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Preparation of aluminophosphate molecular sieves in the presence of nickel( II) and copper( II)
(Butterworth-Heinemann, 1991)
Nickel(ll)-substituted aluminophosphates of structure types 21 and 12 (NiAPO-21 and NiAPO-12) have been prepared hydrothermally in the presence of ethylenediamine as the template. U.v.-visible spectroscopy of NiAPO-21 ...
The structure of CoSAPO-34, containing i-propylamine as a template
(Butterworth-Heinemann, 1991)
The crystal structure of a cobalt silicoaluminophosphate, CoSAPO-34, is reported. The crystals belong to the rhombohedral R3 space group with unit cell parameters a = 13.797(7) and c = 14.898(7) A. The final R index was ...
On the possibility of the preparation open framework manganese phosphate
(Elsevier Inc., 1996)
Manganese(ll)/phosphate/organic template hydrothermal reactions were investigated with the aim of preparing novel crystalline porous materials. Ethylenediamine, isopropylamine, and piperidine were explored as organics that ...
Formation of AlPO4-15 and CoAPO-15 in the presence of hexamethylenetetramine
(Butterworth-Heinemann, 1990)
Two materials, AIPO4-15 and CoAPO-15, with the same aluminophosphate lattice have been obtained by hydrothermal synthesis in the presence of hexamethylenetetramine (HMTA). Their formation is attributed to the influence of ...
Synthesis and characterization of the CoSAPO- 14 and CoSAPO-34
(Butterworth Publishers, 1990)
The hydrothermal synthesis of CoSAPO-14 and CoSAPO-34 in the presence of isopropylamine as the template is described. CoSAPO-14 is a new MeSAPO material that predominantly forms at 125°C, whereas CoSAPO-34 is the main ...
A CoAPO-34 derived from a triclinic precursor prepared in the presence of HF
(Elsevier Science Inc., 1997)
The fluoride route of synthesis of AIPO,-34 is also successful in the preparation of its cobalt modified product (CoAPO-34). The triclinic precursor of CoAPO-34 has been synthesized in the presence of HF and piperidine. ...
A novel open framework zincophosphate: Synthesis and characterization
(Elsevier Science Inc., 1995)
The crystallization of a reactive zincophosphate gel (which may contain Co(ll) component) in the presence of sodium cations at ambient temperature and pressure yielded products (abbreviated ZnPO-HEX or CoZnPO-HEX) with a ...