Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices
Само за регистроване кориснике
2008
Аутори
Radović, IvonaKijevčanin, Mirjana
Gabrijel, Marijan Z.
Šerbanović, Slobodan P.
Đorđević, Bojan D.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The excess molar volumes of 51 binary mixtures containing diverse groups of organic compounds: alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, pentan-1-ol, hexan-1-ol, and heptan-1-ol), (cyclo-) alkanes (hexane, heptane, octane, nonane, decane, undecane, dodecane, and cyclohexane), esters (diethyl carbonate and ethyl chloroacetate), aromatics (o-xylene, m-xylene, p-xylene, and ethylbenzene), ketones (acetone), and ethers (anisole), were predicted from the refractive index data, using three types of equations coupled with several different mixing rules for refractive index calculations: the Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton, and the Oster. These systems were chosen since they belong to different classes of organic species forming molecular interactions and intermolecular forces during mixing resulting in positive or negative, smaller or larger deviations from ideal behaviour. The obtained results were analysed in terms of the applied equation and mixing ru...le, the nature of compounds of the mixtures and the influence of alkyl chain length of the alkane or alcohol molecule.
Кључне речи:
excess molar volume / refractive index / prediction / binary systemsИзвор:
Chemical Papers, 2008, 62, 3, 302-312Издавач:
- Versita, Warsaw
Финансирање / пројекти:
- Примена хемијске термодинамике у феноменима преноса вишефазних вишекомпонентних система (RS-MESTD-MPN2006-2010-142064)
DOI: 10.2478/s11696-008-0027-x
ISSN: 0366-6352
WoS: 000256026900012
Scopus: 2-s2.0-44149091498
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Radović, Ivona AU - Kijevčanin, Mirjana AU - Gabrijel, Marijan Z. AU - Šerbanović, Slobodan P. AU - Đorđević, Bojan D. PY - 2008 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1299 AB - The excess molar volumes of 51 binary mixtures containing diverse groups of organic compounds: alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, pentan-1-ol, hexan-1-ol, and heptan-1-ol), (cyclo-) alkanes (hexane, heptane, octane, nonane, decane, undecane, dodecane, and cyclohexane), esters (diethyl carbonate and ethyl chloroacetate), aromatics (o-xylene, m-xylene, p-xylene, and ethylbenzene), ketones (acetone), and ethers (anisole), were predicted from the refractive index data, using three types of equations coupled with several different mixing rules for refractive index calculations: the Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton, and the Oster. These systems were chosen since they belong to different classes of organic species forming molecular interactions and intermolecular forces during mixing resulting in positive or negative, smaller or larger deviations from ideal behaviour. The obtained results were analysed in terms of the applied equation and mixing rule, the nature of compounds of the mixtures and the influence of alkyl chain length of the alkane or alcohol molecule. PB - Versita, Warsaw T2 - Chemical Papers T1 - Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices EP - 312 IS - 3 SP - 302 VL - 62 DO - 10.2478/s11696-008-0027-x ER -
@article{ author = "Radović, Ivona and Kijevčanin, Mirjana and Gabrijel, Marijan Z. and Šerbanović, Slobodan P. and Đorđević, Bojan D.", year = "2008", abstract = "The excess molar volumes of 51 binary mixtures containing diverse groups of organic compounds: alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, pentan-1-ol, hexan-1-ol, and heptan-1-ol), (cyclo-) alkanes (hexane, heptane, octane, nonane, decane, undecane, dodecane, and cyclohexane), esters (diethyl carbonate and ethyl chloroacetate), aromatics (o-xylene, m-xylene, p-xylene, and ethylbenzene), ketones (acetone), and ethers (anisole), were predicted from the refractive index data, using three types of equations coupled with several different mixing rules for refractive index calculations: the Lorentz-Lorenz, Dale-Gladstone, Eykman, Arago-Biot, Newton, and the Oster. These systems were chosen since they belong to different classes of organic species forming molecular interactions and intermolecular forces during mixing resulting in positive or negative, smaller or larger deviations from ideal behaviour. The obtained results were analysed in terms of the applied equation and mixing rule, the nature of compounds of the mixtures and the influence of alkyl chain length of the alkane or alcohol molecule.", publisher = "Versita, Warsaw", journal = "Chemical Papers", title = "Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices", pages = "312-302", number = "3", volume = "62", doi = "10.2478/s11696-008-0027-x" }
Radović, I., Kijevčanin, M., Gabrijel, M. Z., Šerbanović, S. P.,& Đorđević, B. D.. (2008). Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices. in Chemical Papers Versita, Warsaw., 62(3), 302-312. https://doi.org/10.2478/s11696-008-0027-x
Radović I, Kijevčanin M, Gabrijel MZ, Šerbanović SP, Đorđević BD. Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices. in Chemical Papers. 2008;62(3):302-312. doi:10.2478/s11696-008-0027-x .
Radović, Ivona, Kijevčanin, Mirjana, Gabrijel, Marijan Z., Šerbanović, Slobodan P., Đorđević, Bojan D., "Prediction of excess molar volumes of binary mixtures of organic compounds from refractive indices" in Chemical Papers, 62, no. 3 (2008):302-312, https://doi.org/10.2478/s11696-008-0027-x . .