PMMA-Y2O3 (Eu3+) nanocomposites: Optical and mechanical properties
Nanokompozit PMMA-Y2O3 (Eu3+) - optička i mehanička svojstva
2011
Autori
Musbah, Salah S.Radojević, Vesna
Borna, Nadežda V.
Stojanović, Dušica
Dramićanin, Miroslav
Marinković, Aleksandar
Aleksić, Radoslav
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The results of a study related to the processing and characterization of poly(methyl methacrylate) (PMMA)-Y2O3 (Eu3+) nanocomposites are presented herein. The nanocomposite samples were prepared using a laboratory mixing molder with different contents of Eu-ion doped Y2O3 nanophosphor powder. The influence of particle content on the optical and dynamic mechanical properties of the nanocomposites was investigated. The intensity of the luminescence emission spectra increased as the nanophosphor content in the composite increased. The results of dynamic mechanical analysis revealed that the storage modulus, loss modulus and glass transition temperature (Tg) of the polymer composites increased with increasing content of the nanophosphor powder. The microhardness data also confirmed that the hardness number increased with nanoparticles concentration in the PMMA nanocomposites. The obtained results revealed a relatively linear relationship between Tg and the Vickers hardness.
U okviru ovog rada prezentovano je istraživanje procesiranja i karakterizacije nanokompozitnog materijala poli(metil-metakrilat) (PMMA)-Y2O3 (Eu3+). Uzorci sa različitim sadržajem nanofosfora Y2O3 dopiranog sa Eu jonima procesirani su u laboratorijskom uređaju za umešavanje termoplastičnih polimera. Ispitivan je uticaj udela nanočestica na optička i dinamičko-mehanička svojstva kompozita. Intenzitet luminiscentnog emisionog spektra kompozita raste sa udelom nanofosfora. Rezultati DMA pokazuju da modul deponovane energije, modul gubitaka i temperatura transformacije rastu sa povećanjem udela nanočestica. Mikrotvrdoća kompozita takođe raste sa povećanjem udela nanočestica u kompozitu i pokazuje skoro linearnu zavisnost od temperature transformacije (Tg).
Ključne reči:
nanocomposites / luminescence / mechanical properties / dynamic mechanical analysis / microhardnessIzvor:
Journal of the Serbian Chemical Society, 2011, 76, 8, 1153-1161Izdavač:
- Serbian Chemical Society, Belgrade
Finansiranje / projekti:
- Razvoj tehnologije i poluindustrijskih postrojenja za dobijanje staklenih, polimernih i hibridnih kompozitnih svetlovodnih kablova (RS-MESTD-MPN2006-2010-19047)
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Musbah, Salah S. AU - Radojević, Vesna AU - Borna, Nadežda V. AU - Stojanović, Dušica AU - Dramićanin, Miroslav AU - Marinković, Aleksandar AU - Aleksić, Radoslav PY - 2011 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1799 AB - The results of a study related to the processing and characterization of poly(methyl methacrylate) (PMMA)-Y2O3 (Eu3+) nanocomposites are presented herein. The nanocomposite samples were prepared using a laboratory mixing molder with different contents of Eu-ion doped Y2O3 nanophosphor powder. The influence of particle content on the optical and dynamic mechanical properties of the nanocomposites was investigated. The intensity of the luminescence emission spectra increased as the nanophosphor content in the composite increased. The results of dynamic mechanical analysis revealed that the storage modulus, loss modulus and glass transition temperature (Tg) of the polymer composites increased with increasing content of the nanophosphor powder. The microhardness data also confirmed that the hardness number increased with nanoparticles concentration in the PMMA nanocomposites. The obtained results revealed a relatively linear relationship between Tg and the Vickers hardness. AB - U okviru ovog rada prezentovano je istraživanje procesiranja i karakterizacije nanokompozitnog materijala poli(metil-metakrilat) (PMMA)-Y2O3 (Eu3+). Uzorci sa različitim sadržajem nanofosfora Y2O3 dopiranog sa Eu jonima procesirani su u laboratorijskom uređaju za umešavanje