The thermal degradation kinetics of isomeric poly(dipropyl, itaconates)
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1997
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Metapodaci
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Non-isothermal thermogravimetry was performed in a dynamic nitrogen atmosphere, on a series of poly(di-n-propyl itaconates) (PDnPI) and poly(di-iso-propyl itaconates) (PDiPI) which had been prepared in the presence of various amounts of the chain transfer agent n-dodecyl mercaptan (DDM). Differential thermogravimetry (DTG) showed that both polymers degraded in two stages. The DTG curve of PDnP1 had a large first peak followed by a smaller shoulder, whereas the DTG curve of PDiPI was composed of two peaks of almost equal heights. The addition of DDM during the polymerisations in both cases resulted in a similar decrease in the relative area of the first peak.
Ključne reči:
kinetics / poly(di-propyl itaconates) / polymer structure / thermal degradationIzvor:
Journal of Thermal Analysis and Calorimetry, 1997, 49, 1, 87-94Izdavač:
- Springer, Dordrecht
DOI: 10.1007/BF01987424
ISSN: 1388-6150
WoS: A1997XD48000010
Scopus: 2-s2.0-0030646515
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Katsikas, Lynne AU - Paunović, I AU - Popović, Ivanka PY - 1997 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/142 AB - Non-isothermal thermogravimetry was performed in a dynamic nitrogen atmosphere, on a series of poly(di-n-propyl itaconates) (PDnPI) and poly(di-iso-propyl itaconates) (PDiPI) which had been prepared in the presence of various amounts of the chain transfer agent n-dodecyl mercaptan (DDM). Differential thermogravimetry (DTG) showed that both polymers degraded in two stages. The DTG curve of PDnP1 had a large first peak followed by a smaller shoulder, whereas the DTG curve of PDiPI was composed of two peaks of almost equal heights. The addition of DDM during the polymerisations in both cases resulted in a similar decrease in the relative area of the first peak. PB - Springer, Dordrecht T2 - Journal of Thermal Analysis and Calorimetry T1 - The thermal degradation kinetics of isomeric poly(dipropyl, itaconates) EP - 94 IS - 1 SP - 87 VL - 49 DO - 10.1007/BF01987424 ER -
@article{ author = "Katsikas, Lynne and Paunović, I and Popović, Ivanka", year = "1997", abstract = "Non-isothermal thermogravimetry was performed in a dynamic nitrogen atmosphere, on a series of poly(di-n-propyl itaconates) (PDnPI) and poly(di-iso-propyl itaconates) (PDiPI) which had been prepared in the presence of various amounts of the chain transfer agent n-dodecyl mercaptan (DDM). Differential thermogravimetry (DTG) showed that both polymers degraded in two stages. The DTG curve of PDnP1 had a large first peak followed by a smaller shoulder, whereas the DTG curve of PDiPI was composed of two peaks of almost equal heights. The addition of DDM during the polymerisations in both cases resulted in a similar decrease in the relative area of the first peak.", publisher = "Springer, Dordrecht", journal = "Journal of Thermal Analysis and Calorimetry", title = "The thermal degradation kinetics of isomeric poly(dipropyl, itaconates)", pages = "94-87", number = "1", volume = "49", doi = "10.1007/BF01987424" }
Katsikas, L., Paunović, I.,& Popović, I.. (1997). The thermal degradation kinetics of isomeric poly(dipropyl, itaconates). in Journal of Thermal Analysis and Calorimetry Springer, Dordrecht., 49(1), 87-94. https://doi.org/10.1007/BF01987424
Katsikas L, Paunović I, Popović I. The thermal degradation kinetics of isomeric poly(dipropyl, itaconates). in Journal of Thermal Analysis and Calorimetry. 1997;49(1):87-94. doi:10.1007/BF01987424 .
Katsikas, Lynne, Paunović, I, Popović, Ivanka, "The thermal degradation kinetics of isomeric poly(dipropyl, itaconates)" in Journal of Thermal Analysis and Calorimetry, 49, no. 1 (1997):87-94, https://doi.org/10.1007/BF01987424 . .