Double-layer bioactive glass coatings obtained by pulsed laser deposition
Нема приказа
Аутори
Tanasković, DušankaVeljović, Đorđe
Petrović, Rada
Janaćković, Đorđe
Mitrić, Miodrag
Cojanu, C.
Ristoscu, Carmen
Mihailescu, Ion N.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Pulsed laser deposition was used to obtain functionally graded bioactive glass coatings on titanium substrates. An UV KrF* (lambda=248 nm, tau gt 7 ns) excimer laser was used for the multi-pulse irradiation of the targets. The depositions were performed in oxygen while keeping substrate temperature at 400 degrees C. We used sintered glass targets in the system SiO2-Na2O-K2O-CaO-MgO-P2O5 that differed in SiO2 content, which was either 57 wt.% (6P57) or 61 wt.% (6P61). A glass 6P61 was used as the first layer in direct contact with the metallic substrate, while the outer bioactive layer was made of glass 6P57. Both the bioactive coatings and the bulk glasses were analyzed by Fourier transform infrared spectrometry (FTIR), grazing incidence X-ray diffraction (GIXRD), and scanning electron microscopy (SEM). The FTIR spectra of the glass powders and glass coatings showed the main vibration modes of the Si-O-Si groups. GIXRD analysis confirmed that the glass coatings had an amorphous structu...re. The SEM micrographs of the glass coatings showed the films to consist of droplets with diameters ranging from 0.2 to 5 Pm. SEM was used to determine the rate of apatite formation on the coating when exposed to simulated body fluid (SBF) solution for 7 days. We demonstrated that pulsed laser deposition leads to good glass-metal adhesion on the substrate and well attached bioactive particles on the surface. We consider therefore this method appropriate for forming implants that can develop an apatite layer after immersion in SBF.
Кључне речи:
bioactive glass / coatings / pulsed laser depositionИзвор:
Key Engineering Materials, 2008, 361-363 I, 277-280Издавач:
- Trans Tech Publications Ltd, Durnten-Zurich
Финансирање / пројекти:
- Синтеза, структура, својства и примена функционалних наноструктурних керамичких и биокерамичких материјала (RS-MESTD-MPN2006-2010-142070)
- Romanian Ministry of Education and Research [307/2006 - RETEBIOGLAS]
- EUREKA E!3033 Bionanocomposite
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Tanasković, Dušanka AU - Veljović, Đorđe AU - Petrović, Rada AU - Janaćković, Đorđe AU - Mitrić, Miodrag AU - Cojanu, C. AU - Ristoscu, Carmen AU - Mihailescu, Ion N. PY - 2008 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1220 AB - Pulsed laser deposition was used to obtain functionally graded bioactive glass coatings on titanium substrates. An UV KrF* (lambda=248 nm, tau gt 7 ns) excimer laser was used for the multi-pulse irradiation of the targets. The depositions were performed in oxygen while keeping substrate temperature at 400 degrees C. We used sintered glass targets in the system SiO2-Na2O-K2O-CaO-MgO-P2O5 that differed in SiO2 content, which was either 57 wt.% (6P57) or 61 wt.% (6P61). A glass 6P61 was used as the first layer in direct contact with the metallic substrate, while the outer bioactive layer was made of glass 6P57. Both the bioactive coatings and the bulk glasses were analyzed by Fourier transform infrared spectrometry (FTIR), grazing incidence X-ray diffraction (GIXRD), and scanning electron microscopy (SEM). The FTIR spectra of the glass powders and glass coatings showed the main vibration modes of the Si-O-Si groups. GIXRD analysis confirmed that the glass coatings had an amorphous structure. The SEM micrographs of the glass coatings showed the films to consist of droplets with diameters ranging from 0.2 to 5 Pm. SEM was used to determine the rate of apatite formation on the coating when exposed to simulated body fluid (SBF) solution for 7 days. We demonstrated that pulsed laser deposition leads to good glass-metal adhesion on the substrate and well attached bioactive particles on the surface. We consider therefore this method appropriate for forming implants that can develop an apatite layer after immersion in SBF. PB - Trans Tech Publications Ltd, Durnten-Zurich T2 - Key Engineering Materials T1 - Double-layer bioactive glass coatings obtained by pulsed laser deposition EP - 280 SP - 277 VL - 361-363 I UR - https://hdl.handle.net/21.15107/rcub_vinar_6718 ER -
@article{ author = "Tanasković, Dušanka and Veljović, Đorđe and Petrović, Rada and Janaćković, Đorđe and Mitrić, Miodrag and Cojanu, C. and Ristoscu, Carmen and Mihailescu, Ion N.", year = "2008", abstract = "Pulsed laser deposition was used to obtain functionally graded bioactive glass coatings on titanium substrates. An UV KrF* (lambda=248 nm, tau gt 7 ns) excimer laser was used for the multi-pulse irradiation of the targets. The depositions were performed in oxygen while keeping substrate temperature at 400 degrees C. We used sintered glass targets in the system SiO2-Na2O-K2O-CaO-MgO-P2O5 that differed in SiO2 content, which was either 57 wt.% (6P57) or 61 wt.% (6P61). A glass 6P61 was used as the first layer in direct contact with the metallic substrate, while the outer bioactive layer was made of glass 6P57. Both the bioactive coatings and the bulk glasses were analyzed by Fourier transform infrared spectrometry (FTIR), grazing incidence X-ray diffraction (GIXRD), and scanning electron microscopy (SEM). The FTIR spectra of the glass powders and glass coatings showed the main vibration modes of the Si-O-Si groups. GIXRD analysis confirmed that the glass coatings had an amorphous structure. The SEM micrographs of the glass coatings showed the films to consist of droplets with diameters ranging from 0.2 to 5 Pm. SEM was used to determine the rate of apatite formation on the coating when exposed to simulated body fluid (SBF) solution for 7 days. We demonstrated that pulsed laser deposition leads to good glass-metal adhesion on the substrate and well attached bioactive particles on the surface. We consider therefore this method appropriate for forming implants that can develop an apatite layer after immersion in SBF.", publisher = "Trans Tech Publications Ltd, Durnten-Zurich", journal = "Key Engineering Materials", title = "Double-layer bioactive glass coatings obtained by pulsed laser deposition", pages = "280-277", volume = "361-363 I", url = "https://hdl.handle.net/21.15107/rcub_vinar_6718" }
Tanasković, D., Veljović, Đ., Petrović, R., Janaćković, Đ., Mitrić, M., Cojanu, C., Ristoscu, C.,& Mihailescu, I. N.. (2008). Double-layer bioactive glass coatings obtained by pulsed laser deposition. in Key Engineering Materials Trans Tech Publications Ltd, Durnten-Zurich., 361-363 I, 277-280. https://hdl.handle.net/21.15107/rcub_vinar_6718
Tanasković D, Veljović Đ, Petrović R, Janaćković Đ, Mitrić M, Cojanu C, Ristoscu C, Mihailescu IN. Double-layer bioactive glass coatings obtained by pulsed laser deposition. in Key Engineering Materials. 2008;361-363 I:277-280. https://hdl.handle.net/21.15107/rcub_vinar_6718 .
Tanasković, Dušanka, Veljović, Đorđe, Petrović, Rada, Janaćković, Đorđe, Mitrić, Miodrag, Cojanu, C., Ristoscu, Carmen, Mihailescu, Ion N., "Double-layer bioactive glass coatings obtained by pulsed laser deposition" in Key Engineering Materials, 361-363 I (2008):277-280, https://hdl.handle.net/21.15107/rcub_vinar_6718 .