Densities, viscosities, and refractive indices of the binary systems (PEG200+1,2-propanediol,+1,3-propanediol) and (PEG400+1,2-propanediol,+1,3-propanediol) at (288.15 to 333.15) K and atmospheric pressure: Measurements and modeling
Само за регистроване кориснике
2013
Аутори
Majstorović, DivnaIvaniš, Gorica
Višak, Zoran P.
Živković, Emila
Šerbanović, Slobodan P.
Kijevčanin, Mirjana
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Densities, viscosities, and refractive indices of four binary systems, (PEG200 + 1,2-propanediol), (PEG200 + 1,3-propanediol), (PEG400 + 1,2-propanediol), (PEG400 + 1,3-propanediol) were measured at 10 temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, and 333.15) K and at atmospheric pressure. From these data, excess molar volumes, viscosity deviations and deviations in refractive indices were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of the existing specific molecular interactions and the observed mixing behavior between mixture components, taking into considerations the related effect of temperature. The correlations of V-E binary data were performed by the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vdW1) mixing rule and CEOS/G(E) mixing rule introduced by Twu, Coon, Bluck and Tilton (TCBT). The refractive indices of binary mixtures were... predicted by various mixing rules and compared with experimental data. The viscosity modelling was done by two types of models: predictive UNIFAC-VISCO and correlative Teja-Rice and McAlister equations. In addition, the experimental values of viscosity were used to determine the new CH2O-CH3, CH2O-CH2, CH2O-CH, CH2O-OH, CH-CH3, CH-CH2 and CH-OH interaction parameters for their application in the UNIFAC-VISCO model.
Кључне речи:
Density / Viscosity / Refractive index / Experimental measurement / ModelingИзвор:
Journal of Chemical Thermodynamics, 2013, 57, 510-529Издавач:
- Academic Press Ltd- Elsevier Science Ltd, London
Финансирање / пројекти:
- Research Fund of Ministry of Science and Environmental Protection, Serbia
- Нови индустријски и еколошки аспекти примене хемијске термодинамике на унапређење хемијских процеса са вишефазним и вишекомпонентним системима (RS-MESTD-Basic Research (BR or ON)-172063)
- Fundacao para a Ciencia e a Tecnologia, (FCT), PortugalPortuguese Foundation for Science and Technology [PTDC/EQU-EPR/103505/2008]
DOI: 10.1016/j.jct.2012.07.024
ISSN: 0021-9614
WoS: 000311429700065
Scopus: 2-s2.0-84870247300
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Majstorović, Divna AU - Ivaniš, Gorica AU - Višak, Zoran P. AU - Živković, Emila AU - Šerbanović, Slobodan P. AU - Kijevčanin, Mirjana PY - 2013 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2484 AB - Densities, viscosities, and refractive indices of four binary systems, (PEG200 + 1,2-propanediol), (PEG200 + 1,3-propanediol), (PEG400 + 1,2-propanediol), (PEG400 + 1,3-propanediol) were measured at 10 temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, and 333.15) K and at atmospheric pressure. From these data, excess molar volumes, viscosity deviations and deviations in refractive indices were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of the existing specific molecular interactions and the observed mixing behavior between mixture components, taking into considerations the related effect of temperature. The correlations of V-E binary data were performed by the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vdW1) mixing rule and CEOS/G(E) mixing rule introduced by Twu, Coon, Bluck and Tilton (TCBT). The refractive indices of binary mixtures were predicted by various mixing rules and compared with experimental data. The viscosity modelling was done by two types of models: predictive UNIFAC-VISCO and correlative Teja-Rice and McAlister equations. In addition, the experimental values of viscosity were used to determine the new CH2O-CH3, CH2O-CH2, CH2O-CH, CH2O-OH, CH-CH3, CH-CH2 and CH-OH interaction parameters for their application in the UNIFAC-VISCO model. PB - Academic Press Ltd- Elsevier Science Ltd, London T2 - Journal of Chemical Thermodynamics T1 - Densities, viscosities, and refractive indices of the binary systems (PEG200+1,2-propanediol,+1,3-propanediol) and (PEG400+1,2-propanediol,+1,3-propanediol) at (288.15 to 333.15) K and atmospheric pressure: Measurements and modeling EP - 529 SP - 510 VL - 57 DO - 10.1016/j.jct.2012.07.024 ER -
