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Thermal investigation of some chelate Ni(II) complexes
dc.creator | Rajić, Nevenka | |
dc.creator | Stojaković, Đorđe | |
dc.creator | Gabrovšek, Roman | |
dc.date.accessioned | 2021-03-10T09:47:29Z | |
dc.date.available | 2021-03-10T09:47:29Z | |
dc.date.issued | 1999 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/229 | |
dc.description.abstract | Several diamine-nickel(II) complexes have been prepared and the kinetic parameters of their decomposition reactions investigated. The complexes undergo a gradual thermal decomposition. First, water is lost, followed by the departure of the diamine ligands. The activation energies for the first deamination decrease in the order Ni(1,2-pd)(3)Cl-2(H2O)(2) = Ni(en)(3)Cl-2(H2O)(2) gt Ni(1,3 -pd)(3)Cl-2(H2O)(2) gt Ni(dieten)(2)Cl-2 (H2O)(2) (en = 1,2-diaminoethane; 1,2-pd = 1,2-diaminopropane; 1,3-pd = 1,3-diaminopropane; dieten = 2-diethylaminoethylamine) which is in accordance with the chelate effect. The decomposition of the complexes can be represented by a variety of solid state decomposition models depending on the particular complex, as well as on the stage of the decomposition. | en |
dc.publisher | Serbian Chemical Society, Belgrade | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.source | Journal of the Serbian Chemical Society | |
dc.subject | nickel(II) complexes | en |
dc.subject | kinetic parameters | en |
dc.subject | activation energy | en |
dc.subject | thermal analysis | en |
dc.subject | TG/DTG-DSC | en |
dc.title | Thermal investigation of some chelate Ni(II) complexes | en |
dc.type | article | |
dc.rights.license | BY | |
dc.citation.epage | 130 | |
dc.citation.issue | 2 | |
dc.citation.other | 64(2): 123-130 | |
dc.citation.spage | 123 | |
dc.citation.volume | 64 | |
dc.identifier.pmid | ||
dc.identifier.rcub | https://hdl.handle.net/21.15107/rcub_technorep_229 | |
dc.identifier.scopus | 2-s2.0-0033481979 | |
dc.identifier.wos | 000078653000006 | |
dc.type.version | publishedVersion |
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