Thermoplastic acrylic resin with self-healing properties
Authorized Users Only
2016
Authors
Yerro, OmarRadojević, Vesna
Radović, Ivana
Petrović, Miloš
Uskoković, Petar
Stojanović, Dušica
Aleksić, Radoslav
Article (Published version)
Metadata
Show full item recordAbstract
This article presents a novel processing method of a self-healing acrylic thermoplastic material starting from a healing agent in solution form. The self-healing system consisted of a solution of the healing agent dicyclopentadiene (DCPD) in dimethylformamide (DMF) and a solution of the catalyst bis(tricyclohexylphosphine) benzylidene ruthenium (IV) dichloride (called Grubbs' catalyst) in dichloromethane (DCM). Hollow glass tubes filled with the self-healing components were incorporated into autopolymerizing acrylic resins. The one set of tubes was filled with a solution of DCPD (containing the dye Rhodamine B as a marker) and the other set with a solution of Grubbs' catalyst in dichloromethane. FTIR and DSC analyses revealed that a poly(DCPD) film formed at the healed interface. The low energy impact tests of the samples showed a recovery of 83% after 4 days. The benefits of the Grubb's catalyst solution are twofold; besides the repair of the cracks, which is common for such a system,... the reaction could decrease the content of residual monomer in the acrylic resin, which could reduce diffusion of residual monomer out of the resins. POLYM. ENG. SCI., 56:251-257, 2016.
Source:
Polymer Engineering and Science, 2016, 56, 3, 251-257Publisher:
- Wiley, Hoboken
Funding / projects:
- Predefined functional properties polymer composite materials processes and equipment development (RS-MESTD-Technological Development (TD or TR)-34011)
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45019)
DOI: 10.1002/pen.24244
ISSN: 0032-3888
WoS: 000371634200001
Scopus: 2-s2.0-84958864132
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Yerro, Omar AU - Radojević, Vesna AU - Radović, Ivana AU - Petrović, Miloš AU - Uskoković, Petar AU - Stojanović, Dušica AU - Aleksić, Radoslav PY - 2016 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3452 AB - This article presents a novel processing method of a self-healing acrylic thermoplastic material starting from a healing agent in solution form. The self-healing system consisted of a solution of the healing agent dicyclopentadiene (DCPD) in dimethylformamide (DMF) and a solution of the catalyst bis(tricyclohexylphosphine) benzylidene ruthenium (IV) dichloride (called Grubbs' catalyst) in dichloromethane (DCM). Hollow glass tubes filled with the self-healing components were incorporated into autopolymerizing acrylic resins. The one set of tubes was filled with a solution of DCPD (containing the dye Rhodamine B as a marker) and the other set with a solution of Grubbs' catalyst in dichloromethane. FTIR and DSC analyses revealed that a poly(DCPD) film formed at the healed interface. The low energy impact tests of the samples showed a recovery of 83% after 4 days. The benefits of the Grubb's catalyst solution are twofold; besides the repair of the cracks, which is common for such a system, the reaction could decrease the content of residual monomer in the acrylic resin, which could reduce diffusion of residual monomer out of the resins. POLYM. ENG. SCI., 56:251-257, 2016. PB - Wiley, Hoboken T2 - Polymer Engineering and Science T1 - Thermoplastic acrylic resin with self-healing properties EP - 257 IS - 3 SP - 251 VL - 56 DO - 10.1002/pen.24244 ER -
@article{ author = "Yerro, Omar and Radojević, Vesna and Radović, Ivana and Petrović, Miloš and Uskoković, Petar and Stojanović, Dušica and Aleksić, Radoslav", year = "2016", abstract = "This article presents a novel processing method of a self-healing acrylic thermoplastic material starting from a healing agent in solution form. The self-healing system consisted of a solution of the healing agent dicyclopentadiene (DCPD) in dimethylformamide (DMF) and a solution of the catalyst bis(tricyclohexylphosphine) benzylidene ruthenium (IV) dichloride (called Grubbs' catalyst) in dichloromethane (DCM). Hollow glass tubes filled with the self-healing components were incorporated into autopolymerizing acrylic resins. The one set of tubes was filled with a solution of DCPD (containing the dye Rhodamine B as a marker) and the other set with a solution of Grubbs' catalyst in dichloromethane. FTIR and DSC analyses revealed that a poly(DCPD) film formed at the healed interface. The low energy impact tests of the samples showed a recovery of 83% after 4 days. The benefits of the Grubb's catalyst solution are twofold; besides the repair of the cracks, which is common for such a system, the reaction could decrease the content of residual monomer in the acrylic resin, which could reduce diffusion of residual monomer out of the resins. POLYM. ENG. SCI., 56:251-257, 2016.", publisher = "Wiley, Hoboken", journal = "Polymer Engineering and Science", title = "Thermoplastic acrylic resin with self-healing properties", pages = "257-251", number = "3", volume = "56", doi = "10.1002/pen.24244" }
Yerro, O., Radojević, V., Radović, I., Petrović, M., Uskoković, P., Stojanović, D.,& Aleksić, R.. (2016). Thermoplastic acrylic resin with self-healing properties. in Polymer Engineering and Science Wiley, Hoboken., 56(3), 251-257. https://doi.org/10.1002/pen.24244
Yerro O, Radojević V, Radović I, Petrović M, Uskoković P, Stojanović D, Aleksić R. Thermoplastic acrylic resin with self-healing properties. in Polymer Engineering and Science. 2016;56(3):251-257. doi:10.1002/pen.24244 .
Yerro, Omar, Radojević, Vesna, Radović, Ivana, Petrović, Miloš, Uskoković, Petar, Stojanović, Dušica, Aleksić, Radoslav, "Thermoplastic acrylic resin with self-healing properties" in Polymer Engineering and Science, 56, no. 3 (2016):251-257, https://doi.org/10.1002/pen.24244 . .