@article{ author = "Majstorović, Divna and Ivaniš, Gorica and Višak, Zoran P. and Živković, Emila and Šerbanović, Slobodan P. and Kijevčanin, Mirjana", year = "2013", abstract = "Densities, viscosities, and refractive indices of four binary systems, (PEG200 + 1,2-propanediol), (PEG200 + 1,3-propanediol), (PEG400 + 1,2-propanediol), (PEG400 + 1,3-propanediol) were measured at 10 temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, 318.15, 323.15, 328.15, and 333.15) K and at atmospheric pressure. From these data, excess molar volumes, viscosity deviations and deviations in refractive indices were calculated and fitted to the Redlich-Kister equation. The obtained results have been analyzed in terms of the existing specific molecular interactions and the observed mixing behavior between mixture components, taking into considerations the related effect of temperature. The correlations of V-E binary data were performed by the Peng-Robinson-Stryjek-Vera cubic equation of state (PRSV CEOS) coupled with the van der Waals (vdW1) mixing rule and CEOS/G(E) mixing rule introduced by Twu, Coon, Bluck and Tilton (TCBT). The refractive indices of binary mixtures were predicted by various mixing rules and compared with experimental data. The viscosity modelling was done by two types of models: predictive UNIFAC-VISCO and correlative Teja-Rice and McAlister equations. In addition, the experimental values of viscosity were used to determine the new CH2O-CH3, CH2O-CH2, CH2O-CH, CH2O-OH, CH-CH3, CH-CH2 and CH-OH interaction parameters for their application in the UNIFAC-VISCO model.", publisher = "Academic Press Ltd- Elsevier Science Ltd, London", journal = "Journal of Chemical Thermodynamics", title = "Densities, viscosities, and refractive indices of the binary systems (PEG200+1,2-propanediol,+1,3-propanediol) and (PEG400+1,2-propanediol,+1,3-propanediol) at (288.15 to 333.15) K and atmospheric pressure: Measurements and modeling", pages = "529-510", volume = "57", doi = "10.1016/j.jct.2012.07.024" }
Majstorović, D., Ivaniš, G., Višak, Z. P., Živković, E., Šerbanović, S. P.,& Kijevčanin, M.. (2013). Densities, viscosities, and refractive indices of the binary systems (PEG200+1,2-propanediol,+1,3-propanediol) and (PEG400+1,2-propanediol,+1,3-propanediol) at (288.15 to 333.15) K and atmospheric pressure: Measurements and modeling. in Journal of Chemical Thermodynamics Academic Press Ltd- Elsevier Science Ltd, London., 57, 510-529. https://doi.org/10.1016/j.jct.2012.07.024
Majstorović D, Ivaniš G, Višak ZP, Živković E, Šerbanović SP, Kijevčanin M. Densities, viscosities, and refractive indices of the binary systems (PEG200+1,2-propanediol,+1,3-propanediol) and (PEG400+1,2-propanediol,+1,3-propanediol) at (288.15 to 333.15) K and atmospheric pressure: Measurements and modeling. in Journal of Chemical Thermodynamics. 2013;57:510-529. doi:10.1016/j.jct.2012.07.024 .
Majstorović, Divna, Ivaniš, Gorica, Višak, Zoran P., Živković, Emila, Šerbanović, Slobodan P., Kijevčanin, Mirjana, "Densities, viscosities, and refractive indices of the binary systems (PEG200+1,2-propanediol,+1,3-propanediol) and (PEG400+1,2-propanediol,+1,3-propanediol) at (288.15 to 333.15) K and atmospheric pressure: Measurements and modeling" in Journal of Chemical Thermodynamics, 57 (2013):510-529, https://doi.org/10.1016/j.jct.2012.07.024 . .