termoplastičnih polimera. Ispitivan je uticaj udela nanočestica na optička i dinamičko-mehanička svojstva kompozita. Intenzitet luminiscentnog emisionog spektra kompozita raste sa udelom nanofosfora. Rezultati DMA pokazuju da modul deponovane energije, modul gubitaka i temperatura transformacije rastu sa povećanjem udela nanočestica. Mikrotvrdoća kompozita takođe raste sa povećanjem udela nanočestica u kompozitu i pokazuje skoro linearnu zavisnost od temperature transformacije (Tg). PB - Serbian Chemical Society, Belgrade T2 - Journal of the Serbian Chemical Society T1 - PMMA-Y2O3 (Eu3+) nanocomposites: Optical and mechanical properties T1 - Nanokompozit PMMA-Y2O3 (Eu3+) - optička i mehanička svojstva EP - 1161 IS - 8 SP - 1153 VL - 76 UR - https://hdl.handle.net/21.15107/rcub_technorep_1799 ER -
@article{ author = "Musbah, Salah S. and Radojević, Vesna and Borna, Nadežda V. and Stojanović, Dušica and Dramićanin, Miroslav and Marinković, Aleksandar and Aleksić, Radoslav", year = "2011", abstract = "The results of a study related to the processing and characterization of poly(methyl methacrylate) (PMMA)-Y2O3 (Eu3+) nanocomposites are presented herein. The nanocomposite samples were prepared using a laboratory mixing molder with different contents of Eu-ion doped Y2O3 nanophosphor powder. The influence of particle content on the optical and dynamic mechanical properties of the nanocomposites was investigated. The intensity of the luminescence emission spectra increased as the nanophosphor content in the composite increased. The results of dynamic mechanical analysis revealed that the storage modulus, loss modulus and glass transition temperature (Tg) of the polymer composites increased with increasing content of the nanophosphor powder. The microhardness data also confirmed that the hardness number increased with nanoparticles concentration in the PMMA nanocomposites. The obtained results revealed a relatively linear relationship between Tg and the Vickers hardness., U okviru ovog rada prezentovano je istraživanje procesiranja i karakterizacije nanokompozitnog materijala poli(metil-metakrilat) (PMMA)-Y2O3 (Eu3+). Uzorci sa različitim sadržajem nanofosfora Y2O3 dopiranog sa Eu jonima procesirani su u laboratorijskom uređaju za umešavanje termoplastičnih polimera. Ispitivan je uticaj udela nanočestica na optička i dinamičko-mehanička svojstva kompozita. Intenzitet luminiscentnog emisionog spektra kompozita raste sa udelom nanofosfora. Rezultati DMA pokazuju da modul deponovane energije, modul gubitaka i temperatura transformacije rastu sa povećanjem udela nanočestica. Mikrotvrdoća kompozita takođe raste sa povećanjem udela nanočestica u kompozitu i pokazuje skoro linearnu zavisnost od temperature transformacije (Tg).", publisher = "Serbian Chemical Society, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "PMMA-Y2O3 (Eu3+) nanocomposites: Optical and mechanical properties, Nanokompozit PMMA-Y2O3 (Eu3+) - optička i mehanička svojstva", pages = "1161-1153", number = "8", volume = "76", url = "https://hdl.handle.net/21.15107/rcub_technorep_1799" }
Musbah, S. S., Radojević, V., Borna, N. V., Stojanović, D., Dramićanin, M., Marinković, A.,& Aleksić, R.. (2011). PMMA-Y2O3 (Eu3+) nanocomposites: Optical and mechanical properties. in Journal of the Serbian Chemical Society Serbian Chemical Society, Belgrade., 76(8), 1153-1161. https://hdl.handle.net/21.15107/rcub_technorep_1799
Musbah SS, Radojević V, Borna NV, Stojanović D, Dramićanin M, Marinković A, Aleksić R. PMMA-Y2O3 (Eu3+) nanocomposites: Optical and mechanical properties. in Journal of the Serbian Chemical Society. 2011;76(8):1153-1161. https://hdl.handle.net/21.15107/rcub_technorep_1799 .
Musbah, Salah S., Radojević, Vesna, Borna, Nadežda V., Stojanović, Dušica, Dramićanin, Miroslav, Marinković, Aleksandar, Aleksić, Radoslav, "PMMA-Y2O3 (Eu3+) nanocomposites: Optical and mechanical properties" in Journal of the Serbian Chemical Society, 76, no. 8 (2011):1153-1161, https://hdl.handle.net/21.15107/rcub_technorep_1799 .