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catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions
dc.creator | Rogan, Jelena | |
dc.creator | Poleti, Dejan | |
dc.creator | Karanović, Ljiljana | |
dc.date.accessioned | 2021-03-10T11:36:50Z | |
dc.date.available | 2021-03-10T11:36:50Z | |
dc.date.issued | 2011 | |
dc.identifier.issn | 0108-2701 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/1914 | |
dc.description.abstract | The novel title coordination polymer, {[Cu(C8H4O4)-(C10H9N3)]center dot H2O}(n), synthesized by the slow-diffusion method, takes the form of one-dimensional zigzag chains built up of Cu-II cations linked by benzene-1,3-dicarboxylate (ipht) anions. An exceptional characteristic of this structure is that it belongs to a small group of metal-organic polymers where ipht is coordinated as a bridging tridentate ligand with monodentate and chelate coordination of individual carboxylate groups. The Cu-II cation has a highly distorted square-pyramidal geometry formed by three O atoms from two ipht anions and two N atoms from a di-2-pyridylamine (dipya) ligand. The zigzag chains, which run along the b axis, further construct a three-dimensional metal-organic framework via strong face-to-face pi-pi interactions and hydrogen bonds. A solvent water molecule is linked to the different carboxylate groups via hydrogen bonds. Thermogravimetric and differential scanning calorimetric analyses confirm the strong hydrogen bonding. | en |
dc.publisher | Wiley-Blackwell, Hoboken | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45007/RS// | |
dc.rights | restrictedAccess | |
dc.source | Acta Crystallographica Section C-Crystal Structure Communications | |
dc.title | catena-Poly[[[(di-2-pyridylamine-kappa N-2(2),N-2 ')copper(II)]-mu-benzene-1,3-dicarboxylato-kappa O-3(1),O-1 ':O-3] monohydrate], a zigzag coordination polymer with strong pi-pi interactions | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | M233 | |
dc.citation.other | 67: M230-M233 | |
dc.citation.rank | M23 | |
dc.citation.spage | M230 | |
dc.citation.volume | 67 | |
dc.identifier.doi | 10.1107/S0108270111022451 | |
dc.identifier.pmid | 21727619 | |
dc.identifier.scopus | 2-s2.0-79959960186 | |
dc.identifier.wos | 000292468900008 | |
dc.type.version | publishedVersion |