz amonijačno-citratnog elektrolita, na rotirajuću disk elektrodu od zlata, konstantnom i pulsirajućom strujom. Korozioni potencijal, kinetika katodne i anodne reakcije na elektrohemijski taloženim prevlakama legura Ni-W, sa udelom volframa od 0,11 do 0,25, su ispitivani u kiselim i neutralnim sulfatnim rastvorima, različitih pH vrednosti. Na osnovu dobijenih rezultata izvedene su kinetičke jednačine za katodnu i anodnu reakciju, koje ukazuju na formiranje barijernog sloja oksida volframa i nikla koji sprečava rastvaranje legure i delimično se redukuje pri katodnoj polarizaciji.
Keywords:
electrochemically deposited nickel-tungten alloys / corrosion potential / kinetic catodic and anodic current / elektrohemijsko taloženje / legura nikal-volfram / korozioni potencijal / kinetika katodne i anodne reakcijeSource:
Zaštita materijala, 2006, 47, 2, 3-10Publisher:
- Engineering Society for Corrosion, Belgrade, Serbia
Funding / projects:
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Obradović, Maja AU - Grgur, Branimir AU - Gojković, Snežana Lj. PY - 2006 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/982 AB - Ni-W alloys were electrochemically deposited from an ammonia-citrate electrolyte on rotating disc electrode with a gold disc, by direct and pulsating current. The corrosion potential and kinetics of cathodic and anodic reaction were investigated on the alloys with molar fraction of tungsten from 0.11 to 0.25 in acid and neutral sulfate solutions of various pH. On the basis of kinetic equations resulting from these data, it was proposed that a barrier lazer of nickel and tungsten oxide was formed on the alloy surface preventing further alloy dissolution. AB - Prevlake legure Ni-W su elektrohemijski taložene iz amonijačno-citratnog elektrolita, na rotirajuću disk elektrodu od zlata, konstantnom i pulsirajućom strujom. Korozioni potencijal, kinetika katodne i anodne reakcije na elektrohemijski taloženim prevlakama legura Ni-W, sa udelom volframa od 0,11 do 0,25, su ispitivani u kiselim i neutralnim sulfatnim rastvorima, različitih pH vrednosti. Na osnovu dobijenih rezultata izvedene su kinetičke jednačine za katodnu i anodnu reakciju, koje ukazuju na formiranje barijernog sloja oksida volframa i nikla koji sprečava rastvaranje legure i delimično se redukuje pri katodnoj polarizaciji. PB - Engineering Society for Corrosion, Belgrade, Serbia T2 - Zaštita materijala T1 - Kinetic of corrosion reactions in acid and neutral solutions on electrochemically deposited Ni-W alloys T1 - Kinetika korozionih reakcija u kiselim i neutralnim rastvorima na elektrohemijski taloženim legurama Ni-W EP - 10 IS - 2 SP - 3 VL - 47 UR - https://hdl.handle.net/21.15107/rcub_technorep_982 ER -
@article{ author = "Obradović, Maja and Grgur, Branimir and Gojković, Snežana Lj.", year = "2006", abstract = "Ni-W alloys were electrochemically deposited from an ammonia-citrate electrolyte on rotating disc electrode with a gold disc, by direct and pulsating current. The corrosion potential and kinetics of cathodic and anodic reaction were investigated on the alloys with molar fraction of tungsten from 0.11 to 0.25 in acid and neutral sulfate solutions of various pH. On the basis of kinetic equations resulting from these data, it was proposed that a barrier lazer of nickel and tungsten oxide was formed on the alloy surface preventing further alloy dissolution., Prevlake legure Ni-W su elektrohemijski taložene iz amonijačno-citratnog elektrolita, na rotirajuću disk elektrodu od zlata, konstantnom i pulsirajućom strujom. Korozioni potencijal, kinetika katodne i anodne reakcije na elektrohemijski taloženim prevlakama legura Ni-W, sa udelom volframa od 0,11 do 0,25, su ispitivani u kiselim i neutralnim sulfatnim rastvorima, različitih pH vrednosti. Na osnovu dobijenih rezultata izvedene su kinetičke jednačine za katodnu i anodnu reakciju, koje ukazuju na formiranje barijernog sloja oksida volframa i nikla koji sprečava rastvaranje legure i delimično se redukuje pri katodnoj polarizaciji.", publisher = "Engineering Society for Corrosion, Belgrade, Serbia", journal = "Zaštita materijala", title = "Kinetic of corrosion reactions in acid and neutral solutions on electrochemically deposited Ni-W alloys, Kinetika korozionih reakcija u kiselim i neutralnim rastvorima na elektrohemijski taloženim legurama Ni-W", pages = "10-3", number = "2", volume = "47", url = "https://hdl.handle.net/21.15107/rcub_technorep_982" }
Obradović, M., Grgur, B.,& Gojković, S. Lj.. (2006). Kinetic of corrosion reactions in acid and neutral solutions on electrochemically deposited Ni-W alloys. in Zaštita materijala Engineering Society for Corrosion, Belgrade, Serbia., 47(2), 3-10. https://hdl.handle.net/21.15107/rcub_technorep_982
Obradović M, Grgur B, Gojković SL. Kinetic of corrosion reactions in acid and neutral solutions on electrochemically deposited Ni-W alloys. in Zaštita materijala. 2006;47(2):3-10. https://hdl.handle.net/21.15107/rcub_technorep_982 .
Obradović, Maja, Grgur, Branimir, Gojković, Snežana Lj., "Kinetic of corrosion reactions in acid and neutral solutions on electrochemically deposited Ni-W alloys" in Zaštita materijala, 47, no. 2 (2006):3-10, https://hdl.handle.net/21.15107/rcub_technorep_982 .