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Incorporation of Pt, Ru and Pt-Ru nanoparticles into ordered mesoporous carbons for efficient oxygen reduction reaction in alkaline media
(Electrochimica Acta, 2015)
Ordered mesoporous carbon, volume-doped up to 3w.% with Pt, Ru and Pt-Ru nanoparticles was synthesized by evaporation-induced self-assembly method, under acidic conditions. The content of incorporated metal was determined ...
Ni-Sn coatings as cathodes for hydrogen evolution in alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 2013)
In this work the hydrogen evolution reaction (HER) at Ni-Sn alloy coatings, deposited onto Ni 40 mesh at different current densities from the bath containing 0.1 mol dm(-3) SnCl2 + 0.3 mol dm(-3) NiCl2 in the pyrophosphate-glycine ...
Hydrogen peroxide oxidation on passive iron in alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 1992)
The kinetics of hydrogen peroxide oxidation were studied on passive iron in alkaline solutions of pH ranging from 9.8 to 13.8, using the rotating disk electrode. Measurements were taken using the linear sweep technique. ...
Oxygen reduction on iron-IV. The reduction of hydrogen peroxide as the intermediate in oxygen reduction reaction in alkaline solutions
(Pergamon-Elsevier Science Ltd, Oxford, 1991)
The kinetics of hydrogen peroxide reduction were studied on iron in borate buffered and unbuffered solutions of pH ranging from 8.6 to 13.8, with and without the presence of chloride ions. A rotating disk electrode was ...
Ti substrate coated with composite Cr–MoO2 coatings as highly selective cathode materials in hypochlorite production
(Elsevier, 2013)
The aim of this work was to investigate the possibility of preparation of the composite Cr–MoO2 coatings onto steel and titanium substrates as cathode materials with high selective properties which imply the suppression ...
The origin of high activity of Pt-Au surfaces in the formic acid oxidation
(Pergamon-Elsevier Science Ltd, Oxford, 2009)
We have investigated the oxidation of HCOOH on Au-modified Pt (Au"Pt) and Pt-modified Au (Pt")/Au) electrodes to establish the role of the ensemble and the electronic effect in the catalysis of this reaction. The surfaces ...
The effect of the electrode surface roughness at low level of coarseness on the polarization characteristics of electrochemical processes
(Pergamon-Elsevier Science Ltd, Oxford, 2010)
In this study, it is considered: (a) the effect of the exchange current density to the limiting diffusion current density ratio (J(0)/J(L)) at low level of surface coarseness on the polarization characteristics of the ...
Kinetics of the hydrogen evolution reaction on Fe-Mo film deposited on mild steel support in alkaline solution
(Pergamon-Elsevier Science Ltd, Oxford, 2005)
The mechanism and kinetics of the hydrogen evolution reaction were studied. in 1.0 mol dm(-3) NaOH solution on Fe-Mo alloy electrodes prepared by electrodeposition at constant current densities from a pyrophosphate bath. ...
The influence of the aging time of RuO2 and TiO2 sols on the electrochemical properties and behavior for the chlorine evolution reaction of activated titanium anodes obtained by the sol-gel procedure
(Elsevier, 2000)
The influence of the aging time of RuO2 and TiO2 sols used for the preparation of (40% RuO2+60% TiO2)/Ti anodes by the sol-gel procedure on the electrochemical properties and behavior for the chlorine evolution reaction ...
Synthesis and characterization of MoOx-Pt/C and TiOx-Pt/C nano-catalysts for oxygen reduction
(Pergamon-Elsevier Science Ltd, Oxford, 2009)
The oxygen reduction reaction (ORR) was studied at carbon supported MoOx-Pt/C and TiOx-Pt nanocatalysts in 0.5 mol dm(-3) HClO4 solution, at 25 degrees C. The MoOx-Pt/C and TiOx-Pt/C catalysts were prepared by the polyole ...