The influence of polychromatic light on methomyl degradation in TiO2 and ZnO aqueous suspension
Apstrakt
The photocatalytic degradation of the insecticide methomyl in water using TiO2 Merck Eusolex (R) T (anatase) under Osram ultra-vitalux (R) lamp light (315-400 nm, 300W) was studied. The effect of the operational parameters, such as initial concentration of catalyst, initial methomyl concentration, initial salt concentration (NaCl), and pH, was studied. The optimal concentration of catalyst was found to be 2.0 g/L. Using the Langmuir-Hinshelwood mechanism as a base, a pseudo-first-order kinetic model was illustrated and the adsorption equilibrium constant and the rate constant of the surface reaction were calculated (K-MT = 0.079 L/mg and k
Ključne reči:
Photocatalytic degradation / Methomyl / Titanium dioxide / Zinc oxide / Water remediationIzvor:
Desalination and Water Treatment, 2014, 52, 22-24, 4342-4349Izdavač:
- Desalination Publ, Hopkinton
Finansiranje / projekti:
- Razvoj integrisanih sistema upravljanja štetnim organizmima u biljnoj proizvodnji sa ciljem prevazilaženja rezistentnosti i unapređenja kvaliteta i bezbednosti hrane (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-46008)
- Proučavanje sinteze, strukture i aktivnosti organskih jedinjenja prirodnog i sintetskog porekla (RS-MESTD-Basic Research (BR or ON)-172013)
DOI: 10.1080/19443994.2013.803321
ISSN: 1944-3994
WoS: 000340288400032
Scopus: 2-s2.0-84878919220
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Tomašević, Anđelka AU - Mijin, Dušan AU - Gašić, Slavica AU - Kiss, Erno PY - 2014 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2652 AB - The photocatalytic degradation of the insecticide methomyl in water using TiO2 Merck Eusolex (R) T (anatase) under Osram ultra-vitalux (R) lamp light (315-400 nm, 300W) was studied. The effect of the operational parameters, such as initial concentration of catalyst, initial methomyl concentration, initial salt concentration (NaCl), and pH, was studied. The optimal concentration of catalyst was found to be 2.0 g/L. Using the Langmuir-Hinshelwood mechanism as a base, a pseudo-first-order kinetic model was illustrated and the adsorption equilibrium constant and the rate constant of the surface reaction were calculated (K-MT = 0.079 L/mg and k PB - Desalination Publ, Hopkinton T2 - Desalination and Water Treatment T1 - The influence of polychromatic light on methomyl degradation in TiO2 and ZnO aqueous suspension EP - 4349 IS - 22-24 SP - 4342 VL - 52 DO - 10.1080/19443994.2013.803321 ER -
@article{ author = "Tomašević, Anđelka and Mijin, Dušan and Gašić, Slavica and Kiss, Erno", year = "2014", abstract = "The photocatalytic degradation of the insecticide methomyl in water using TiO2 Merck Eusolex (R) T (anatase) under Osram ultra-vitalux (R) lamp light (315-400 nm, 300W) was studied. The effect of the operational parameters, such as initial concentration of catalyst, initial methomyl concentration, initial salt concentration (NaCl), and pH, was studied. The optimal concentration of catalyst was found to be 2.0 g/L. Using the Langmuir-Hinshelwood mechanism as a base, a pseudo-first-order kinetic model was illustrated and the adsorption equilibrium constant and the rate constant of the surface reaction were calculated (K-MT = 0.079 L/mg and k", publisher = "Desalination Publ, Hopkinton", journal = "Desalination and Water Treatment", title = "The influence of polychromatic light on methomyl degradation in TiO2 and ZnO aqueous suspension", pages = "4349-4342", number = "22-24", volume = "52", doi = "10.1080/19443994.2013.803321" }
Tomašević, A., Mijin, D., Gašić, S.,& Kiss, E.. (2014). The influence of polychromatic light on methomyl degradation in TiO2 and ZnO aqueous suspension. in Desalination and Water Treatment Desalination Publ, Hopkinton., 52(22-24), 4342-4349. https://doi.org/10.1080/19443994.2013.803321
Tomašević A, Mijin D, Gašić S, Kiss E. The influence of polychromatic light on methomyl degradation in TiO2 and ZnO aqueous suspension. in Desalination and Water Treatment. 2014;52(22-24):4342-4349. doi:10.1080/19443994.2013.803321 .
Tomašević, Anđelka, Mijin, Dušan, Gašić, Slavica, Kiss, Erno, "The influence of polychromatic light on methomyl degradation in TiO2 and ZnO aqueous suspension" in Desalination and Water Treatment, 52, no. 22-24 (2014):4342-4349, https://doi.org/10.1080/19443994.2013.803321 . .