Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane plus n-alkane systems
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The Peng-Robinson-Stryjek-Vera (PRSV) equation of state (EOS) coupled with a modified two parameter van der Waals one-fluid mixing rule (MvdW1) and the Huron-Vidal-Orbey-Sandler mixing rule incorporating the NRTL equation as a G(E) model was used for the correlation of excess enthalpy (H-E, excess heat capacity (C-p(E)) and the simultaneous correlation of both properties. All calculations with temperature dependent parameters of EOS models were applied to 1,3-dioxolane+n-alkane systems. The correlation of the H-E and C-p(E) data alone with four coefficients and the H-E+C-p(E) data with six coefficients of the temperature dependent parameters of the HVOS-NRTL models could be considered as very satisfactory.
Keywords:
equation of state / mixing rule / excess properties / 1,3-dioxolane / n-alkaneSource:
Journal of the Serbian Chemical Society, 1999, 64, 12, 801-811Publisher:
- Serbian Chemical Society, Belgrade
DOI: 10.2298/jsc9912801d
ISSN: 0352-5139
PubMed:
WoS: 000084636900009
Scopus: 2-s2.0-0040715969
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Tehnološko-metalurški fakultetTY - JOUR AU - Đorđević, Bojan D. AU - Kijevčanin, Mirjana AU - Tasić, Aleksandar AU - Šerbanović, Slobodan P. PY - 1999 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/228 AB - The Peng-Robinson-Stryjek-Vera (PRSV) equation of state (EOS) coupled with a modified two parameter van der Waals one-fluid mixing rule (MvdW1) and the Huron-Vidal-Orbey-Sandler mixing rule incorporating the NRTL equation as a G(E) model was used for the correlation of excess enthalpy (H-E, excess heat capacity (C-p(E)) and the simultaneous correlation of both properties. All calculations with temperature dependent parameters of EOS models were applied to 1,3-dioxolane+n-alkane systems. The correlation of the H-E and C-p(E) data alone with four coefficients and the H-E+C-p(E) data with six coefficients of the temperature dependent parameters of the HVOS-NRTL models could be considered as very satisfactory. PB - Serbian Chemical Society, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane plus n-alkane systems EP - 811 IS - 12 SP - 801 VL - 64 DO - 10.2298/jsc9912801d ER -
@article{ author = "Đorđević, Bojan D. and Kijevčanin, Mirjana and Tasić, Aleksandar and Šerbanović, Slobodan P.", year = "1999", abstract = "The Peng-Robinson-Stryjek-Vera (PRSV) equation of state (EOS) coupled with a modified two parameter van der Waals one-fluid mixing rule (MvdW1) and the Huron-Vidal-Orbey-Sandler mixing rule incorporating the NRTL equation as a G(E) model was used for the correlation of excess enthalpy (H-E, excess heat capacity (C-p(E)) and the simultaneous correlation of both properties. All calculations with temperature dependent parameters of EOS models were applied to 1,3-dioxolane+n-alkane systems. The correlation of the H-E and C-p(E) data alone with four coefficients and the H-E+C-p(E) data with six coefficients of the temperature dependent parameters of the HVOS-NRTL models could be considered as very satisfactory.", publisher = "Serbian Chemical Society, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane plus n-alkane systems", pages = "811-801", number = "12", volume = "64", doi = "10.2298/jsc9912801d" }
Đorđević, B. D., Kijevčanin, M., Tasić, A.,& Šerbanović, S. P.. (1999). Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane plus n-alkane systems. in Journal of the Serbian Chemical Society Serbian Chemical Society, Belgrade., 64(12), 801-811. https://doi.org/10.2298/jsc9912801d
Đorđević BD, Kijevčanin M, Tasić A, Šerbanović SP. Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane plus n-alkane systems. in Journal of the Serbian Chemical Society. 1999;64(12):801-811. doi:10.2298/jsc9912801d .
Đorđević, Bojan D., Kijevčanin, Mirjana, Tasić, Aleksandar, Šerbanović, Slobodan P., "Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane plus n-alkane systems" in Journal of the Serbian Chemical Society, 64, no. 12 (1999):801-811, https://doi.org/10.2298/jsc9912801d . .