Hydrocarbon selectivity models for iron-based Fischer-Tropsch catalyst
2015
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Two kinetic models of Fischer-Tropsch product selectivity have been developed based on reaction networks from the literature. The models were fitted to experimental data obtained using commercial iron-based catalyst in a stirred tank slurry reactor and under a wide range of process conditions. Results showed that both of the rival models were able to provide a satisfactory prediction of the experimental product distribution for n-paraffin, 1- and 2-olefin. The simpler of the two models, a reaction network with a single type of active sites and solubility enhanced 1-olefin readsorption term, was chosen as more adequate for practical use.
Ključne reči:
Fischer-Tropsch synthesis / Kinetic model / Iron catalyst / Product selectivity / Olefin readsorptionIzvor:
Chemical Engineering Research & Design, 2015, 95, 1-11Izdavač:
- Elsevier, Amsterdam
Finansiranje / projekti:
- US DOEUnited States Department of Energy (DOE) [DE-FG26-02NT41540]
- Qatar Foundation
- Razvoj efikasnijih hemijsko-inženjerskih procesa zasnovan na istraživanjima fenomena prenosa i principima intenzifikacije procesa (RS-MESTD-Basic Research (BR or ON)-172022)
DOI: 10.1016/j.cherd.2014.12.015
ISSN: 0263-8762
WoS: 000351966600001
Scopus: 2-s2.0-84975806611
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Olewski, Tomasz AU - Todić, Branislav AU - Nowicki, Lech AU - Nikačević, Nikola AU - Bukur, Dragomir B. PY - 2015 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2972 AB - Two kinetic models of Fischer-Tropsch product selectivity have been developed based on reaction networks from the literature. The models were fitted to experimental data obtained using commercial iron-based catalyst in a stirred tank slurry reactor and under a wide range of process conditions. Results showed that both of the rival models were able to provide a satisfactory prediction of the experimental product distribution for n-paraffin, 1- and 2-olefin. The simpler of the two models, a reaction network with a single type of active sites and solubility enhanced 1-olefin readsorption term, was chosen as more adequate for practical use. PB - Elsevier, Amsterdam T2 - Chemical Engineering Research & Design T1 - Hydrocarbon selectivity models for iron-based Fischer-Tropsch catalyst EP - 11 SP - 1 VL - 95 DO - 10.1016/j.cherd.2014.12.015 ER -
@article{ author = "Olewski, Tomasz and Todić, Branislav and Nowicki, Lech and Nikačević, Nikola and Bukur, Dragomir B.", year = "2015", abstract = "Two kinetic models of Fischer-Tropsch product selectivity have been developed based on reaction networks from the literature. The models were fitted to experimental data obtained using commercial iron-based catalyst in a stirred tank slurry reactor and under a wide range of process conditions. Results showed that both of the rival models were able to provide a satisfactory prediction of the experimental product distribution for n-paraffin, 1- and 2-olefin. The simpler of the two models, a reaction network with a single type of active sites and solubility enhanced 1-olefin readsorption term, was chosen as more adequate for practical use.", publisher = "Elsevier, Amsterdam", journal = "Chemical Engineering Research & Design", title = "Hydrocarbon selectivity models for iron-based Fischer-Tropsch catalyst", pages = "11-1", volume = "95", doi = "10.1016/j.cherd.2014.12.015" }
Olewski, T., Todić, B., Nowicki, L., Nikačević, N.,& Bukur, D. B.. (2015). Hydrocarbon selectivity models for iron-based Fischer-Tropsch catalyst. in Chemical Engineering Research & Design Elsevier, Amsterdam., 95, 1-11. https://doi.org/10.1016/j.cherd.2014.12.015
Olewski T, Todić B, Nowicki L, Nikačević N, Bukur DB. Hydrocarbon selectivity models for iron-based Fischer-Tropsch catalyst. in Chemical Engineering Research & Design. 2015;95:1-11. doi:10.1016/j.cherd.2014.12.015 .
Olewski, Tomasz, Todić, Branislav, Nowicki, Lech, Nikačević, Nikola, Bukur, Dragomir B., "Hydrocarbon selectivity models for iron-based Fischer-Tropsch catalyst" in Chemical Engineering Research & Design, 95 (2015):1-11, https://doi.org/10.1016/j.cherd.2014.12.015 . .