Template effect in caesium selective phenolic resins
Abstract
Two new phenolic resins have been synthesised by alkaline polycondensation of resorcinol and acetaldehyde using template polymerisation. The extraction properties of the resins have been evaluated in competitive extraction and show a selectivity in favour of Cs+. This selectivity is enhanced for the template resins. Structural data of the resins are discussed on the basis of C-13-NMR CPMAS spectra. In particular, for caesium template resins, a structure similar to resorcinarene has been evidenced.
Keywords:
phenolic resins / caesium / resorcinol / resorcinarene / template polymerisation / competitive extraction / C-13 CPMAS solid state NMRSource:
Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, 1998, 32, 4, 477-484Publisher:
- Kluwer Academic Publ, Dordrecht
DOI: 10.1023/A:1008069301996
ISSN: 0923-0750
WoS: 000078280900007
Scopus: 2-s2.0-0001525610
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Favre-Reguillon, A AU - Dunjić, Branko AU - Dumont, N AU - Lemaire, M PY - 1998 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/200 AB - Two new phenolic resins have been synthesised by alkaline polycondensation of resorcinol and acetaldehyde using template polymerisation. The extraction properties of the resins have been evaluated in competitive extraction and show a selectivity in favour of Cs+. This selectivity is enhanced for the template resins. Structural data of the resins are discussed on the basis of C-13-NMR CPMAS spectra. In particular, for caesium template resins, a structure similar to resorcinarene has been evidenced. PB - Kluwer Academic Publ, Dordrecht T2 - Journal of Inclusion Phenomena and Molecular Recognition in Chemistry T1 - Template effect in caesium selective phenolic resins EP - 484 IS - 4 SP - 477 VL - 32 DO - 10.1023/A:1008069301996 ER -
@article{ author = "Favre-Reguillon, A and Dunjić, Branko and Dumont, N and Lemaire, M", year = "1998", abstract = "Two new phenolic resins have been synthesised by alkaline polycondensation of resorcinol and acetaldehyde using template polymerisation. The extraction properties of the resins have been evaluated in competitive extraction and show a selectivity in favour of Cs+. This selectivity is enhanced for the template resins. Structural data of the resins are discussed on the basis of C-13-NMR CPMAS spectra. In particular, for caesium template resins, a structure similar to resorcinarene has been evidenced.", publisher = "Kluwer Academic Publ, Dordrecht", journal = "Journal of Inclusion Phenomena and Molecular Recognition in Chemistry", title = "Template effect in caesium selective phenolic resins", pages = "484-477", number = "4", volume = "32", doi = "10.1023/A:1008069301996" }
Favre-Reguillon, A., Dunjić, B., Dumont, N.,& Lemaire, M.. (1998). Template effect in caesium selective phenolic resins. in Journal of Inclusion Phenomena and Molecular Recognition in Chemistry Kluwer Academic Publ, Dordrecht., 32(4), 477-484. https://doi.org/10.1023/A:1008069301996
Favre-Reguillon A, Dunjić B, Dumont N, Lemaire M. Template effect in caesium selective phenolic resins. in Journal of Inclusion Phenomena and Molecular Recognition in Chemistry. 1998;32(4):477-484. doi:10.1023/A:1008069301996 .
Favre-Reguillon, A, Dunjić, Branko, Dumont, N, Lemaire, M, "Template effect in caesium selective phenolic resins" in Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, 32, no. 4 (1998):477-484, https://doi.org/10.1023/A:1008069301996 . .