Biofuel cell based on horseradish peroxidase immobilized on copper sulfide as anode for decolorization of anthraquinone AV109 dye
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2016
Authors
Šekuljica, NatašaGvozdenović, Milica
Knežević-Jugović, Zorica
Jugović, Branimir
Grgur, Branimir
Article (Published version)
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Show full item recordAbstract
The potential application of electrochemically formed copper sulfide as horseradish peroxidase mediator in the enzymatic biofuel cell and anthraquinone AV109 dye as a fuel is investigated. The open circuit voltage of 0.52 V and short circuit current of similar to 3.6 mu A/cm(2) are obtained, with the maximum specific power of similar to 1 mu W/cm(2). The influence of internal resistance of the cell is discussed. Decolorization is investigated under open circuit potentials, and under external load of 3.31 k Omega conditions. In both cases, 40% of decolorization is achieved, but are three times faster under external load conditions. Specific energy during decolorization in such cell is estimated to 5 mWh/m(2). The possible mechanism of the power generation during decolorization of AV 109 dye is discussed.
Keywords:
Enzyme / Mediators / Hydrogen peroxide / Oxygen reductionSource:
Journal of Energy Chemistry, 2016, 25, 3, 403-408Publisher:
- Elsevier Science Bv, Amsterdam
Funding / projects:
- Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-MESTD-Basic Research (BR or ON)-172046)
DOI: 10.1016/j.jechem.2016.03.011
ISSN: 2095-4956
WoS: 000380077000010
Scopus: 2-s2.0-84963490966
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Tehnološko-metalurški fakultetTY - JOUR AU - Šekuljica, Nataša AU - Gvozdenović, Milica AU - Knežević-Jugović, Zorica AU - Jugović, Branimir AU - Grgur, Branimir PY - 2016 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3239 AB - The potential application of electrochemically formed copper sulfide as horseradish peroxidase mediator in the enzymatic biofuel cell and anthraquinone AV109 dye as a fuel is investigated. The open circuit voltage of 0.52 V and short circuit current of similar to 3.6 mu A/cm(2) are obtained, with the maximum specific power of similar to 1 mu W/cm(2). The influence of internal resistance of the cell is discussed. Decolorization is investigated under open circuit potentials, and under external load of 3.31 k Omega conditions. In both cases, 40% of decolorization is achieved, but are three times faster under external load conditions. Specific energy during decolorization in such cell is estimated to 5 mWh/m(2). The possible mechanism of the power generation during decolorization of AV 109 dye is discussed. PB - Elsevier Science Bv, Amsterdam T2 - Journal of Energy Chemistry T1 - Biofuel cell based on horseradish peroxidase immobilized on copper sulfide as anode for decolorization of anthraquinone AV109 dye EP - 408 IS - 3 SP - 403 VL - 25 DO - 10.1016/j.jechem.2016.03.011 ER -
@article{ author = "Šekuljica, Nataša and Gvozdenović, Milica and Knežević-Jugović, Zorica and Jugović, Branimir and Grgur, Branimir", year = "2016", abstract = "The potential application of electrochemically formed copper sulfide as horseradish peroxidase mediator in the enzymatic biofuel cell and anthraquinone AV109 dye as a fuel is investigated. The open circuit voltage of 0.52 V and short circuit current of similar to 3.6 mu A/cm(2) are obtained, with the maximum specific power of similar to 1 mu W/cm(2). The influence of internal resistance of the cell is discussed. Decolorization is investigated under open circuit potentials, and under external load of 3.31 k Omega conditions. In both cases, 40% of decolorization is achieved, but are three times faster under external load conditions. Specific energy during decolorization in such cell is estimated to 5 mWh/m(2). The possible mechanism of the power generation during decolorization of AV 109 dye is discussed.", publisher = "Elsevier Science Bv, Amsterdam", journal = "Journal of Energy Chemistry", title = "Biofuel cell based on horseradish peroxidase immobilized on copper sulfide as anode for decolorization of anthraquinone AV109 dye", pages = "408-403", number = "3", volume = "25", doi = "10.1016/j.jechem.2016.03.011" }
Šekuljica, N., Gvozdenović, M., Knežević-Jugović, Z., Jugović, B.,& Grgur, B.. (2016). Biofuel cell based on horseradish peroxidase immobilized on copper sulfide as anode for decolorization of anthraquinone AV109 dye. in Journal of Energy Chemistry Elsevier Science Bv, Amsterdam., 25(3), 403-408. https://doi.org/10.1016/j.jechem.2016.03.011
Šekuljica N, Gvozdenović M, Knežević-Jugović Z, Jugović B, Grgur B. Biofuel cell based on horseradish peroxidase immobilized on copper sulfide as anode for decolorization of anthraquinone AV109 dye. in Journal of Energy Chemistry. 2016;25(3):403-408. doi:10.1016/j.jechem.2016.03.011 .
Šekuljica, Nataša, Gvozdenović, Milica, Knežević-Jugović, Zorica, Jugović, Branimir, Grgur, Branimir, "Biofuel cell based on horseradish peroxidase immobilized on copper sulfide as anode for decolorization of anthraquinone AV109 dye" in Journal of Energy Chemistry, 25, no. 3 (2016):403-408, https://doi.org/10.1016/j.jechem.2016.03.011 . .