The polymerisation kinetics of lower dialkyl itaconates
dc.creator | Tomić, Simonida | |
dc.creator | Filipović, Jovanka M. | |
dc.creator | Veličković, Jovan S. | |
dc.creator | Katsikas, Lynne | |
dc.creator | Popović, Ivanka | |
dc.date.accessioned | 2021-03-10T09:47:21Z | |
dc.date.available | 2021-03-10T09:47:21Z | |
dc.date.issued | 1999 | |
dc.identifier.issn | 1022-1352 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/227 | |
dc.description.abstract | The free radical polymerisation kinetics of diethyl- (DEI), dipropyl- (DnPI), dibutyl- (DnBI), and dihexyl itaconate (DHI) in the bulk were studied in the temperature range from 50 to 70 degrees C. The concentration of the initiator, 2,2'-azoisobutyronitrile (AIBN), was varied between 0.02 and 0.085 mol/dm(3). The rate of polymerisation (R-p), degree of polymerisation (DP), overall polymerization rate constant (K), the ratio of the propagation and termination rate constants (k(p)/k(t)(1/2)), as well as the chain transfer constant to monomer (C-M) were determined. The values of R-p, K, and k(p)/k(t)(1/2) of the investigated monomers all increase with increasing size of the alkyl group in the ester substituent, whereas C-M decreases when going from the dimethyl to the dihexyl ester. The values of C-M are larger than the corresponding values for the alkyl esters of methacrylic acid. | en |
dc.publisher | Wiley-VCH Verlag Gmbh, Weinheim | |
dc.rights | restrictedAccess | |
dc.source | Macromolecular Chemistry and Physics | |
dc.title | The polymerisation kinetics of lower dialkyl itaconates | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 2427 | |
dc.citation.issue | 10 | |
dc.citation.other | 200(10): 2421-2427 | |
dc.citation.rank | M21 | |
dc.citation.spage | 2421 | |
dc.citation.volume | 200 | |
dc.identifier.doi | 10.1002/(sici)1521-3935(19991001)200:102421::aid-macp24213.0.co;2-e | |
dc.identifier.pmid | ||
dc.identifier.scopus | 2-s2.0-0343928497 | |
dc.identifier.wos | 000083050000033 | |
dc.type.version | publishedVersion |