Influence of the precursor chemical composition on heavy metal adsorption properties of hemp (Cannabis Sativa) fibers based biocarbon
2017
Authors
Vukčević, MarijaPejić, Biljana
Pajić-Lijaković, Ivana
Kalijadis, Ana
Kostić, Mirjana
Laušević, Zoran
Laušević, Mila
Article (Published version)
Metadata
Show full item recordAbstract
Waste hemp (Cannabis sativa) fibers were used as sustainable and renewable raw materials for production of low-cost biocarbon sorbent for heavy metals removal. Carbon precursors of different chemical composition were obtained by oxidative and alkaline treatments of hemp fibers. Influence of lignocellulosic precursor chemical composition on hemp fibers-based biocarbon (HFB) characteristics was examined by BET surface area measurement, scanning electron microscopy and mass titration. It was found that lignin content and polymorphic transformation of cellulose increase the SBET of microporous HFBs, while hemicelluloses induce more homogeneous distribution of adsorption active sites. Heavy metal ions adsorption onto HFBs is primarily influenced by the amount of surface oxygen groups, while specific surface area plays a secondary role. Equilibrium data obtained for lead ions adsorption were analyzed by different nonlinear adsorption isotherms, and the best fitting model was chosen using sta...ndard deviation and Akaike information criterion (AIC
Keywords:
hemp fibers / chemical composition / biocarbon / heavy metal ions / adsorption mechanismSource:
Journal of the Serbian Chemical Society, 2017, 82, 12, 1417-1431Publisher:
- Srpsko hemijsko društvo, Beograd
Funding / projects:
- Development and Application of Methods and Materials for Monitoring New Organic Contaminants, Toxic Compounds and Heavy Metals (RS-MESTD-Basic Research (BR or ON)-172007)
- Functionalization, characterization and application of cellulose and cellulose derivatives (RS-MESTD-Basic Research (BR or ON)-172029)
DOI: 10.2298/JSC170310080V
ISSN: 0352-5139
WoS: 000419391700008
Scopus: 2-s2.0-85040091880
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Vukčević, Marija AU - Pejić, Biljana AU - Pajić-Lijaković, Ivana AU - Kalijadis, Ana AU - Kostić, Mirjana AU - Laušević, Zoran AU - Laušević, Mila PY - 2017 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3641 AB - Waste hemp (Cannabis sativa) fibers were used as sustainable and renewable raw materials for production of low-cost biocarbon sorbent for heavy metals removal. Carbon precursors of different chemical composition were obtained by oxidative and alkaline treatments of hemp fibers. Influence of lignocellulosic precursor chemical composition on hemp fibers-based biocarbon (HFB) characteristics was examined by BET surface area measurement, scanning electron microscopy and mass titration. It was found that lignin content and polymorphic transformation of cellulose increase the SBET of microporous HFBs, while hemicelluloses induce more homogeneous distribution of adsorption active sites. Heavy metal ions adsorption onto HFBs is primarily influenced by the amount of surface oxygen groups, while specific surface area plays a secondary role. Equilibrium data obtained for lead ions adsorption were analyzed by different nonlinear adsorption isotherms, and the best fitting model was chosen using standard deviation and Akaike information criterion (AIC PB - Srpsko hemijsko društvo, Beograd T2 - Journal of the Serbian Chemical Society T1 - Influence of the precursor chemical composition on heavy metal adsorption properties of hemp (Cannabis Sativa) fibers based biocarbon EP - 1431 IS - 12 SP - 1417 VL - 82 DO - 10.2298/JSC170310080V ER -
@article{ author = "Vukčević, Marija and Pejić, Biljana and Pajić-Lijaković, Ivana and Kalijadis, Ana and Kostić, Mirjana and Laušević, Zoran and Laušević, Mila", year = "2017", abstract = "Waste hemp (Cannabis sativa) fibers were used as sustainable and renewable raw materials for production of low-cost biocarbon sorbent for heavy metals removal. Carbon precursors of different chemical composition were obtained by oxidative and alkaline treatments of hemp fibers. Influence of lignocellulosic precursor chemical composition on hemp fibers-based biocarbon (HFB) characteristics was examined by BET surface area measurement, scanning electron microscopy and mass titration. It was found that lignin content and polymorphic transformation of cellulose increase the SBET of microporous HFBs, while hemicelluloses induce more homogeneous distribution of adsorption active sites. Heavy metal ions adsorption onto HFBs is primarily influenced by the amount of surface oxygen groups, while specific surface area plays a secondary role. Equilibrium data obtained for lead ions adsorption were analyzed by different nonlinear adsorption isotherms, and the best fitting model was chosen using standard deviation and Akaike information criterion (AIC", publisher = "Srpsko hemijsko društvo, Beograd", journal = "Journal of the Serbian Chemical Society", title = "Influence of the precursor chemical composition on heavy metal adsorption properties of hemp (Cannabis Sativa) fibers based biocarbon", pages = "1431-1417", number = "12", volume = "82", doi = "10.2298/JSC170310080V" }
Vukčević, M., Pejić, B., Pajić-Lijaković, I., Kalijadis, A., Kostić, M., Laušević, Z.,& Laušević, M.. (2017). Influence of the precursor chemical composition on heavy metal adsorption properties of hemp (Cannabis Sativa) fibers based biocarbon. in Journal of the Serbian Chemical Society Srpsko hemijsko društvo, Beograd., 82(12), 1417-1431. https://doi.org/10.2298/JSC170310080V
Vukčević M, Pejić B, Pajić-Lijaković I, Kalijadis A, Kostić M, Laušević Z, Laušević M. Influence of the precursor chemical composition on heavy metal adsorption properties of hemp (Cannabis Sativa) fibers based biocarbon. in Journal of the Serbian Chemical Society. 2017;82(12):1417-1431. doi:10.2298/JSC170310080V .
Vukčević, Marija, Pejić, Biljana, Pajić-Lijaković, Ivana, Kalijadis, Ana, Kostić, Mirjana, Laušević, Zoran, Laušević, Mila, "Influence of the precursor chemical composition on heavy metal adsorption properties of hemp (Cannabis Sativa) fibers based biocarbon" in Journal of the Serbian Chemical Society, 82, no. 12 (2017):1417-1431, https://doi.org/10.2298/JSC170310080V . .