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On the choice of optimal conformation in linear free-energy relationships. Reactivity of 2-[(carboxymethyl)sulfanyl]-4-oxo-4-arylbutanoic acids with diphenyldiazomethane
(Pergamon-Elsevier Science Ltd, Oxford, 2012)
Rate constants for the esterification of eleven 2-[(carboxymethyl)sulfanyl]-4-oxo-4-arylbutanoic acids with diphenyldiazomethane in ethanol at 30 degrees C were determined, and correlated with substituent constants using ...
Adding Value to the Oil Cake as a Waste from Oil Processing Industry: Production of Lipase and Protease by Candida utilis in Solid State Fermentation
(Springer, New York, 2012)
Olive oil cake is a by-product from the olive oil processing industry and can be used for the lipase and protease production by Candida utilis in solid state fermentation. Different carbon and nitrogen sources were evaluated, ...
Diffusion and solubility of commercial poly(methyl methacrylate) denture base material modified with dimethyl itaconate and di-n-butyl itaconate during water absorption/desorption cycles
(Wiley-Blackwell, Hoboken, 2012)
This study evaluated the water absorption, solubility, kinetics of water diffusion and residual monomer content of commercial poly(methyl methacrylate) (PMMA) denture base material modified with dimethyl itaconate (DMI) ...
The application of zeolite nanopowder for the construction of the dense composite polymer membranes for carbon dioxide separation
(Inst Materials Physics, Bucharest, 2012)
The main task of the work is to construct the polymeric membrane that could be used for the waste gases treatment. For this purpose, membrane must have high permeability for the carbon dioxide and low permeability of the ...
Covalently immobilized lipase catalyzing high-yielding optimized geranyl butyrate synthesis in a batch and fluidized bed reactor
(Elsevier, Amsterdam, 2012)
Three commercially available polymers (Sepabeads (R) EC-EP, Sepabeads (R) EC-HA and Purolite (R) A-109) were tested for potential application as supports for covalent immobilization of lipase from Candida rugosa by analyzing ...
Isolation of Hemoglobin from Bovine Erythrocytes by Controlled Hemolysis in the Membrane Bioreactor
(Springer, New York, 2012)
In this work, we describe an optimized procedure based on gradual hemolysis for the isolation of hemoglobin derived from bovine slaughterhouse erythrocytes in a membrane bioreactor. The membrane bioreactor system that ...
Production and ionization energies of KnF (n=2-6) clusters by thermal ionization mass spectrometry
(Wiley, Hoboken, 2012)
RATIONALE The very small clusters of the type KnF are of particular importance since their first ionization energies (IEs) are lower than those of the alkali metal atoms. Theoretical calculation has demonstrated that this ...
Formation of nano-plate silver particles in the presence of polyampholyte copolymer
(Elsevier Science Bv, Amsterdam, 2012)
Poly(2-(dimethylamino)ethyl methacrylate-co-acrylic acid) polyampholyte copolymers were synthesized by radical polymerization of the co-monomers in different molar ratios (2-1, 1-1 and 1-2). The water solutions of the ...
Microwave-assisted polyol synthesis of carbon-supported platinum-based bimetallic catalysts for ethanol oxidation
(Springer, New York, 2012)
High surface area carbon-supported Pt, PtRh, and PtSn catalysts were synthesized by microwave-assisted polyol procedure and tested for ethanol oxidation in perchloric acid. The catalysts were characterized by thermogravimetric ...
Improved Covalent Immobilization of Horseradish Peroxidase on Macroporous Glycidyl Methacrylate-Based Copolymers
(Springer, New York, 2012)
A macroporous copolymer of glycidyl methacrylate and ethylene glycol dimethacrylate, poly(GMA-co-EGDMA), with various surface characteristics and mean pore size diameters ranging from 44 to 200 nm was synthesized, modified ...