A kinetics study of the methomyl electrochemical degradation in the chloride containing solutions
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2014
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The kinetics of the electrochemical degradation of methomyl has been study by the means of electrochemical techniques, UV-vis spectrophotometry, HPLC, and HPLC-ESI-MS in the sodium chloride containing solution. Degradation kinetics has been investigated on the DSA Ti/RuO2 electrode in mainly 2 g dm(-3) sodium chloride solution, applying the currents in the range of 10-90 mA and methomyl concentration from 0.05 to 0.5 mM. It has been suggested that methomyl degradation initially follows the pseudo zero-order Langmuir-Hinshelwood reaction kinetics, and mixed homogeneous and heterogeneous pseudo first-order reaction during prolonged electrolysis.
Ključne reči:
Degradation / Electrochemical / Langmuir-Hinshelwood mechanism / UV-vis / LC-MSIzvor:
Applied Catalysis B-Environmental, 2014, 147, 429-438Izdavač:
- Elsevier, Amsterdam
Finansiranje / projekti:
- Proučavanje sinteze, strukture i aktivnosti organskih jedinjenja prirodnog i sintetskog porekla (RS-MESTD-Basic Research (BR or ON)-172013)
- Elektrohemijska sinteza i karakterizacija nanostrukturiranih funkcionalnih materijala za primenu u novim tehnologijama (RS-MESTD-Basic Research (BR or ON)-172046)
DOI: 10.1016/j.apcatb.2013.09.028
ISSN: 0926-3373
WoS: 000330489400048
Scopus: 2-s2.0-84885395580
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Grgur, Branimir AU - Mijin, Dušan PY - 2014 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2798 AB - The kinetics of the electrochemical degradation of methomyl has been study by the means of electrochemical techniques, UV-vis spectrophotometry, HPLC, and HPLC-ESI-MS in the sodium chloride containing solution. Degradation kinetics has been investigated on the DSA Ti/RuO2 electrode in mainly 2 g dm(-3) sodium chloride solution, applying the currents in the range of 10-90 mA and methomyl concentration from 0.05 to 0.5 mM. It has been suggested that methomyl degradation initially follows the pseudo zero-order Langmuir-Hinshelwood reaction kinetics, and mixed homogeneous and heterogeneous pseudo first-order reaction during prolonged electrolysis. PB - Elsevier, Amsterdam T2 - Applied Catalysis B-Environmental T1 - A kinetics study of the methomyl electrochemical degradation in the chloride containing solutions EP - 438 SP - 429 VL - 147 DO - 10.1016/j.apcatb.2013.09.028 ER -
@article{ author = "Grgur, Branimir and Mijin, Dušan", year = "2014", abstract = "The kinetics of the electrochemical degradation of methomyl has been study by the means of electrochemical techniques, UV-vis spectrophotometry, HPLC, and HPLC-ESI-MS in the sodium chloride containing solution. Degradation kinetics has been investigated on the DSA Ti/RuO2 electrode in mainly 2 g dm(-3) sodium chloride solution, applying the currents in the range of 10-90 mA and methomyl concentration from 0.05 to 0.5 mM. It has been suggested that methomyl degradation initially follows the pseudo zero-order Langmuir-Hinshelwood reaction kinetics, and mixed homogeneous and heterogeneous pseudo first-order reaction during prolonged electrolysis.", publisher = "Elsevier, Amsterdam", journal = "Applied Catalysis B-Environmental", title = "A kinetics study of the methomyl electrochemical degradation in the chloride containing solutions", pages = "438-429", volume = "147", doi = "10.1016/j.apcatb.2013.09.028" }
Grgur, B.,& Mijin, D.. (2014). A kinetics study of the methomyl electrochemical degradation in the chloride containing solutions. in Applied Catalysis B-Environmental Elsevier, Amsterdam., 147, 429-438. https://doi.org/10.1016/j.apcatb.2013.09.028
Grgur B, Mijin D. A kinetics study of the methomyl electrochemical degradation in the chloride containing solutions. in Applied Catalysis B-Environmental. 2014;147:429-438. doi:10.1016/j.apcatb.2013.09.028 .
Grgur, Branimir, Mijin, Dušan, "A kinetics study of the methomyl electrochemical degradation in the chloride containing solutions" in Applied Catalysis B-Environmental, 147 (2014):429-438, https://doi.org/10.1016/j.apcatb.2013.09.028 . .